New Heusler compounds in Ni-Mn-In and Ni-Mn-Sn alloys.

Rapidly quenched ternary Ni-Mn-T (T = In, Sn) alloys exhibit features associated with magnetic skyrmions, so that XRD, TEM, EDS, SAED and HREM investigations were carried out for structural characterization on the two alloy systems. In this paper, we report a new type of Mn-rich Heusler compound with a cubic unit cell, a = 0.9150 nm in Ni-Mn-In and a = 0.9051 nm in Ni-Mn-Sn, which coexist with a Ni-rich full-Heusler compound with defects, a = 0.6094 nm in Ni-Mn-In and a = 0.6034 nm in Ni-Mn-Sn. A further analysis of the experimental results reveals a close structural relationship between these two compounds.

Structural and magnetic properties of bulk Mn2PtSn.

Interplay between structural and magnetic order parameters is one of the key mechanisms of tuning properties of materials intended for device applications in spintronics. Here, using density functional calculations, we study combined effects of tetragonal distortion and non-collinear magnetic order in Mn2PtSn. We show that this material has two energetically close energy minimums corresponding to tetragonal lattice. In one of these phases, Mn2PtSn exhibits ferrimagnetic order with nearly fully compensated total magnetic moment, while in the other phase that corresponds to the lowest energy, a non-collinear magnetic arrangement emerges, with very large canting angle of the Mn local magnetic moments. The non-collinear alignment is explained through the interplay of exchange couplings between nearest and next nearest neighbor Mn atoms. Results are compared with those reported in recent literature, both experimental and theoretical.

Effect of Co substitution on the magnetic and electron-transport properties of Mn2PtSn.

The structural, magnetic and electron-transport properties of Mn(2)Pt(1-x)Co(x)Sn(x = 0, 0.3, 0.5, 0.7, 1) ribbons prepared by arc-melting and melt-spinning were investigated. The rapidly quenched alloys with x = 0 and 0.3 were found to crystallize in the inverse tetragonal structure, but the structure transformed into inverse cubic as x increased to 0.5. At room temperature, the samples are ferro or ferrimagnetic, and the Curie temperature increases by 225 K from 370 K for Mn(2)PtSn (x = 0) to 595 K for Mn(2)CoSn (x = 1). The measured anisotropy constants for the inverse-tetragonal alloys are on the order of 1 Merg cm(-3) at room temperature. The ribbons are moderately conducting with the room temperature resistivities being between 0.4 and 8.4 mΩ cm. Interestingly, the thermal coefficient of resistivity transforms from positive to negative and the magnetoresistance transforms from negative to positive as the value of x reaches 0.5.

Direct chemical synthesis of L1(0)-FePtAu nanoparticles with high coercivity.

We report a facile synthesis of hard magnetic L10-FePtAu nanoparticles by coreduction of Fe(acac)3, Pt(acac)2 (acac = acetylacetonate) and gold acetate in oleylamine. In the current reaction condition, NP sizes are controlled to be 5.5 to 11.0 nm by changing the amount of Au doping. When the Au composition in the NPs is higher than 14%, the hard magnetic NPs are directly obtained without any annealing. The highest coercivity of 12.15 kOe at room temperature could be achieved for the NPs with 32% Au doping, which is much higher than the coercivities reported by the previous studies on solution-synthesized FePt nanoparticles. The reported one-pot synthesis of L10-FePtAu NPs may help to build superstrong magnets for magnetic or data-storage applications.

Monodisperse MPt (M = Fe, Co, Ni, Cu, Zn) nanoparticles prepared from a facile oleylamine reduction of metal salts.

We report a simple, yet general, approach to monodisperse MPt (M = Fe, Co, Ni, Cu, Zn) nanoparticles (NPs) by coreduction of M(acac)2 and Pt(acac)2 (acac = acetylacetonate) with oleylamine at 300 °C. In the current reaction condition, oleylamine serves as the reducing agent, surfactant, and solvent. As an example, we describe in details the synthesis of 9.5 nm CoPt NPs with their compositions controlled from Co37Pt63 to Co69Pt31. These NPs show composition-dependent structural and magnetic properties. The unique oleylamine reduction process makes it possible to prepare MPt NPs with their physical properties and surface chemistry better rationalized for magnetic or catalytic applications.

Structural and magnetic transitions in cubic Mn3Ga.

The structural, magnetic and electron-transport properties of cubic Mn3Ga have been investigated. The alloys prepared by arc melting and melt-spinning show an antiferromagnetic spin order at room temperature but undergo coupled structural and magnetic phase transitions at 600 and 800 K. First-principles calculations show that the observed magnetic properties are consistent with that of a cubic Mn3Ga crystallizing in the disordered Cu3Au-type structure. The samples exhibit metallic electron transport with a resistance minimum near 30 K, followed by a logarithmic upturn below the minimum. The observed anomaly in the low-temperature resistivity has been discussed as a consequence of electron scattering at the low-lying excitations of the structurally disordered Mn3Ga lattice.

