Review of hydraulics of Floating Treatment Islands retrofitted in waterbodies receiving stormwater.

Stormwater pollution causes an excessive influx of nutrients and metals to the receiving waterbodies (stormwater ponds, lakes, and rivers), which can cause eutrophication and metal toxicity. One of the most cost-effective and eco-friendly solutions to stormwater pollution is constructing Floating Treatment Islands (FTIs) within the waterbodies receiving stormwater runoff. Treatment efficiency of FTIs depends on many factors including plant species, temperature, detention time, and pollutant loading rate. Another important factor is FTI hydraulics, which determines the amount of inflow to the root zone and residence time, greatly impacting the treatment. However, only a few studies refer to the hydraulics of waterbodies retrofitted with FTIs. This paper reviews available literature on field-scale, laboratory-scale and numerical studies on the hydraulics of FTI retrofitted waterbodies. Because of limited knowledge on the factors affecting hydraulics of waterbodies retrofitted with FTIs, current practices cannot ensure maximum hydraulic performance of this system. This review paper identifies different factors affecting the FTI hydraulics, investigates knowledge gaps, and provides future research direction for hydraulically efficient design of FTIs to treat stormwater. It was found that there is a need to investigate the impact of new design parameters such as FTI shape, FTI coverage, inlet-outlet configurations, and shape of waterbody on the hydraulic performance of FTI retrofitted waterbodies. A lack of dimensional analysis on FTI retrofitted waterbodies in existing literature revealed that field-scale values were not properly scaled down in laboratory experiments. Although a few short-circuiting prevention mechanisms (SPMs) were used in different field-scale studies, those mechanisms may be vulnerable to short-circuiting in the vertical dimension. It was revealed that studying the role of eddy diffusion and gap layer for vertical short-circuiting can help designing better SPMs. This review also identified that further investigation is required to incorporate root flexibility in the current modeling approach of FTI retrofitted waterbodies.

Improving stormwater quality at source using catch basin inserts.

Stormwater runoff transports contaminants, including gross pollutants (GPs) accumulated on surfaces to nearby receiving water bodies. These may clog storm drainage systems, seal side entry pits and increase dissolved pollutants in receiving water bodies. Best management practices (BMPs) such as oil and grit separators, grassed swales, vegetated filter strips, retention ponds, and catch basin inserts (CBIs) are implemented to reduce stormwater pollutants in urban runoff. However, the information on physicochemical characteristics of the pollutants are still few in literature but important to improve the design of BMPs, considering qualitative aspects, and their operation. CBIs are devices used to remove GPs at source without requiring any extra land use because they are typically mounted within a catch basin (e.g. side entry pit) or existing drain. In this study, improvement of stormwater quality was investigated at two different sites (Subiaco, a residential area and Hillarys Boat Harbour, a commercial-marine-recreational area; Western Australia) where a new CBI made of non-woven polypropylene geotextile was installed in side entry pits to capture GPs at source. Influent and effluent water from the CBIs was collected and analyzed for BOD, COD, TSS and PO4-P with maximum improvements in water quality of 90%, 88%, 88% and 26% respectively. The heavy metals in influent and effluent water were found very low and below the guideline values. Analysis of particle size distribution, specific surface area of solids, SEM images and heavy metal content (Cu, Fe, Ni, Pb, Zn, Cd) in solids showed that the residential area contained more finer particles than the commercial area but that solids in the commercial area contained greater concentrations of heavy metals than those from the residential area. The specific surface area was found to be higher in the residential area and particles were thought to be largely sourced from traffic. However, these characteristics may be monitored for longer term for more CBIs installed in different locations.

Characterising stormwater gross pollutants captured in catch basin inserts.

The accumulation of wash-off solid waste, termed gross pollutants (GPs), in drainage systems has become a major constraint for best management practices (BMPs) of stormwater. GPs should be captured at source before the material clogs the drainage network, seals the infiltration capacity of side entry pits or affects the aquatic life in receiving waters. BMPs intended to reduce stormwater pollutants include oil and grit separators, grassed swales, vegetated filter strips, retention ponds, and catch basin inserts (CBIs) are used to remove GP at the source and have no extra land use requirement because they are typically mounted within a catch basin (e.g. side entry pits; grate or gully pits). In this study, a new type of CBI, recently developed by Urban Stormwater Technologies (UST) was studied for its performance at a site in Gosnells, Western Australia. This new type of CBI can capture pollutants down to particle sizes of 150µm while retaining its shape and pollutant capturing capacity for at least 1year. Data on GP and associated water samples were collected during monthly servicing of CBIs for one year. The main component of GPs was found to be vegetation (93%): its accumulation showed a strong relationship (r2=0.9) with rainfall especially during the wet season. The average accumulation of total GP load for each CBI was 384kg/ha/yr (dry mass) with the GP moisture content ranging from 24 to 52.5%. Analysis of grain sizes of GPs captured in each CBI showed similar distributions in the different CBIs. The loading rate coefficient (K) calculated from runoff and GP load showed higher K-values for CBI located near trees. The UST developed CBI in this study showed higher potential to capture GPs down to 150µm in diameter than similar CBI devices described in previous studies.

