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1.
ACS Appl Mater Interfaces ; 15(13): 16755-16767, 2023 Apr 05.
Article in English | MEDLINE | ID: mdl-36947435

ABSTRACT

Rational design and structural regulation of hybrid nanomaterials with superior electrochemical performance are crucial for developing sustainable energy storage platforms. Among these materials, NiCo-layered double hydroxides (NiCo-LDHs) demonstrate an exceptional charge storage capabilities owing to their tunable 2D lamellar structure, large interlayer spacing, and rich redox electrochemically active sites. However, NiCo-LDHs still suffer from sever agglomeration of their particles with limited charge transfer rates, resulting in an inadequate rate capability. In this study, bimetallic ZnCo-metal organic framework (MOF) tripods were grown on the surface of NiCo-LDH nanowires, which significantly reduced the self-agglomeration and stacking of the NiCo-LDH nanowire arrays, offering more accessible active sites for charge transfer and shortening the path for ion diffusion. The fabricated hybrid ZnCo-MOF@NiCo-LDH and its individual counterparts were tested as supercapacitor electrodes. The ZnCo-MOF@NiCo-LDH electrode demonstrated a remarkable specific capacitance of 1611 F g-1 at 2 A g-1 with an enhanced rate capability of 66% from 2 to 20 A g-1. Moreover, an asymmetric all solid-state supercapacitor device was constructed using ZnCo-MOF@NiCo-LDH and palm tree-derived activated carbon (P-AC) as positive and negative poles, respectively. The constructed device can store a high specific energy of 44.5 Wh Kg-1 and deliver a specific power of 876.7 W Kg-1 with outstanding Columbic efficiency over 10,000 charging/discharging cycles at 15 A g-1.

2.
ACS Appl Mater Interfaces ; 14(22): 25545-25555, 2022 Jun 08.
Article in English | MEDLINE | ID: mdl-35604325

ABSTRACT

The direct growth of sub-100 nm thin-film metal oxides has witnessed a sustained interest as a superlative approach for the fabrication of smart energy storage platforms. Herein, sub-100 nm Zr-doped orthorhombic Nb2O5 nanotube films are synthesized directly on the Nb-Zr substrate and tested as negative supercapacitor electrode materials. To boost the pseudocapacitive performance of the fabricated films, supplement Nb4+ active sites (defects) are subtly induced into the metal oxide lattice, resulting in 13% improvement in the diffusion current at 100 m V/s over that of the defect-free counterpart. The defective sub-100 nm film (H-NbZr) exhibits areal and volumetric capacitances of 6.8 mF/cm2 and 758.3 F/cm3, respectively. The presence of oxygen-deficient states enhances the intrinsic conductivity of the thin film, resulting in a reduction in the band gap energy from 3.25 to 2.5 eV. The assembled supercapacitor device made of nitrogen-doped activated carbon (N-AC) and H-NbZr (N-AC//H-NbZr) is able to retain 93, 83, 78, and 66% of its first cycle capacitance after 1000, 2000, 3000, and 4500 successive charge/discharge cycles, respectively. An eminent energy record of approximately 0.77 µW h/cm2 at a power of 0.9 mW/cm2 is achieved at 1 mA/cm2 with superb capability.

3.
Langmuir ; 37(17): 5161-5171, 2021 May 04.
Article in English | MEDLINE | ID: mdl-33876646

ABSTRACT

We demonstrate the fabrication of binder-free electrospun nickel-manganese oxides embedded into carbon-shell fibrous electrodes. The morphological and structural properties of the assembled electrode materials were elucidated by high-resolution transmission electron microscopy (HR-TEM), field-emission scanning electron microscopy, and glancing-angle X-ray diffraction. The fibrous structure of the electrodes was retained even after annealing at high temperatures. The X-ray photoelectron spectroscopy and HR-TEM analyses revealed the formation of nickel and manganese oxides in multiple oxidation states (Ni2+, Ni3+, Mn2+, Mn3+, and Mn4+) embedded in the carbon shell. The embedded nickel-manganese oxides into the carbon matrix fibrous electrodes exhibit an excellent capacitance (1082 F/g) in 1 M K2SO4 at 1 A/g and possess a high rate capability of 73% at 5 A/g. The high rate capability and capacitance can be attributed to the presence of carbon cross-linked channels, the binder-free nature of the electrodes, and various oxidation states of the Ni-Mn oxides. The asymmetric supercapacitor device constructed of the as-fabricated nanofibers and the bio-derived microporous carbon as the positive and negative electrodes, respectively, sustains up to 1.9 V with a high specific capacitance at 1.5 A/g of 108 F/g. The nanofibrous//bio-derived device exhibits an outstanding specific energy of 54.2 W h/kg with a high specific power of 1425 W/kg. Interestingly, the tested device maintains a high capacitive retention of 92% upon cycling over 10,000 charging/discharging cycles.

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