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Chem Commun (Camb) ; 49(10): 1020-2, 2013 Feb 01.
Article in English | MEDLINE | ID: mdl-23258275

ABSTRACT

We report the formation of left- (M-helix) and right-handed (P-helix) nanoassemblies of a porphyrin-diaminopurine conjugate (Por-DAP) templated by a single stranded oligodeoxythymidine (dT40) via directional hydrogen bonding. The supramolecular helicity can be controlled by the ionic strength, Por-DAP : dT40 ratio, and annealing rate.


Subject(s)
DNA, Single-Stranded/chemistry , Nanostructures/chemistry , Porphyrins/chemical synthesis , 2-Aminopurine/analogs & derivatives , 2-Aminopurine/chemistry , Hydrogen Bonding , Molecular Structure , Porphyrins/chemistry
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