Moss biomass as effective biosorbents for heavy metals in contaminated water.

The study explored batch adsorption of Cd(II) and Pb(II) ions using moss biomass from Barbula consanguinea and Hyophila involuta, assessing removal efficiency concerning various parameters. Both moss species showed high removal rates for Cd(II) (87 % for B. consanguinea and 89 % for H. involuta) and Pb(II) (93 % for B. consanguinea and 94 % for H. involuta) from contaminated water, reaching equilibrium within 30 min. While Cd(II) removal was pH-independent, Pb(II) removal showed pH-dependence, peaking at pH 5.0-5.5. Adsorption isotherm analysis indicated that the Langmuir, Freundlich, Elovich, Sips, and Redlich-Peterson models best described Cd(II) and Pb(II) adsorption onto both moss species (except for Cd(II) adsorption onto H. involuta), with R 2  > 0.98. This confirms a heterogeneous surface with both monolayer and multilayer adsorption sites. The pseudo-second-order kinetic model confirmed chemisorption on moss biomass from both species. FTIR spectra identified major binding sites such as phenols, alkaloids, amines, alkenes, nitro compounds, and low-molecular-weight carbohydrates. EDS analysis validated the bonding of Cd(II) and Pb(II) ions to the biomass surface by displacing Ca(II) ions. According to the Langmuir model, moss biomass exhibited selective adsorption, favoring Pb(II) over Cd(II). B. consanguinea showed a higher adsorption capacity than H. involuta, which is attributed to its higher negative zeta potential. This study underscores the novelty of moss biomass for heavy metal removal in wastewater treatment, highlighting its sustainability, effectiveness, cost-efficiency, versatility, and eco-friendliness.

Unveiling the adoption of metaverse technology in Bangkok metropolitan areas: A UTAUT2 perspective with social media marketing and consumer engagement.

As the metaverse emerges as a transformative digital realm, its adoption and integration into various aspects of society are subjects of increasing scholarly and practical interest. This research investigated the factors influencing the intention to use metaverse technology (IU) in Bangkok metropolitan areas, with a particular focus on the extended Unified Theory of Acceptance and Use of Technology 2 (UTAUT2) framework, alongside the role of social media marketing (SMM) and consumer engagement (CE). To verify behavioral intention, gender, age, and experience are proposed as moderating factors affecting the constructs on individuals' behavioral intention of metaverse technology usage. The study collected data from 403 Thai internet users living in Bangkok and its surrounding areas using an online questionnaire. Subsequently, the PLS-SEM method was employed to validate the research model's robustness and reliability. Structural model analysis revealed significant relationships among constructs, highlighting SMM's direct influence on UTAUT2 (ß = 0.787) and CE (ß = 0.211). Serial mediation analyzes demonstrated a fully mediating role of SMM influencing UI through CE (ß = 0.572) and UTAUT2 (ß = 0.306). Moderation analyzes revealed the association between SMM and IU, mediated through UTAUT2 and CE, is moderated by age and experience. Additionally, the integration of PLS-SEM and artificial neural network (ANN) models underscored the accuracy and predictive power of the proposed framework. The findings of this study not only contribute to academic literature but also offer practical implications for marketers aiming to navigate the metaverse landscape effectively. They emphasize the pivotal role of UTAUT2 constructs and the subtle interplay between SMM, CE, and IU in shaping successful marketing strategies.

Understanding online purchase intention of plant-based foods: Exploring causal factors and moderating role of self-efficacy within the SOR theory.

This research explored Thai consumers' online purchase intention for plant-based foods (PBFs), investigating factors shaping this intention and the impact of self-efficacy. Conducting surveys on 402 individuals from Bangkok, Thailand, the study employed structural equation modelling (SEM) to analyse relationships among consumer identity, online brand trust, social influence, perceived value, and self-efficacy concerning online purchase intention. Findings revealed significant influences of consumer identity, online brand trust, social influence, and perceived value on online purchase intention, with online brand trust having the most significant direct effect. Additionally, self-efficacy moderated the impact of these factors on online purchase intention. The study's contribution lies in highlighting the role of online brand trust and self-efficacy levels in shaping consumer behaviour, which is crucial for promoting sustainable dietary choices and improving well-being through digital marketing strategies.

