Nitrogen removal mechanisms in biochar-amended sand filters treating onsite wastewater.

The performance of biochar-amended sand filters treating septic tank effluent (STE) was investigated in bench-scale columns. Softwood biochar showed higher NH4 + -N adsorption capacity (1.3 mg N g-1 ), and its water holding capacity (0.57 g ml-1 ) was significantly higher than sand (0.26 g ml-1 ). Two biochar amendment ratios (10% and 30%) were selected for STE treatment in short-term (20 days) and long-term (8 months) studies. During the short-term experiment, the overall total nitrogen removal efficiency was greater in biochar-amended sand columns (94.7%-95.6%) than in 100% sand columns (71.2%) due to the additional NH4 + -N adsorption by biochar. Greater nitrification performance was also observed in biochar-amended columns (87.1%-96.3%) than in 100% sand columns (61.4%) during long-term operation when alkalinity was insufficient. The nitrification performance in biochar-amended columns resumed more quickly (<7 days) after sufficient alkalinity was amended. The density of total biomass and nitrifying bacteria in biochar-amended columns (30%) were significantly higher at all experimental stages, suggesting biochar served as a growth media for enhanced biomass growth. The alkalinity changes and STE composition fluctuation had little impact on the nitrification performance of the 30% biochar-amended sand columns. In addition, biochar surface functional groups and zeta potential changed little after long-term STE filtration. Collectively, the results demonstrated proper biochar amendment ratio (30%) could enhance the nitrification performance of sand filters treating STE by increasing the system hydraulic retention time, providing additional alkalinity for nitrification, and serving as a growth media for enhanced biomass growth.

Potential release of legacy nitrogen from soil surrounding onsite wastewater leaching pools.

This study examined whether the accumulation of nitrogen (legacy nitrogen) within and surrounding leaching pools for onsite wastewater treatment may act as a source of nitrogen contamination to groundwater upon changes to the quantity and/or composition of the influent to the pool. In this study, one concrete leaching pool with neutral pH (A, pH 6.9) and one leaching pool after acid washing (B, pH 3.7) were selected to examine the quantity and composition of legacy nitrogen in the surrounding soil, as well as evaluate the potential release of this nitrogen under two environmentally relevant leaching scenarios: (i) the concrete leaching pool serves as the final discharge unit for aerobic treatment unit (ATU) effluent; (ii) extreme weather events (flash flood/heavy rains) act to increase the quantity and dilute the composition of flow to the pool. Core sample analysis showed that organic nitrogen accounts for the majority (97.3-99.7%) of the total nitrogen (TN) at site A (4.1 ±â€¯0.6 mg N/g soil) and site B (3.0 ±â€¯0.4 mg N/g soil); while ammonium was the major form of inorganic nitrogen present at the sites. The TN accumulated under the two leaching pools was equivalent to approximately 17-39 days of nitrogen loading to the system. pH had a significant impact on the mass of TN leached from the soil, while no significant difference in leached TN was observed for the two leaching scenarios. The amount of TN leached from the soil matrix was not affected by the flow rate (18.6 mL/d in scenario i vs. 547.2 mL/d in scenario ii) or flow pattern (intermittent dosing vs. continuous flow). The quantity of TN leached from soils in both scenario (i) and (ii) was low and accounted for 2.6-8.9% of the total nitrogen in the soil.