ABSTRACT
2-Oxo-1,3,5-trinitro-1,3,5-triazacyclohexane (Keto-RDX or K-6), the most powerful energetic material among nitrourea explosives, has been prepared and scaled up at laboratory level. The identity and purity of the product are tested by elemental analysis, IR, NMR, mass and HPLC techniques. Thermal response and sensitivity experiments on K-6 are also described. The data on sensitivity shows that K-6 can be utilised practically only in phlegmatized form.
Subject(s)
Rodenticides/chemistry , Rodenticides/chemical synthesis , Triazines/chemistry , Triazines/chemical synthesis , Chromatography, High Pressure Liquid , Magnetic Resonance Spectroscopy , Mass Spectrometry , TemperatureABSTRACT
3-Amino-5-nitro-1,2,4-triazole (ANTA) and its derivatives have been prepared in order to carry out the systematic studies on structural aspects, explosive and thermal behaviour. Thermal studies were carried out for ANTA and 4,6-bis-(3-amino-5-nitro-1H-1,2,4-triazole-1-yl)-5-nitropyrimidine (DANTNP) by thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimeter (DSC) and manometric thermal analysis. The results show that (DANTNP) is more thermally stable than ANTA when compared in terms of activation energy.
