1.
Chem Commun (Camb)
; 53(45): 6121-6124, 2017 Jun 01.
Article
in English
| MEDLINE
| ID: mdl-28530281
ABSTRACT
An inherently chiral metallocorrole has been resolved for the first time by means of HPLC on a chiral stationary phase. For the compound in question, a homoleptic tungsten biscorrole, the absolute configurations of the enantiomers were assigned using online HPLC-ECD measurements in conjunction with time-dependent CAM-B3LYP calculations, which provided accurate simulations of the ECD spectra.