Effect of graphene oxide on the uptake, translocation and toxicity of metal mixture to Lepidium sativum L. plants: Mitigation of metal phytotoxicity due to nanosorption.

Due to its unique structure and exceptional properties, graphene oxide (GO) is increasingly used in various fields of industry and therefore is inevitably released into the environment, where it interacts with different contaminants. However, the information relating to the ability of GO to affect the toxicity of contaminants is still limited. Therefore, the aim of our study was to synthesize GO, to examine the phytotoxicity of different concentrations of GO and its co-exposure with the metal mixture using garden cress (Lepidium sativum L.) as a test organism and to evaluate the potential of GO to affect toxicity of metals and their uptake by plants. The metal mixture (MIX) containing Ni (II), Zn (II), Cr (III) and Cu (II) was prepared in accordance with the maximum-permissible-concentrations (MPC) accepted for the inland waters in the EU. Additionally, the capacity of GO to adsorb metals was studied in specific conditions of the phytotoxicity test and assessed using adsorption isotherms. Our data indicate that in most cases the tested concentrations of MIX, GO and MIX + GO did not affect seed germination, root growth and biomass of roots and seedlings, however, they were found to alter photosynthesis processes, enhance production of carotenoids and H2O2 as well as to activate lipid peroxidation. Additionally, our study revealed that GO affects the accumulation of tested metals in roots and shoots of the MIX-exposed L. sativum. This is due to the capacity of GO to adsorb metals from the growth medium. Therefore, low concentrations of GO can be used for water decontamination.

Carbon and Pu isotopes in Baltic Sea sediments.

Distributions of 137Cs, 239,240Pu, Δ14C and δ13C measured in sediments indicated low 137Cs and 239,240Pu activities in the Curonian Lagoon and higher levels in the open Baltic Sea. Depleted δ13CTOC values were found in the Curonian Lagoon as compared with the open Baltic Sea, while the most depleted Δ14CTOC values were found in the Gotland Deep. The global fallout Pu dominated in the deeper zones of the Baltic Sea, while higher 240Pu/239Pu atom ratios were characteristic of the coastal regions.

Magnetic graphene oxide based nano-composites for removal of radionuclides and metals from contaminated solutions.

Magnetic graphene oxide based composites of the nano-particle size of <10 nm were synthesized, characterized and used in sorption experiments. The adsorption of Cs(I), Co(II), Ni(II), Cu(II) and Pb(II) to nano-composites was studied in a wide range of initial concentrations and analyzed by Langmuir and Freundlich models. In addition, the effects of pH and coexisting ions on the adsorption of Cs to Prussian blue based composites were investigated. The maximum adsorption capacities of studied elements varied from 29 to 641 mg g-1. The obtained Langmuir and Freundlich constants indicated the dominating physisorption mechanism and favorable adsorption conditions.

Transport of (137)Cs, (241)Am and Pu isotopes in the Curonian Lagoon and the Baltic Sea.

Activities of (137)Cs, (241)Am and (239,240)Pu were analyzed with special emphasis on better understanding of radionuclide transport from land via the Neman River estuaries to the Baltic Sea and behavior in the marine environment. Although activity concentrations of (137)Cs in water samples collected the Baltic Sea were almost 100 times higher as compared to the Curonian Lagoon, its activities in the bottom sediments were found to be comparable. Activity (238)Pu/(239,240)Pu and atom (240)Pu/(239)Pu ratios indicated a different contribution of the Chernobyl-originated Pu to the suspended particulate matter (SPM) and bottom sediments. The largest amount of the Chernobyl-derived Pu was found in the smallest suspended matter particles of 0.2-1 µm in size collected in the Klaipeda Strait in 2011-2012. The decrease of characteristic activity (238)Pu/(239,240)Pu and atom (240)Pu/(239)Pu ratios towards the global fallout ones in surface soil and the corresponding increase of plutonium (Pu) ratios in the suspended particulate matter and bottom sediments have indicated that the Chernobyl-derived Pu, primarily deposited on the soil surface, was washed out and transported to the Baltic Sea. Behavior of (241)Am was found to be similar to that of Pu isotopes.