Impact of groundwater flow on methane gas migration and retention in unconsolidated aquifers.

Methane leaking at depth from hydrocarbon wells poses an environmental and safety hazard. However, determining the occurrence and magnitude of gas migration at ground surface is challenging, as part of the leaking gas is retained during upward migration. We investigated migration through unconsolidated sedimentary aquifers using a two-phase, two-component (water and methane) flow and transport model constructed in DuMux. A sensitivity analysis for migration through a 60 m thick sandy aquifer showed that retention by dissolution can be significant even with low groundwater Darcy velocities of 1 m.yr-1. Retention was negligible in the absence of groundwater flow. Besides groundwater velocity, both hydrogeological (permeability, entry pressure, pore-size distribution, and residual gas saturation) and leakage conditions (depth, magnitude and spatial dimensions) determined model outcomes. Additional simulations with interbedded finer grained sediments resulted in substantial lateral spreading of migrating gas. This delayed upward migration and enhanced retention in overlying sandy units where groundwater velocities are highest. Overall, the results of this study show that for unconsolidated aquifer systems and the most commonly observed leakage rates (0.1-10 m3.d-1), significant amounts of migrating methane can be retained due to dissolution into laterally flowing groundwater. Consequently, resulting atmospheric methane emissions above such leaks may be delayed with decades after the onset of leakage, significantly reduced, or prevented entirely.

Occurrence and fate of methane leakage from cut and buried abandoned gas wells in the Netherlands.

Methane leakage caused by well integrity failure was assessed at 28 abandoned gas wells and 1 oil well in the Netherlands, which have been plugged, cut and buried to below the ground surface (≥3 mbgl). At each location, methane concentrations were thoroughly scanned at the surface. A static chamber setup was used to measure methane flow rates from the surface as well as from 1 m deep holes drilled using a hand auger. An anomalously high flow rate from 1 m depth combined with isotopic confirmation of a thermogenic origin revealed ongoing leakage at 1 of the 29 wells (3.4%), that had gone undetected by surficial measurements. Gas fluxes at the other sites were due to shallow production of biogenic methane. Detailed investigation at the leaking well (MON-02), consisting of 28 flux measurements conducted in a 2 × 2 m grid from holes drilled to 1 and 2 m depth, showed that flux magnitude was spatially heterogeneous and consistently larger at 2 m depth compared to 1 m. Isotopic evidence revealed oxidation accounted for roughly 25% of the decrease in flux towards the surface. The estimated total flux from the well (443 g CH4 hr-1) was calculated by extrapolation of the individual flow rate measurements at 2 m depth and should be considered an indicative value as the validity of the estimate using our approach requires confirmation by modelling and/or experimental studies. Together, our findings show that total methane emissions from leaking gas wells in the Netherlands are likely negligible compared to other sources of anthropogenic methane emissions (e.g. <1% of emissions from the Dutch energy sector). Furthermore, subsurface measurements greatly improve the likelihood of detecting leakage at buried abandoned wells and are therefore essential to accurately assess their greenhouse gas emissions and explosion hazards.

Impact of an historic underground gas well blowout on the current methane chemistry in a shallow groundwater system.

Blowouts present a small but genuine risk when drilling into the deep subsurface and can have an immediate and significant impact on the surrounding environment. Nevertheless, studies that document their long-term impact are scarce. In 1965, a catastrophic underground blowout occurred during the drilling of a gas well in The Netherlands, which led to the uncontrolled release of large amounts of natural gas from the reservoir to the surface. In this study, the remaining impact on methane chemistry in the overlying aquifers was investigated. Methane concentrations higher than 10 mg/L (n = 12) were all found to have δ13C-CH4 values larger than -30‰, typical of a thermogenic origin. Both δ13C-CH4 and δD-CH4 correspond to the isotopic composition of the gas reservoir. Based on analysis of local groundwater flow conditions, this methane is not a remnant but most likely the result of ongoing leakage from the reservoir as a result of the blowout. Progressive enrichment of both δ13C-CH4 and δD-CH4 is observed with increasing distance and decreasing methane concentrations. The calculated isotopic fractionation factors of εC = 3 and εD = 54 suggest anaerobic methane oxidation is partly responsible for the observed decrease in concentrations. Elevated dissolved iron and manganese concentrations at the fringe of the methane plume show that oxidation is primarily mediated by the reduction of iron and manganese oxides. Combined, the data reveal the long-term impact that underground gas well blowouts may have on groundwater chemistry, as well as the important role of anaerobic oxidation in controlling the fate of dissolved methane.