ABSTRACT
Water hyacinth (WH) is an aquatic weed with an experimentally proven potential as a feedstock for bioethanol production. Unlike other bioethanol feedstocks, water hyacinth has no requirement for land use and resource consumption for cultivation. This study evaluates scaled-up bioethanol production process routes, modelled using the Aspen Plus process simulator to analyse the process performance of water hyacinth as a bioethanol feedstock. Four process scenarios are developed by combining two different feedstock pretreatment methods (i.e., alkali pretreatment and diluted acid pretreatment) and bioethanol dehydration techniques (i.e., azeotropic distillation and extractive distillation). Mass and energy flows of the four scenarios are comparatively analysed. Results show that the alkali pretreatment method provides a higher bioethanol yield (i.e., 254 L/tonne-WH) compared with the dilute acid pretreatment method (i.e., 210 L/tonne-WH). In addition, the process route combining alkali pretreatment and extractive dehydration techniques indicates the least process energy consumption of 45,310 MJ/m3 of bioethanol. The process energy flow analysis evaluates two energy sustainability indicators, i.e., net energy gain and renewability factor, with further interpretation of variation effects of the key process parameters through a sensitivity analysis. The feasible ways of utilising water hyacinth as a fuel-grade bioethanol feedstock for industrial-scale production are discussed. Supplementary Information: The online version contains supplementary material available at 10.1007/s13399-023-03891-w.
ABSTRACT
Membrane-based air separation (O2/N2) is of great importance owing to its energy efficiency as compared to conventional processes. Currently, dense polymeric membranes serve as the main pillar of industrial processes used for the generation of O2- and N2-enriched gas. However, conventional polymeric membranes often fail to meet the selectivity needs owing to the similarity in the effective diameters of O2 and N2 gases. Meanwhile, mixed-matrix membranes (MMMs) are convenient to produce high-performance membranes while keeping the advantages of polymeric materials. Here, we propose a novel MMM for O2/N2 separation, which is composed of Matrimid® 5218 (Matrimid) as the matrix, cobalt(II) phthalocyanine microparticles (CoPCMPs) as the filler, and Pluronic® F-127 (Pluronic) as the compatibilizer. By the incorporation of CoPCMPs to Matrimid, without Pluronic, interfacial defects were formed. Pluronic-treated CoPCMPs, on the other hand, enhanced O2 permeability and O2/N2 selectivity by 64% and 34%, respectively. We explain the enhancement achieved with the increase of both O2 diffusivity and O2/N2 solubility selectivity.
