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1.
J Phys Chem Lett ; 7(11): 2080-4, 2016 Jun 02.
Article in English | MEDLINE | ID: mdl-27193044

ABSTRACT

The trans-cis isomerization makes azobenzene (AB) a robust molecular switch. Once adsorbed to a metal, however, the switching is inefficient or absent due to rapid excited-state quenching or loss of the trans-cis bistability. We find that tris-[4-(phenylazo)-phenyl]-amine is a rather efficient switch on Ag(111). Using scanning tunneling and atomic force microscopy at submolecular resolution along with density functional theory calculations, we show that the switching process is no trans-cis isomerization but rather a reorientation of the N-N bond of an AB unit. It proceeds through a twisting motion of the azo-bridge that leads to a lateral shift of a phenyl ring. Thus, the role of the Ag substrate is ambivalent. While it suppresses the original bistability of the azobenzene units, it creates a new one by inducing a barrier for the rotation of the N-N bond.

2.
J Am Chem Soc ; 135(24): 8814-7, 2013 Jun 19.
Article in English | MEDLINE | ID: mdl-23724828

ABSTRACT

Trioctyl-functionalized triazatriangulenium (trioctyl-TATA) deposited on Au(111) and Ag(111) surfaces by electrospray ionization was investigated using low-temperature scanning tunneling microscopy. The molecule surprisingly adsorbs with gauche rather than anti conformations of the octyl groups. We observed chiral amplification in the islands. Only one of the eight possible configurations of the octyl groups was found in homochiral hexagonal networks. Quantum-chemical calculations confirmed and explained the preference for the gauche conformations of adsorbed trioctyl-TATA.


Subject(s)
Alkanes/chemistry , Microscopy, Scanning Tunneling , Adsorption , Gold/chemistry , Models, Molecular , Molecular Conformation , Silver/chemistry , Surface Properties
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