Synthesis of porphyrinoids with silane anchors and their covalent self-assembling and metallation on solid surface.

We have synthesized a set of porphyrin and phthalocyanine compounds with two different silane anchors. Syntheses of the anchor-substituted chromophores have been carried out via hydrosilylation of alkene derivatives, catalyzed by platinum complexes. The reduction side-process was suppressed using specific anchor/catalyst pairs, and the silane-containing compounds were successfully isolated from hydrogenated by-products in pure form with good yields. The target porphyrinoids having stable reactive silane anchors possess the ability to self-assemble on metal oxides and quartz surfaces and optical fibers. Covalent attachment is done in one-step, which makes the bonding process fast and easy. Immobilized chromophores were further converted by on-surface reactions into Zn(II) and Mg(II) metal complexes. The metallation time was found to be as fast as 1 min for Zn ion. Bonding densities calculated from the absorbances of the deposited layers give rough estimations for packing of the molecules on various substrates and evidence for monomolecular layers formation.

Demonstration of a waveguide regime for a silica hollow--core microstructured optical fiber with a negative curvature of the core boundary in the spectral region > 3.5 µm.

We present a numerical and experimental demonstration of a waveguide regime in a broad band spectral range for the hollow core microstructured optical fibers (HC MOFs) made of silica with a negative curvature of the core boundary. It is shown that HC MOFs with the cladding consisting only of one row of silica capillaries allows to guide light from the near to mid infrared despite of high material losses of silica in this spectral region. Such result can be obtained by a special arrangement of cladding capillaries which leads to a change in the sign of the core boundary curvature. The change in the sign of the core boundary curvature leads to a loss of simplicity of boundary conditions for core modes and to "localization" and limitation of their interaction with the cladding material in space. Such HC MOFs made of different materials can be potential candidates for solving problem of ultra high power transmission including transmission of CO and CO2 laser radiation.

High-power photonic-bandgap fiber laser.

An original architecture of an active fiber allowing a nearly diffraction-limited beam to be produced is demonstrated. The active medium is a double-clad large-mode-area photonic-bandgap fiber consisting of a 10,000 ppm by weight Yb(3+)-doped core surrounded by an alternation of high- and low-index layers constituting a cylindrical photonic crystal. The periodic cladding allows the robust propagation of a approximately 200 microm(2) fundamental mode and efficiently discriminates against the high-order modes. The M(2) parameter was measured to be 1.17. A high-power cw laser was built exhibiting 80% slope efficiency above threshold. The robust propagation allows the fiber to be tightly bent. Weak incidence on the slope efficiency was observed with wounding radii as small as 6 cm.

Highly dispersive large mode area photonic bandgap fiber.

An all-silica photonic bandgap fiber composed of a low-index core surrounded by alternating high- and low-index rings allows us to achieve a large mode area (500 microm(2)) and large chromatic dispersion. Sharp resonances from the even Bragg mode to odd ring modes theoretically lead to 20,000 ps/(nm km) chromatic dispersion when large bends are applied. By nature, sharp resonances are sensitive to inhomogeneities along the fiber length. Under experimental conditions, the resonances are broadened and the dispersion coefficient is decreased to 1000 ps/(nm km). However, to the best of our knowledge, this is the largest dispersion coefficient reported using a large mode area fiber.

Arc-induced long-period gratings in aluminosilicate glass fibers.

Permanent long-period gratings were written using arc discharges in two aluminosilicate fibers, one of which was doped with erbium. Reversible gratings were also mechanically induced in both fibers. The thermal behavior of the arc-induced gratings was investigated at up to 1100 degrees C. It was found that the shift of the resonant wavelengths exhibited a well-defined linear dependence on temperature up to 700 degrees C.