Strong influence of magnetic field and non-uniform stress on elastic modulus and transition temperatures of twinned Ni-Fe(Co)-Ga alloy.

The magnetization value and electric resistivity of the single-crystalline sample of Ni50Fe19Co4Ga27 shape memory alloy were measured. The elastic modulus was determined by the Dynamic Mechanical Analysis (DMA). The characteristic temperatures of martensitic transformation (MT) of the alloy were estimated from the temperature dependences of magnetization, electric resistivity and elastic modulus. A significant disparity between MT temperatures resulting from DMA and those estimated from magnetic and resistivity measurements was discovered. It was argued that the discrepancy is caused by the non-uniform mechanical stressing of twinned single crystal by the DMA analyzer. Moreover, the DMA measurements revealed a significant decrease of the elastic modulus of twinned martensite under the applied magnetic field of 1.5 kOe. To explain this effect, the temperature-dependent Young's modulus of twinned crystal lattice was computed. The computations showed that the experimentally observed field-induced change of the elastic modulus is caused by the stress-assisted detwinning of the crystal lattice by the applied magnetic field.

Antibacterial activity, cytocompatibility, and thermomechanical stability of Ti40Zr10Cu36Pd14 bulk metallic glass.

This paper envisions Ti40Zr10Cu36Pd14 bulk metallic glass as an oral implant material and evaluates its antibacterial performance in the inhabitation of oral biofilm formation in comparison with the gold standard Ti-6Al-4V implant material. Metallic glasses are superior in terms of biocorrosion and have a reduced stress shielding effect compared with their crystalline counterparts. Dynamic mechanical and thermal expansion analyses on Ti40Zr10Cu36Pd14 show that these materials can be thermomechanically shaped into implants. Static water contact angle measurement on samples' surface shows an increased surface wettability on the Ti-6Al-4V surface after 48 â€‹h incubation in the water while the contact angle remains constant for Ti40Zr10Cu36Pd14. Further, high-resolution transmission and scanning transmission electron microscopy analysis have revealed that Ti40Zr10Cu36Pd14 interior is fully amorphous, while a 15 â€‹nm surface oxide is formed on its surface and assigned as copper oxide. Unlike titanium oxide formed on Ti-6Al-4V, copper oxide is hydrophobic, and its formation reduces surface wettability. Further surface analysis by X-ray photoelectron spectroscopy confirmed the presence of copper oxide on the surface. Metallic glasses cytocompatibility was first demonstrated towards human gingival fibroblasts, and then the antibacterial properties were verified towards the oral pathogen Aggregatibacter actinomycetemcomitans responsible for oral biofilm formation. After 24 â€‹h of direct infection, metallic glasses reported a >70% reduction of bacteria viability and the number of viable colonies was reduced by ∼8 times, as shown by the colony-forming unit count. Field emission scanning electron microscopy and fluorescent images confirmed the lower surface colonization of metallic glasses in comparison with controls. Finally, oral biofilm obtained from healthy volunteers was cultivated onto specimens' surface, and proteomics was applied to study the surface property impact on species composition within the oral plaque.

Water in Mesoporous Confinement: Glass-To-Liquid Transition or Freezing of Molecular Reorientation Dynamics?

The first mechanical relaxation measurements (f = 400 Hz) of water confined in micro-porous silica were performed more than 40 years ago. The authors reported a so called "capillary transition" (here denoted as P3) of water in the core of the pores and a second one at a lower temperature, which they called the "adsorbate transition" (P1 in present work) related to water near the surface of the pores. The capillary transition was identified with the freezing of water in the centre of the pores. However, even 40 years later, the origin of the adsorbate transition is not yet clear. One study relates it to the liquid-to-glass transition of the supercooled water in the pores, and another study to the freezing of the proton reorientations at the lattice defects. The present work shows the data from extensive dynamic mechanical analysis (DMA) measurements (f = 0.1 Hz-70 Hz) of water confined in mesoporous silica (d = 2.5, 5 and 10 nm), which are in favour of a liquid-to-glass scenario.

