Desalinating a real hyper-saline pre-treated produced water via direct-heat vacuum membrane distillation.

Membrane distillation (MD) is an emerging thermal desalination technology capable of desalinating waters of any salinity. During typical MD processes, the saline feedwater is heated and acts as the thermal energy carrier; however, temperature polarization (as well as thermal energy loss) contributes to low distillate fluxes, low single-pass water recovery and poor thermal efficiency. An alternative approach is to integrate an extra thermal energy carrier as part of the membrane and/or module assembly, which can channel externally provided heat directly to the membrane-feedwater interface and/or along the feed channel length. This direct-heat delivery has been demonstrated to increase single-pass water recovery and enhance the overall thermal efficiency. We developed a bench-scale direct-heated vacuum MD (DHVMD) process to desalinate pre-treated oil and gas "produced water" with an initial total dissolved solids of 115,500 ppm at a feed temperature ranging between 24 and 32 °C. We evaluated both water flux and specific energy consumption (SEC) as a function of water recovery. The system achieved a 50% water recovery without significant scaling, with an average flux >6 kg m-2 hr-1 and a SEC as low as 2,530 kJ kg-1. The major species of mineral scales (i.e., NaCl, CaSO4, and SrSO4) that limited the water recovery to 68% were modeled in terms of thermodynamics and identified by scanning electron microscopy and energy-dispersive X-ray spectroscopy. In addition, we further developed and employed a physics-based process model to estimate temperature, salinity, water transport and energy flows for full-scale vacuum MD and DHVMD modules. Model results show that a direct-heat input rate of 3,600 W can increase single-pass water recovery from 2.1% to 3.1% while lowering the thermal SEC from 7,800 kJ kg-1 to 6,517 kJ kg-1 in an unoptimized module. Finally, the scaling up potential of DHVMD process is briefly discussed.

Capillary-Driven Rise of Well-Wetting Liquid on the Outer Surface of Cylindrical Nozzles.

Well-wetting liquids exiting small-diameter nozzles in the dripping regime can partially rise up along the outer nozzle surfaces. This is problematic for fuel injectors and other devices such as direct-contact heat and mass exchangers that incorporate arrays of nozzles to distribute liquids. We report our experimental and numerical study of the rising phenomenon for wide ranges of parameters. Our study shows that the interplay of three dimensionless numbers (the Bond number, the Weber number, and the Ohnesorge number) governs the capillary-driven rise dynamics. In general, as the flow rate or the viscosity increases, the capillary-driven rise height over each dripping period becomes smaller. We identify liquid flow rates below which the temporal evolution of the meniscus positions can be well approximated by a quasistatic model based on the Young-Laplace equation. Our analysis reveals two critical Bond numbers that give nozzle sizes, which correspond to the maximum meniscus rise and the onset of capillary-driven rise cessation. These critical Bond numbers are characterized as a function of the contact angle, regardless of the fluid type. Our study leads to a more efficient and optimized nozzle design in systems using wetting liquids by reducing both the risks of contamination and high pressure drop in such devices.