Metal toxicity in Bryum coronatum Schwaegrichen: impact on chlorophyll content, lamina cell structure, and metal accumulation.

This research examined the impact of heavy metals, including Cd, Pb, and Zn, on chlorophyll content and lamina cell structure in Bryum coronatum. After exposure to varying metal concentrations (0.015, 0.065, 0.250, 1, and 4 mg/L), chlorophyll content, chloroplast numbers, lamina cell change, and metal accumulation were investigated. Chlorophyll content was assessed using spectrophotometry, whereas chloroplast numbers and lamina cell changes were examined under a light microscope. Metal accumulation was quantified through ICP-MS. The findings revealed that Cd notably reduced chlorophyll a content, while Pb and Zn showed minimal influence. Cd and Pb exposure decreased the number of chloroplasts in lamina cells, with no impact from Zn. The moss's capacity to absorb metals increased with higher exposure levels, indicating its potential as a biomonitor for heavy metal pollution. Cell mortality occurred in response to Cd and Pb, primarily in the median and apical lamina regions, while Zn had no effect. This study sheds light on heavy metal toxicity in B. coronatum, underscoring its significance for environmental monitoring. Further research on the mechanisms and consequences of heavy metal toxicity in bryophytes is essential for a comprehensive understanding of this critical issue.

The capacity of moss B. coronatum to absorb metals increased with higher exposure levels, providing quantitative data on heavy metal pollution around it.

Evolutionary History of the Marchantia polymorpha Complex.

The potential role of introgression in evolution has gained increased interest in recent years. Although some fascinating examples have been reported, more information is needed to generalize the importance of hybridization and introgression for adaptive divergence. As limited data exist on haploid dominant species, we analyzed genomes of three subspecies of the liverwort Marchantia polymorpha. We used available genomic data for subsp. ruderalis and carried out whole-genome (PacBio) sequencing for one individual each of subsp. montivagans and subsp. polymorpha as well as Illumina resequencing of additional genomes for all three subspecies. The three subspecies were compared against M. paleacea as outgroup. Our analyses revealed separation of the three taxa, but all three possible topologies were richly represented across the genomes, and the underlying divergence order less obvious. This uncertainty could be the result of the divergence of the three subspecies close in time, or that introgression has been frequent since divergence. In particular, we found that pseudo-chromosome 2 in subsp. montivagans was much more diverged than other parts of the genomes. This could either be explained by specific capture of chromosome 2 from an unknown related species through hybridization or by conservation of chromosome 2 despite intermittent or ongoing introgression affecting more permeable parts of the genomes. A higher degree of chromosomal rearrangements on pseudo-chromosome 2 support the second hypothesis. Species tree analyses recovered an overall topology where subsp. montivagans diverged first and subsp. ruderalis and subsp. polymorpha appeared as sister lineages. Each subspecies was associated with its own chloroplast and mitochondrial haplotype group. Our data suggest introgression but refute a previous hypothesis that subsp. ruderalis is a new stabilized hybrid between the other two subspecies.

Ecology of black flies (Diptera: Simuliidae) in streams of northern and southern Thailand: Factors associated with larval and pupal distributions.

The ecology of black flies in Thailand was investigated, based on 19,451 larvae and pupae collected from 65 stream sites in 10 northern provinces during the rainy, cool, and hot seasons, and 1,906 larvae and pupae collected from 18 sites in 9 southern provinces during the cool season. Twenty-seven black fly species were identified from northern Thailand, of which 26 were found in the cool season, when richness was greatest. Significant regressions between species richness and elevation fit a unimodal model in the rainy season but a linear model in the cool and hot seasons. Twenty-two species occurred in all seasons. Species in the subgenera Gomphostilbia and Nevermannia were most common in the hot season, whereas species in the subgenus Simulium were predominant in the cool season. Some species (e.g., S. nakhonense) were geographically widespread, whereas others (e.g., S. chaliowae and S. weji) were restricted to particular localities. Eighteen species and species complexes were found in southern Thailand. The S. tani complex was the most widely distributed taxon, occurring at 66.7% of the sites in the South. Ecological analyses revealed that water temperature, elevation, conductivity, dissolved oxygen, and stream size were among the significant factors associated with the distributions of black flies in both regions of Thailand-the same factors associated with simuliid distributions in other areas of the world.