Exploring the structural complexity of intermetallic compounds by an adaptive genetic algorithm.

Solving the crystal structures of novel phases with nanoscale dimensions resulting from rapid quenching is difficult due to disorder and competing polymorphic phases. Advances in computer speed and algorithm sophistication have now made it feasible to predict the crystal structure of an unknown phase without any assumptions on the Bravais lattice type, atom basis, or unit cell dimensions, providing a novel approach to aid experiments in exploring complex materials with nanoscale grains. This approach is demonstrated by solving a long-standing puzzle in the complex crystal structures of the orthorhombic, rhombohedral, and hexagonal polymorphs close to the Zr2Co11 intermetallic compound. From our calculations, we identified the hard magnetic phase and the origin of high coercivity in this compound, thus guiding further development of these materials for use as high performance permanent magnets without rare-earth elements.

Hf-Co and Zr-Co alloys for rare-earth-free permanent magnets.

The structural and magnetic properties of nanostructured Co-rich transition-metal alloys, Co(100-x)TMx (TM = Hf, Zr and 10 ≤ x ≤ 18), were investigated. The alloys were prepared under non-equilibrium conditions using cluster-deposition and/or melt-spinning methods. The high-anisotropy HfCo7 and Zr2Co11 structures were formed for a rather broad composition region as compared to the equilibrium bulk phase diagrams, and exhibit high Curie temperatures of above 750 K. The composition, crystal structure, particle size, and easy-axis distribution were precisely controlled to achieve a substantial coercivity and magnetization in the nanostructured alloys. This translates into high energy products in the range of about 4.3-12.6 MGOe, which are comparable to those of alnico.

Permanent magnetism of intermetallic compounds between light and heavy transition-metal elements.

First-principle calculations are used to investigate the intrinsic magnetic properties of intermetallic alloys of the type XMn, where X is a 4d or 5d element and M is Fe or Co. Emphasis is on the hexagonal C14 Laves-phase 1:2 and 1:5 alloys, the latter crystallizing in the CaCu5 structure. These series are of interest in permanent magnetism from fundamental and practical viewpoints, respectively. In the former, the unit cells form a prototypical motif where a heavy atom with high spin-orbit coupling and magnetocrystalline anisotropy is surrounded by many somewhat smaller M atoms with high magnetization, and the latter are Laves-phase derivatives of renewed interest in permanent magnetism. Our DFT calculations predict magnetic moments, magnetizations and anisotropies, as well as formation energies. The results are analyzed across the 4d and 5d series, especially with respect to hybridization effects between 3d and 4d/5d bands.

One-pot synthesis of urchin-like FePd-Fe3O4 and their conversion into exchange-coupled L1(0)-FePd-Fe nanocomposite magnets.

We report a one-pot synthesis of urchin-like FePd-Fe3O4 nanocomposites, spherical clusters of FePd nanoparticles (NPs) with spikes of Fe3O4 nanorods (NRs), via controlled thermal decomposition of Fe(CO)5 and reduction of Pd(acac)2. The FePd NPs with sizes between 6 and 9 nm self-aggregate into 60 nm superparticles (SPs), and Fe3O4 NRs grow on the surface of these SPs. Reductive annealing at 500 °C converts the FePd-Fe3O4 into exchange-coupled nanocomposites L1(0)-FePd-Fe with their Hc tunable from 0.8 to 2.6 kOe and Ms controlled from 90 to 190 emu/g. The work provides a general approach to L1(0)-FePd-Fe nanocomposite magnets for understanding exchange coupling at the nanoscale. The concept may be extended to other magnetic nanocomposite systems and may help to build superstrong magnets for magnetic applications.

Experimental and theoretical studies of hydroxyl-induced magnetism in TiO nanoclusters.

A main challenge in understanding the defect ferromagnetism in dilute magnetic oxides is the direct experimental verification of the presence of a particular kind of defect and distinguishing its magnetic contributions from other defects. The magnetic effect of hydroxyls on TiO nanoclusters has been studied by measuring the evolution of the magnetic moment as a function of moisture exposure time, which increases the hydroxyl concentration. Our combined experiment and density-functional theory (DFT) calculations show that as dissociative water adsorption transforms oxygen vacancies into hydroxyls, the magnetic moment shows a significant increase. DFT calculations show that the magnetic moment created by hydroxyls arises from 3d orbitals of neighboring Ti sites predominantly from the top and second monolayers. The two nonequivalent hydroxyls contribute differently to the magnetic moment, which decreases as the separation of hydroxyls increases. This work illustrates the essential interplay among defect structure, local structural relaxation, charge redistribution, and magnetism. The microscopic differentiation and clarification of the specific roles of each kind of intrinsic defect is critical for the future applications of dilute magnetic oxides in spintronic or other multifunctional materials.

