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1.
Nanomaterials (Basel) ; 12(12)2022 Jun 10.
Article in English | MEDLINE | ID: mdl-35745331

ABSTRACT

Space exploration missions are currently becoming more frequent, due to the ambition for space colonization in sight of strengthening terrestrial technologies and extracting new raw materials and/or resources. In this field, the study of the materials' behaviour when exposed to space conditions is fundamental for enabling the use of currently existing materials or the development of new materials suitable for application in extra-terrestrial environments. In particular, the versatility of polymers renders them suitable for advanced applications, but the effects of space radiation on these materials are not yet fully understood. Here, to shed light on the effects of simulated solar wind on a polymeric material, polymethyl methacrylate (PMMA) was produced through radical bulk polymerization. The PMMA in the form of a thin film was subjected to proton beam bombardment at different fluences and in a high vacuum environment, with structural changes monitored through real-time FT-IR analysis. The structure of the residual material was investigated through MALDI-TOF mass spectrometry and 1H-NMR spectroscopy. The collected data allowed us to hypothesize the structural modifications of the PMMA and the related mechanisms.

2.
Phys Chem Chem Phys ; 19(32): 21759-21768, 2017 Aug 16.
Article in English | MEDLINE | ID: mdl-28782765

ABSTRACT

Laboratory experiments have shown that the energetic processing, i.e. ion bombardment and UV photolysis, of interstellar grain mantles and cometary surfaces is efficient in the production of formamide. To explain its presence in the gas-phase in these astrophysical environments, a desorption mechanism has to be taken into account. In this work we show experimental results on the thermal evolution of formamide when deposited at 17 K as pure and in mixture with water or carbon monoxide. In these samples, we observed formamide desorption at 220 K. Moreover, we discuss its synthesis in a mixture containing molecular nitrogen, methane and water (N2:CH4:H2O) deposited at 17 K and bombarded with 200 keV H+. Heating the sample, we observed that the newly formed formamide remains trapped in the refractory residue produced after the ion bombardment up to 296 K. To analyse the samples we used Fourier transform-infrared spectroscopy (FT-IR) that allowed us to study the infrared spectra between the deposition and the complete desorption of formamide. Here we discuss the experimental results in view of their astrophysical relevance.

3.
Rev Sci Instrum ; 84(3): 033503, 2013 Mar.
Article in English | MEDLINE | ID: mdl-23556817

ABSTRACT

A semiconductor detector coupled with a neutron converter is a good candidate for neutron detection, especially for its compactness and reliability if compared with other devices, such as (3)He tubes, even though its intrinsic efficiency is rather lower. In this paper we show a neutron detector design consisting of a 3 cm × 3 cm silicon pad detector coupled with one or two external (6)LiF layers, enriched in (6)Li at 95%, placed in contact with the Si active surfaces. This prototype, first characterized and tested at INFN Laboratori Nazionali del Sud and then at JRC Ispra, was successfully shown to detect thermal neutrons with the expected efficiency and an outstanding gamma rejection capability.

4.
Rev Sci Instrum ; 81(9): 093503, 2010 Sep.
Article in English | MEDLINE | ID: mdl-20886978

ABSTRACT

We propose a technique for thermal neutron detection, based on a (6)Li converter placed in front of scintillating fibers readout by means of silicon photomultipliers. Such a technique allows building cheap and compact detectors and dosimeters, thus possibly opening new perspectives in terms of granular monitoring of neutron fluxes as well as space-resolved neutron detection.

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