ABSTRACT
A new technique that enables frequency-resolved cavity ringdown absorption spectra to be obtained over a large optical bandwidth by a single laser shot is described. The technique, ringdown spectral photography (RSP), simultaneously employs two key principles to record the time and frequency response of an optical cavity along orthogonal axes of a CCD array detector. Previously, the principles employed in RSP were demonstrated with narrow-band laser light that was scanned in frequency [Chem. Phys. Lett. 292, 143 (1998)]. Here, the RSP method is demonstrated using single pulses of broadband visible laser light. The ability to obtain broad as well as rotationally resolved spectra over a large bandwidth with high sensitivity is demonstrated.
ABSTRACT
The cavity ringdown technique (CRLAS) has been employed to measure the gas phase absorption spectrum of the platinum silicide molecule in the 350 nm region. All nine of the measured rovibronic bands are assigned to a single 1 sigma-1 sigma electronic transition, with a ground state vibrational frequency of omega "e = 549.0(3) cm-1, and a bond length of r"0 = 2.069(1) angstroms. The results of this study are compared with experimental data for the coinage metal silicides. Additionally, time-of-flight mass spectrometric results indicate that a variety of polyatomic metal silicides are formed in our molecular jet expansion.