Two glass transitions of polyurea networks: effect of the segmental molecular weight.

Polymer-nanoparticle composites (PNCs) play an increasing role in technology. Inorganic or organic nanoparticles are usually incorporated into a polymer matrix to improve material properties. Polyurea is a spontaneously occurring PNC, exhibiting a phase segregated structure with hard nanodomains embedded in a soft (elastically compliant) matrix. This system shows two glass transitions at Tg1 and Tg2. It has been argued that they are related to the freezing of motion of molecular segments in the soft matrix (usual polymer α-glass transition at Tg1) and to regions of restricted mobility near the hard nanodomains (α'-process) at Tg2, respectively. We present detailed dynamic mechanical analysis (DMA) measurements for polyurea networks with different segmental lengths l(c) (2.5, 12.1, 24.5 nm) of the polymer chains, i.e. different volume fractions ϕ(x) (0.39, 0.12, 0.07) of the hard domains. The two glass transitions show up in two distinct peaks in tan δ at Tα and Tα'. Analysing the data using a Havriliak-Negami term for the α- and α'-relaxation, as well as Vogel-Fulcher dependencies for the corresponding relaxation times, it is found that the α-glass transition at Tg1 increases strongly (up to ΔT = 70 K) with increasing ϕ(x), whereas the α'-transition at Tg2 remains unchanged. At ϕ(x)(c) ≈ 0.19 the two curves intersect, i.e. Tg1 = Tg2. This value of ϕ(x)(c) is very close to the percolation threshold of randomly oriented overlapping ellipsoids of revolution with an aspect ratio of about 1 : 4-1 : 5. We therefore conclude that around 19% of the hard nanodomains polyurea changes from a system of hard nanoparticles embedded in a soft matrix (ϕ(x) ≤ ϕ(x)(c)) to a system of soft domains confined in a network of percolated hard domains at ϕ(x) ≥ ϕ(x)(c).

Statistical similarity between the compression of a porous material and earthquakes.

It has long been stated that there are profound analogies between fracture experiments and earthquakes; however, few works attempt a complete characterization of the parallels between these so separate phenomena. We study the acoustic emission events produced during the compression of Vycor (SiO(2)). The Gutenberg-Richter law, the modified Omori's law, and the law of aftershock productivity hold for a minimum of 5 decades, are independent of the compression rate, and keep stationary for all the duration of the experiments. The waiting-time distribution fulfills a unified scaling law with a power-law exponent close to 2.45 for long times, which is explained in terms of the temporal variations of the activity rate.

Elastic and anelastic anomalies associated with the antiferromagnetic ordering transition in wüstite, FexO.

The elastic and anelastic properties of three different samples of Fe(x)O have been determined in the frequency range 0.1-2 MHz by resonant ultrasound spectroscopy and in the range 0.1-50 Hz by dynamic mechanical analysis in order to characterize ferroelastic aspects of the magnetic ordering transition at T(N) ~ 195 K. No evidence was found of separate structural and magnetic transitions but softening of the shear modulus was consistent with the involvement of bilinear coupling, λe(4)q, between a symmetry-breaking strain, e(4), and a structural order parameter, q. Unlike a purely ferroelastic transition, however, C(44) does not go to zero at the critical temperature, T*(c), due to the intervention of the magnetic ordering at a higher temperature. The overall pattern of behaviour is nevertheless consistent with what would be expected for a system with separate structural and magnetic instabilities, linear-quadratic coupling between the structural (q) and magnetic (m) driving order parameters, λqm(2), and T(N) > T*(c). Comparison with data from the literature appears to confirm the same pattern in MnO and NiO, with a smaller difference between T(N) and T*(c) in the former and a larger difference in the latter. Strong attenuation of acoustic resonances at high frequencies and a familiar pattern of attenuation at low frequencies suggest that twin walls in the rhombohedral phase have typical ferroelastic properties. Acoustic dissipation in the stability field of the cubic phase is tentatively attributed to anelastic relaxations of the defect ordered structure of non-stoichiometric wüstite or of the interface between local regions of wüstite and magnetite, with a rate controlling step determined by the diffusion of iron.

