A non-edible waste as a potential sorptive media for removal of herbicide from the watershed.

A non-edible waste, from biodiesel processing industry is being turned to carbonaceous material (biochar) using slow pyrolysis. The material was found to be amorphous with hydroxyl, methyl, carbonyl and carboxyl functional groups onto the surface. The influencing parameters, namely adsorbate concentration (0.05-5 mg/l), biochar loading (0.02-0.4 g), pH(3-12) and particle sizes (0.03-0.13 mm) were studied to observe the effect on the sorption of simazine using biochar. A multivariate optimization using central composite design in response surface methodology was performed employing desirability function. The optimized biosorption efficiency (B%) and capacity qe was found to be 91.98 % and 0.83 mg/g respectively with the optimized parameters as 3.76 mg/l of adsorbate concentration, 0.12 g of biochar loading, pH of 5.26 and 0.0535 mm of particle size. The simazine adsorption phenomena were found to be multilayer heterogeneous sorption based on Langmuir and Freundlich models. The kinetics investigation shows that chemisorption was involved for the transfer of simazaine to the surface of biochar with three distinct intra particulate diffusional zones. An adsorption process requires activation energy of 11.27 kJ/mol and the negative magnitude of ΔH* indicates the exothermicity involved in the process.

Optimization of glucose formation in karanja biomass hydrolysis using Taguchi robust method.

The main objective of the present study is aimed to optimize the process parameters for the production of glucose from karanja seed cake. The Taguchi robust design method with L9 orthogonal array was applied to optimize hydrolysis reaction conditions and maximize sugar yield. Effect of temperature, acid concentration, and acid to cake weight ratio were considered as the main influencing factors which effects the percentage of glucose and amount of glucose formed. The experimental results indicated that acid concentration and liquid to solid ratio had a principal effect on the amount of glucose formed when compared to that of temperature. The maximum glucose formed was 245 g/kg extractive free cake.

Biotreatability studies of pharmaceutical wastewater using an anaerobic suspended film contact reactor.

The pharmaceutical industrial effluents, which include several organic solvents and other toxic chemicals, are generally treated by aerobic process, which is cost intensive in nature. The alternative anaerobic route to degrade the toxic effluents is attractive due to the lower cost of treatment and the generation of gas, which can supplement the energy requirements. There are few reports on the anaerobic treatment of the pharmaceutical effluents. In the present investigation, the effluents from a bulk drug industry, which utilizes several organic chemicals, have been taken to assess their applicability for anaerobic treatment. The organic loading rates were varied from 0.25 kg/m3/day to 2.5 kg/m3/day and the COD reduction was found to be in the range of 60 to 80%. Long term operation of an anaerobic suspended film contact reactor carried out with 1.25 kg/m3/day was found to be optimum. The biogas generated during the degradation process was monitored and the methane content was found to be 60-70%.

Reverse micellar extraction of antibiotics from aqueous solutions.

Several antibiotics such as erythromycin, oxytetracyclin, benzylpenicillin, and actidione were extracted from aqueous buffers into reverse micellar solution of bis(2-ethylhexyl) sulfosuccinate sodium salt (AOT) in isooctane and recovered with high efficiency under mild conditions. Preliminary experiments with oxytetracycline dissolved in a fermentation broth indicate that the antibiotic can be selectively extracted from the broth and recovered efficiently without serious loss of potency.