Removal of emerging perfluorooctanoic acid and perfluorooctane sulfonate contaminants from lake water.

Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) are the major polyfluoroalkyl substances (PFASs) contaminating global water environment. This study investigated the efficiency of granular activated carbon (GAC), ultrafiltration (UF) and nanofiltration (NF) treatment for removing PFOS and PFOA contaminants from lake water. NF gave greater removal of all contaminant types (in terms of organic matter, PFOS and PFOA) than GAC treatment which in turn was greater than UF treatment. The lower removal by UF was due to larger pore size of the membrane compared to the size of the target contaminants. For all treatment processes, lower pH (4) in the feedwater showed greater rejection of the organics and selected PFASs. This was likely due to increase in the electrostatic repulsion between solute and sorbent. It could be observed that on increasing the concentration of organics in the feed solution, the rejection of PFOA/PFOS decreased which was due to competition between organics and PFOS/PFOA for binding sites on the membrane/activated carbon surface. It was also noted that protein content led to greater influence for lower rejection of the PFOA/PFOS than carbohydrate or DOC content. This study demonstrated the potential use of membrane processes for removing emerging persistent organic pollutant removal from lake water.

Impact of ozonation, anion exchange resin and UV/H2O2 pre-treatments to control fouling of ultrafiltration membrane for drinking water treatment.

The effects of ozonation, anion exchange resin (AER) and UV/H2O2 were investigated as a pre-treatment to control organic fouling (OF) of ultrafiltration membrane in the treatment of drinking water. It was found that high molecular weight (MW) organics such as protein and polysaccharide substances were majorly responsible for reversible fouling which contributed to 90% of total fouling. The decline rate increased with successive filtration cycles due to deposition of protein content over time. All pre-treatment could reduce the foulants of a Ultrafiltration membrane which contributed to the improvement in flux, and there was a greater improvement of flux by UV/H2O2 (61%) than ozonation (43%) which in turn was greater than AER (23%) treatment. This was likely due to the effective removal/breakdown of high MW organic content. AER gave greater removal of biofouling potential components (such as biodegradable dissolved organic carbon and assimilable organic carbon contents) compared to UV/H2O2 and ozonation treatment. Overall, this study demonstrated the potential of pre-treatments for reducing OF of ultrafiltration for the treatment of drinking water.

Modelling combined effect of chloramine and copper on ammonia-oxidizing microbial activity using a biostability approach.

Continuous and batch laboratory experiments were used to evaluate the combined effects of copper and chloramine on ammonia oxidizing microbes present in otherwise high nitrifying water samples. The experimental data were analyzed using a biostability concept and quantified with the biostable residual concentratrion (BRC) of monochloramine, or the concentration that prevents the onset of nitrification. In the batch experiments, copper dosing ≥0.25 mg-Cu L(-1) resulted in complete inhibition of nitrification, and a lower copper dosing (0.1 mg-Cu L(-1)) delayed nitrification. The BRC was systematically lowered with the addition of copper. For example, a free-ammonium concentration of 0.1 mg-N L(-1) had a BRC of 0.73 mg-Cl2 L(-1) with no Cu, but addition of 0.1 mg-Cu L(-1) lowered the BRC to 0.16 mg-Cl2 L(-1), while addition of 0.25 mg-Cu L(-1) eliminated the need to add chloramine (BRC = 0). A non-competitive inhibition model fit the experimental data well with a copper threshold of 0.044 mg-Cu L(-1) and can be used to estimate Cu doses needed to prevent nitrification based on the chloramine concentration. Full scale systems applications need further study.

Modelling temperature effects on ammonia-oxidising bacterial biostability in chloraminated systems.

The biostability concept has been successfully used to predict the onset of nitrification in drinking water distribution systems, but in certain cases deficiencies have been observed in the predictions, indicating that modifications to parameters were needed. At the biostable disinfectant residual concentration (BRC), the rate of ammonia-oxidising bacterial (AOB) growth due to the substrate (free ammonia) and the rate of inactivation due to the disinfectant are balanced. Growth and inactivation rates vary greatly with temperature, but temperature is yet to be considered in the biostability equation. In this paper, two separate novel models are proposed which take into account the temperature effects on the biostability equation. First, a novel model of specific growth rate variability with temperature was shown to be valid for different bacterial species. Then, the biostability model was modified and validated for ammonia-oxidising bacterial activity using data collected from laboratory and full-scale distribution systems. The proposed model has two important uses: while the specific growth rate model and biostability model can be widely adopted for many microbes, the biostability model for AOB also has the potential to aid water utilities in disinfectant residual management throughout yearly temperature variations.