Strain coupling mechanisms and elastic relaxation associated with spin state transitions in LaCoO3.

Advantage is taken of the wealth of experimental data relating to the evolution with temperature of spin states of Co(3+) in LaCoO3 in order to undertake a detailed investigation of the mechanisms by which changes in electronic structure can influence strain, and elastic and anelastic relaxations in perovskites. The macroscopic strain accompanying changes in the spin state in LaCoO3 is predominantly a volume strain arising simply from the change in effective ionic radius of the Co(3+) ions. This acts to renormalize the octahedral tilting transition temperature in a manner that is easily understood in terms of coupling between the tilt and spin order parameters. Results from resonant ultrasound spectroscopy at high frequencies (0.1-1.5 MHz) reveal stiffening of the shear modulus which scales qualitatively with a spin order parameter defined in terms of changing Co-O bond lengths. From this finding, in combination with results from dynamic mechanical analysis at low frequencies (0.1-50 Hz) and data from the literature, four distinctive anelastic relaxation mechanisms are identified. The relaxation times of these are displayed on an anelasticity map and are tentatively related to spin-spin relaxation, spin-lattice relaxation, migration of twin walls and migration of magnetic polarons. The effective activation energy for the freezing of twin wall motion below ~590 K at low frequencies was found to be 182 ± 21 kJ mol(-1) (1.9 ± 0.2 eV) which is attributed to pinning by pairs of oxygen vacancies, though the local mechanisms appear to have a spread of relaxation times. It seems inevitable that twin walls due to octahedral tilting must have quite different characteristics from the matrix in terms of local spin configurations of Co(3+). A hysteresis in the elastic properties at high temperatures further emphasizes the importance of oxygen content in controlling the properties of LaCoO3.

Anelastic loss behaviour of mobile microstructures in SrZr(1-x)Ti(x)O3 perovskites.

Anelastic loss mechanisms associated with phase transitions in SrZr(1-x)Ti(x)O(3) perovskites (x = 0.375, 0.450, 0.550, 0.775) have been investigated by dynamic mechanical analysis between 128 and 723 K at frequencies of 0.1-50 Hz. Distinctive patterns of changes in the elastic moduli due to octahedral tilting transitions correlate closely with data for the shear modulus obtained previously by resonant ultrasound spectroscopy at high frequencies (∼0.5 MHz). The I4/mcm <--> Imma transition is first order and has a characteristic minimum in the shear modulus and Young's modulus. For x = 0.450 and 0.550, a dissipation peak occurs at the transition temperature, the maximum of which varies with frequency according to a power law relationship of the form tanδ = Af(n), with n≈ - 0.3. Debye-like dissipation peaks in the stability field of the Imma structure at x = 0.375 have a frequency and temperature dependence consistent with twin wall pinning by defects with an activation energy ∼ 184 kJ mol(-1). These results indicate that there is diversity of pinning and relaxation processes for transformation twin walls and interfaces in different perovskites with I4/mcm, Imma and Pnma structures.

Piezo-optic coefficients of MgO-doped LiNbO3 crystals.

We describe an interferometric technique suitable for determination of piezo-optic coefficients (POCs) in crystals. The method considers real nonparallelism of measured samples, thereby improving the measuring precision of POCs significantly. Corresponding equations are derived for the interferometric half-wave stress method. Using this technique we have determined a complete set of POCs of pure and MgO-doped LiNbO(3) crystals. The reliability of the data has been confirmed by comparing the effective POCs expressed through the combinations of measured POCs and the effective POCs determined independently using highly precise optical birefringence measurements. Pure and MgO-doped LiNbO(3) crystals reveal nearly the same magnitudes of POCs. However, LiNbO(3):MgO exhibits about 4 times higher resistance with respect to powerful light radiation, making it more suitable for application in acousto-optic devices that deal with superpowerful laser radiation.