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1.
Polymers (Basel) ; 13(12)2021 Jun 20.
Article in English | MEDLINE | ID: mdl-34203069

ABSTRACT

Two new photopolymerizable vinyl (2-(allyloxy) 1,4-naphthoquinone, HNQA) and epoxy (2-(oxiran-2yl methoxy) 1,4-naphthoquinone, HNQE) photoinitiators derived from lawsone were designed in this paper. These new photoinitiators can be used as one-component photoinitiating systems for the free-radical photopolymerization of acrylate bio-based monomer without the addition of any co-initiators. As highlighted by the electron paramagnetic resonance (EPR) spin-trapping results, the formation of carbon-centered radicals from an intermolecular H abstraction reaction was evidenced and can act as initiating species. Interestingly, the introduction of iodonium salt (Iod) used as a co-initiator has led to (1) the cationic photopolymerization of epoxy monomer with high final conversions and (2) an increase of the rates of free-radical polymerization of the acrylate bio-based monomer; we also demonstrated the concomitant thiol-ene reaction and cationic photopolymerizations of a limonene 1,2 epoxide/thiol blend mixture with the HNQA/Iod photoinitiating system.

2.
Chempluschem ; 82(10): 1298-1307, 2017 Oct.
Article in English | MEDLINE | ID: mdl-31957991

ABSTRACT

Photoinitiating systems combining 2,6-diaminoanthraquinone (AQD), iodonium salt (Iod), and benzyl alcohol derivatives have been developed to efficiently initiate the cationic polymerization of epoxy monomers upon light exposure. Electron spin resonance spin-trapping (ESR ST) experiments, fluorescence investigations, and steady-state photolysis have demonstrated that a dye-sensitized reaction occurs between AQD and the benzyl alcohol derivatives through a hydrogen abstraction mechanism upon light illumination, followed by reduction of Iod. The in situ liberation of protic acids promotes the cationic photopolymerization of epoxy monomers concomitantly with hydrolysis and condensation of the reactive methoxysilanes of an organic-inorganic precursor, for example, 3-glycidyloxypropyltrimethoxysilane (GPTMS). Nanoindentation experiments and scratch resistance tests proved that the resulting GPTMS coatings exhibit very good resistance to brittle fracture and excellent adherence to stainless-steel substrates. Interestingly, antibacterial tests of the GPTMS coatings showed efficient antifouling and biocide properties against E. coli and S. aureus.

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