Synthesis and characterization Agar/GO/ZnO NPs nanocomposite for removal of methylene blue and methyl orange as azo dyes from food industrial effluents.

Herein, with using graphene oxide (GO), agar and ZnO NPs was synthesized as nanocomposite to removal of dyes contaminants from food industry effluents. Synthesis and characterization of the nanocomposite adsorbent were carried out by FTIR, XRD, FE-SEM, TEM, EDX and DLS analyses. The effects of various parameters such as pH, initial dye concentration, contact time and temperature on the removal of methylene blue (MB) and methyl orange (MO) as azo dyes were investigated. The used nanocomposite can be effective in the adsorption of dyes due to their different functional groups. The Freundlich and Langmuir models were used to investigate the isotherm of contaminants removal. The results showed that the removal of methylene blue and methyl orange dyes followed the Freundlich isotherm, and the values of the R2 correlation coefficient for agar/GO, and agar/GO/ZnO nanocomposites for MB dye was 0.9640 and 0.9977, respectively, and for dye MO, 0.9918 and 0.9683, respectively. The maximum removal percentages for MB and MO dyes were 88% and 91%, respectively.

Removal of pharmaceuticals (diclofenac and amoxicillin) by maltodextrin/reduced graphene and maltodextrin/reduced graphene/copper oxide nanocomposites.

Due to the scarcity of water and the growing industrialization, pharmaceutical wastewater treatment is of particular importance. For this reason, it is necessary to achieve an efficient method to eliminate all types of pharmaceutical pollutants. Herein, synthetic nano-composite is proposed to take a step towards improving the operation of removing pharmaceutical contaminants from the environment and aquatic and industrial effluents. Binary (maltodextrin/reconstituted graphene nanocomposite) and ternary (maltodextrin/reconstituted graphene nanocomposite/copper oxide) nanocomposites were prepared and characterized using, FT-IR, FESEM-EDS, TEM, DLS, and XRD. The nanocomposites were used to eliminate diclofenac and amoxicillin as Pharmaceuticals. The removal of amoxicillin at a concentration of 30 mg/L with an adsorbent dose of 0.05 g and a pH of 7.4 and an optimal temperature of 20 °C in 10 min has the highest removal rate of 86%. In addition, diclofenac with nano-adsorbents prepared under optimal conditions, including an initial concentration of 20 mg/L, adsorbent dose of 0.05 g, adsorption time of 7 min, a temperature of 20 °C and a pH of 7, has the highest removal efficiency of 94%. The results indicated that the prepared nanocomposites are alternative adsorbents to remove Pharmaceuticals from water.

Domino ring opening/cyclization of oxiranes for synthesis of functionalized 2H-pyran-5-carboxylate.

A simple method for the synthesis of functionalized 2H-pyrans via a catalytic reaction of an oxirane, an alkyne, and a malonate has been developed in which a 6-exo-dig cyclization pathway is observed. In this transformation, the attack of in situ generated copper acetylides on oxiranes formed homopropargylic alcohol intermediates which further transferred to 2H-pyrans with the help of malonates.

Synthesis and characterization of polyethylene glycol mediated silver nanoparticles by the green method.

The roles of green chemistry in nanotechnology and nanoscience fields are very significant in the synthesis of diverse nanomaterials. Herein, we report a green chemistry method for synthesized colloidal silver nanoparticles (Ag NPs) in polymeric media. The colloidal Ag NPs were synthesized in an aqueous solution using silver nitrate, polyethylene glycol (PEG), and ß-D-glucose as a silver precursor, stabilizer, and reducing agent, respectively. The properties of synthesized colloidal Ag NPs were studied at different reaction times. The ultraviolet-visible spectra were in excellent agreement with the obtained nanostructure studies performed by transmission electron microscopy (TEM) and their size distributions. The Ag NPs were characterized by utilizing X-ray diffraction (XRD), zeta potential measurements and Fourier transform infrared (FT-IR). The use of green chemistry reagents, such as glucose, provides green and economic features to this work.

Investigation of the inclusion complex of ß-cyclodextrin with mycophenolate mofetil.

The acid-base equilibrium of mycophenolate mofetil is studied in the absence and presence of ß-cyclodextrin (ß-CD). The conditional acidity constants are obtained by rank annihilation factor analysis (RAFA) as a function of ß-CD concentrations. Also the stability constants for inclusion complexes of ß-CD with both acidic and basic forms are calculated. The conditional acidity constant decreases by increasing ß-CD concentration. The calculated stability constants show that the acidic form of mycophenolate mofetil forms more stable inclusion complex (552±7 M(-1)) than its basic anionic form (158±2 M(-1)).

Effect of inclusion complex on nitrous acid reaction with flavonoids.

The kinetic of the nitrous acid reactions with quercetin and catechin has been studied using spectrophotometric method in aqueous solution. The results show that these antioxidants participate in oxidation reactions with nitrous acid which is derived from protonation of nitrite ion in mild acidic conditions. Corresponding o-quinones as relatively stable products were detected by spectrophotometric techniques. pH dependence of the reactions has been examined and the rate constants of reactions were obtained by non-linear fitting of kinetic profiles. The effect of ß-cyclodextrin on the oxidation pathway was another object of this study. It is shown that ß-cyclodextrin has an inhibitory effect on the oxidation reaction. The rate constants of oxidation reactions for complexed forms and their stability constants were obtained based on changes in the reaction rates as a function of ß-cyclodextrin concentration.

Synthesis of silver/montmorillonite nanocomposites using γ-irradiation.

Silver nanoparticles (Ag-NPs) were synthesized into the interlamellar space of montmorillonite (MMT) by using the γ-irradiation technique in the absence of any reducing agent or heat treatment. Silver nitrate and γ-irradiation were used as the silver precursor and physical reducing agent in MMT as a solid support. The MMT was suspended in the aqueous AgNO(3) solution, and after the absorption of silver ions, Ag(+) was reduced using the γ-irradiation technique. The properties of Ag/MMT nanocomposites and the diameters of Ag-NPs were studied as a function of γ-irradiation doses. The interlamellar space limited particle growth (d-spacing [d(s)] = 1.24-1.42 nm); powder X-ray diffraction and transmission electron microscopy (TEM) measurements showed the production of face-centered cubic Ag-NPs with a mean diameter of about 21.57-30.63 nm. Scanning electron microscopy images indicated that there were structure changes between the initial MMT and Ag/MMT nanocomposites under the increased doses of γ-irradiation. Furthermore, energy dispersive X-ray fluorescence spectra for the MMT and Ag/ MMT nanocomposites confirmed the presence of elemental compounds in MMT and Ag-NPs. The results from ultraviolet-visible spectroscopy and TEM demonstrated that increasing the γ-irradiation dose enhanced the concentration of Ag-NPs. In addition, the particle size of the Ag-NPs gradually increased from 1 to 20 kGy. When the γ-irradiation dose increased from 20 to 40 kGy, the particle diameters decreased suddenly as a result of the induced fragmentation of Ag-NPs. Thus, Fourier transform infrared spectroscopy suggested that the interactions between Ag-NPs with the surface of MMT were weak due to the presence of van der Waals interactions. The synthesized Ag/MMT suspension was found to be stable over a long period of time (ie, more than 3 months) without any sign of precipitation.