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1.
Environ Sci Technol ; 56(12): 9083-9091, 2022 06 21.
Article in English | MEDLINE | ID: mdl-35671404

ABSTRACT

The relevance of wastewater treatment plant (WWTP) effluents in fluvial networks is increasing as urbanization grows in catchments. Urban-sourced fine particles from WWTP effluents deposit and accumulate in the streambed sediment of receiving streams over time and can fuel respiration rates, which can thus potentially increase rates of biogeochemical reactions and CO2 emissions to the atmosphere. We aimed to provide a quantitative assessment of the influence of WWTP-sourced fine particles deposited in the streambed sediment on stream metabolic activity for 1 year in an intermittent Mediterranean stream. More nutrient-rich and metabolically active fine particle standing stocks were observed downstream of the WWTP, propagating to the end of the 820 m study reach, especially during the dry period (i.e., when the dilution capacity of the stream to WWTP inputs is <40%). Based on the longitudinal patterns of fine particle standing stocks and their metabolic activity, we estimated that the in-stream bioreactive capacity associated with these fine particles could potentially lead to substantial carbon dioxide emissions to the atmosphere (3.1 g C/m2/d). We show the importance of incorporating fine particle standing stocks downstream of point source inputs, particularly WWTPs in intermittent streams, into carbon budgets.


Subject(s)
Hydrology , Water Purification , Carbon Dioxide , Urbanization
3.
Phys Rev E ; 105(1-1): 014105, 2022 Jan.
Article in English | MEDLINE | ID: mdl-35193292

ABSTRACT

We present a framework for systems in which diffusion-advection transport of a tracer substance in a mobile zone is interrupted by trapping in an immobile zone. Our model unifies different model approaches based on distributed-order diffusion equations, exciton diffusion rate models, and random-walk models for multirate mobile-immobile mass transport. We study various forms for the trapping time dynamics and their effects on the tracer mass in the mobile zone. Moreover, we find the associated breakthrough curves, the tracer density at a fixed point in space as a function of time, and the mobile and immobile concentration profiles and the respective moments of the transport. Specifically, we derive explicit forms for the anomalous transport dynamics and an asymptotic power-law decay of the mobile mass for a Mittag-Leffler trapping time distribution. In our analysis we point out that even for exponential trapping time densities, transient anomalous transport is observed. Our results have direct applications in geophysical contexts, but also in biological, soft matter, and solid state systems.

4.
Phys Rev E ; 103(5-1): 052123, 2021 May.
Article in English | MEDLINE | ID: mdl-34134286

ABSTRACT

Stochastic resetting, a diffusive process whose amplitude is reset to the origin at random times, is a vividly studied strategy to optimize encounter dynamics, e.g., in chemical reactions. Here we generalize the resetting step by introducing a random resetting amplitude such that the diffusing particle may be only partially reset towards the trajectory origin or even overshoot the origin in a resetting step. We introduce different scenarios for the random-amplitude stochastic resetting process and discuss the resulting dynamics. Direct applications are geophysical layering (stratigraphy) and population dynamics or financial markets, as well as generic search processes.

5.
Ground Water ; 53(5): 699-708, 2015.
Article in English | MEDLINE | ID: mdl-25214174

ABSTRACT

Numerical transport models based on the advection-dispersion equation (ADE) are built on the assumption that sub-grid cell transport is Fickian such that dispersive spreading around the average velocity is symmetric and without significant tailing on the front edge of a solute plume. However, anomalous diffusion in the form of super-diffusion due to preferential pathways in an aquifer has been observed in field data, challenging the assumption of Fickian dispersion at the local scale. This study develops a fully Lagrangian method to simulate sub-grid super-diffusion in a multidimensional regional-scale transport model by using a recent mathematical model allowing super-diffusion along the flow direction given by the regional model. Here, the time randomizing procedure known as subordination is applied to flow field output from MODFLOW simulations. Numerical tests check the applicability of the novel method in mapping regional-scale super-diffusive transport conditioned on local properties of multidimensional heterogeneous media.


Subject(s)
Groundwater , Models, Theoretical , Water Movements , Water Pollutants, Chemical , Computer Simulation , Diffusion
6.
Nature ; 505(7483): 391-4, 2014 Jan 16.
Article in English | MEDLINE | ID: mdl-24429636

ABSTRACT

Measured rates of river incision into bedrock are commonly interpreted as proxies for rates of rock uplift (see refs 1 and 2, for example) and indices of the strength of climatic forcing of erosion over time (see refs 3 and 4, for example). This approach implicitly assumes that river incision rates are in equilibrium with external forcings over a wide range of timescales. Here we directly test this assumption by examining the temporal scaling of bedrock river incision from 155 independent measurements of river incision compiled from 14 sites. Of these sites, 11 exhibit a negative power-law dependence of bedrock river incision rate on measurement interval, a relationship that is apparent over timescales of 10(4)-10(7) years and is independent of tectonic and geomorphic setting. Thus, like rates of sediment accumulation, rates of river incision into bedrock exhibit non-steady-state behaviour even over very long measurement intervals. Non-steady-state behaviour can be explained by episodic hiatuses in river incision triggered by alluvial deposition, if such hiatuses have a heavy-tailed length distribution. Regardless of its cause, the dependence of incision rate on measurement interval complicates efforts to infer tectonic or climatic forcing from changes in rates of river incision over time or from comparison of rates computed over different timescales.

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