On the synthesis and physical properties of iron doped SnO2 nanoparticles.

The synthesis of iron doped tin oxide by pulsed laser pyrolysis is reported. The as obtained nanoparticles have a dominant SnO2 phase (as revealed by Wide Angle X-ray Scattering), with particles of the order of 10 nm. The doping with iron or iron oxide triggers magnetic properties as confirmed by SQUID experiments. EDX measurements supported the presence of Fe while Wide Angle X-ray Scattering failed to sense any iron or iron-oxide phase. It is concluded that Fe is well dispersed within the tin-oxide nanoparticles. The coercitive field has a complex dependence on the Fe/Sn content suggesting that the magnetization is not controlled solely by the amount of Fe dispersed within the nanoparticles.

Anomalous Hall effect and electron transport in ferromagnetic MnBi films.

The electron transport properties of highly c-axis oriented MnBi thin films of various thicknesses have been investigated. Samples are metallic but the low temperature resistivity shows an unusual T(3) dependence. Transverse Hall effect measurements show that both the ordinary and anomalous Hall coefficients decrease with decreasing temperature below 300 K, but the ordinary Hall coefficient (R(0)) undergoes a sign reversal around 105 K, where the magnetic anisotropy also changes sign. Analysis of the Hall data for various samples shows that the anomalous Hall coefficient (R(s)) exhibits a strong ρ(2) dependence, where ρ is the longitudinal resistivity.

Ferromagnetic resonance investigations on styrene-butadiene-styrene barium ferrite nanocomposites.

FMR measurements on barium ferrite nanoparticles (with an average length of about 13 nm) dispersed within a block copolymer (styrene-butadiene-styrene) are reported. Resonance spectra have been successfully simulated by a convolution of a Dysonian line and a Lorentzian line. The temperature dependence of FMR spectra in the so called in-the-plane and out-of the-plane configurations is reported. The angular dependence of FMR spectra at room temperature is analyzed in detail and simulated within simple thermodynamic model that takes into account the competition between shape and magnetocrystalline anisotropies. FMR data revealed that the local magnetic field acting on uncoupled electronic spin is dominated by the magnetocrystalline contribution, which eventually includes surface effects. The strong connection between FMR spectra and hysteresis loop is demonstrated.

Magnetic properties of barium ferrite dispersed within polystyrene-butadiene-styrene block copolymers.

Magnetic properties of nanocomposite materials obtained by dispersing barium ferrite nanoparticles within polystyrene-butadiene-styrene block copolymer, in the temperature range, 300 to 500 K are reported. The temperature dependence of the magnetization at saturation, averaged uniaxial magnetocrystalline anisotropy, and coercive field of thick films are analyzed. A "matrix effect" was noticed within the glass transition range of the hard component (polystyrene) of the polymeric matrix. The reported modifications of the magnetic properties were assigned to the competition between the magnetic and mechanical reorientation of nanoparticles within the polymeric matrix. Such modifications were not observed in barium ferrite dispersed in cement.

FePt nanocluster films for high-density magnetic recording.

High anisotropy L1(0) ordered FePt thin films are considered to have high potential for use as high areal density recording media, beyond 1 Tera bit/in2. In this paper, we review recent results on the synthesis and magnetic properties of L1(0) FePt nanocomposite films. Several fabrication methods have been developed to produce high-anisotropy FePt films: epitaxial and non-epitaxial growth of (001)-oriented FePt:X (X = Au, Ag, Cu, C, etc.) composite films that might be used for perpendicular media; monodispersed FePt nanocluster-assembled films grown with a gas-aggregation technique and having uniform cluster size and narrow size distribution; self-assembled FePt particles prepared with chemical synthesis by reduction/decomposition techniques, etc. The magnetic properties are controllable through variations in the nanocluster properties and nanostructure. FePt and related films show promise for development as heat-assisted magnetic recording media at extremely high areal densities. The self-assembled FePt arrays show potential for approaching the ultimate goal of single-grain-per-bit patterned media.

Magnetic and structural properties of electrochemically self-assembled Fe1-xCox nanowires.

Fe1-xCox (0 < or = x < or = 1) nanowires have been self-assembled by electrodeposition in porous alumina films. The crystal structure is bee at the Fe end. With increased addition of Co, the crystal structure remains bcc until about 67% addition of Co. At the Co end, the structure is a mixture of hcp and fcc. Magnetic studies show very high coercivities for the Fe-Co alloys in the bcc phase. For Fe0.67Co0.33 nanowires of diameter 9 nm, the coercivity is about 2900 Oe, whereas for Fe0.33Co0.67 nanowires, it is about 2850 Oe. Temperature and size dependence of magnetic properties show no indication of superparamagnetic effects down to wire diameters of 9 nm.