Potential re-use of sewage sludge as a raw material in the production of eco-friendly bricks.

Wastewater (sewage) treatment plants generate a high volume of sludge that, although it is classified as class II-A (not inert) non-hazardous waste, is commonly disposed of in sanitary landfills. Hence the environmental urge to assess its valorization possibilities. The present study describes the use of a sewage sludge as raw material in the production of red ceramic bricks by extrusion, focusing on the technological changes brought about by the presence of the sludge during the plastic forming process, in terms of the plasticity of the mixture and its subsequent extrudability. To quantitatively identify the best moisture conditions for the extrusion of high-quality products, shear strain amplitude sweep (torsional) tests were conducted on green (moist) prismatic samples produced with different moisture and sludge contents. For sewage sludge contents up to 10 wt%, the optimal moisture content was identified at 31-33 wt%. Higher water demand was identified for 15 wt% of sludge, for which optimal extrusion results required 35 wt% moisture. The total linear shrinkage after drying and firing, as well as the water absorption, were within the limits required for ceramic bricks for all the sludge contents. The results for compressive strength of the fired bricks also demonstrate that the incorporation of up to 15 wt% sewage sludge into the clay mixture is highly feasible for the production of extruded ceramic bricks.

Interpreting rheology and electrical conductivity: It all boils down to which particle size.

HYPOTHESIS: The electrical charges that develop on the surface of the ceramic particles upon contact with water, due to the interaction with ions in solution, result in a liquid-solid interface, which utterly modifies the properties of individual particles and the way they interact with each other to form a structure. This work explores a new approach to the relationships between structure and stability of suspensions. EXPERIMENTS: For this purpose, suspensions with a constant 0.35 volume fraction of α-alumina particles, neither spherical nor smooth, and controlled ionic strength (0-90 mM KCl) were prepared and characterized in terms of flow behaviour, electrical conductivity and particle's electrokinetic mobility. FINDINGS: Electrical conductivity (132 µS/cm < conductivity < 5730 µS/cm) and rheology measurements (10-2 Pa s < viscosity < 104 Pa s) were found to complement each other to produce a more accurate picture of the suspension's structure. Deviations of experimental data from well-accepted behavioural models were elucidated when the surface area equivalent particle size was used. With the electrical double layer thickness obtained from electrical conductivity measurements, this enabled the interpretation of the relationship between the suspension's viscosity and the particles electrical conductivity, which provides a criterion for the stability of concentrated colloidal suspensions.

Effect of quartz sand replacement by agate rejects in triaxial porcelain.

The ceramics industry, given the high volume of materials processed, stands as one of the largest consumers of natural raw materials but has also the capacity and potential to make significant contributions to solving environmental problems associated with other industries rejects. This work investigates the effects of quartz sand replacement by agate rejects (scrap) in a traditional triaxial porcelain composition. The study was carried out using the design of experiments (DoE) method. Characterization results were used to calculate statistically significant and valid regression equations, relating dried and fired body properties with clay, feldspar and agate scrap contents in the unfired mixture. The regression models were then discussed against X-ray diffraction and scanning electron microscopy results and used simultaneously to delimit the combinations of those three raw materials most adequate to produce a porcelainized stoneware floor tile with specified properties. Thus, an alternative use of an otherwise waste material is proposed, which can be translated into economic benefits and an important and welcome relief on environmental and waste disposal concerns.

Electrical conductivity and stability of concentrated aqueous alumina suspensions.

This work describes the effect of solids load and ionic strength on the electrical conductivity (K(S)) of concentrated aqueous suspensions of commercial alpha-alumina (1-35 vol% solids). The results obtained show that the dependency of the electrical conductivity of the suspending liquid (K(L)) on the volume fraction of solids is well described by Maxwell's model. The change in the conductivity of the suspensions relative to that of the suspending liquid (K(S)/K(L)) was found to be inversely proportional to the solids content, as predicted by Maxwell's model. The relative conductivity rate, DeltaK, could be interpreted in terms of the DLVO theory and the particles double layer parameter, kappaa, and used as a stability criterion. As kappaa changes, in response to the changes in ionic strength, so does the conducting to insulating character of the particles and, as such, their contribution to the overall suspension conductivity (expressed by DeltaK). When the particles become insulating, the suspension conductivity decreases when the solids load increases. The turning point in this particle behaviour corresponds to a critical concentration of ions in the solution that destabilises the suspension and is associated with the critical coagulation concentration (ccc). It is the electrical double layer that ultimately determines the conducting or insulating character of the particles, and that character can be made to change, as required for suspension stability, and accessed by the relative conductivity rate.