Occurrence characteristics and potential risk of microplastics under different land conditions.

Microplastics (MPs) pollution has caused widespread concern, more researchers have focused on MPs in farmland soil. However, the distribution of MPs in different land use types, land restoration years and crop types remained largely unexplored. Therefore, the study investigated the distribution characteristics and evaluated ecological risk of MPs in soil of northern Shaanxi Province, China. The abundance, particle size, morphology and polymer types of MPs in soil were analyzed by sample collection, Raman spectroscopy and laser direct infrared spectroscopy (LDIR). The ecological risk index (H) and pollution load index (PLI) were employed to assess the risks posed by MPs in the soil. It was shown that the concentration of MPs in farmland soil was the highest (4483 items·kg-1) among the different land use types. The average abundance of microplastics in farmland soil was 1.98 times than that in industrial park soil. An increase in restoration years corresponded with a decrease in MPs abundance and an increase in smaller-sized MPs. In addition, the content of MPs in the soil of perennial crops was more stable, with fluctuations less than 25%, and the size of MPs was smaller than that of the annual crops. The main types of MPs in the soil of the study area were PP (28.5%) and PET (24.1%), MPs with size between 20 and 40 µm were dominated. Based on the pollution load index (PLI), 51.9% of the sampling sites were categorized as moderately polluted, and the MPs pollution risk of farmland soil was the highest. Mild and moderate pollution caused fewer adverse impact, while extremely strong pollution was detrimental to ecosystems and human health. In general, the study would provide a foundational understanding of MPs pollution levels and environment risk associated with different land use types, land restoration years and crop types.

Tire plastic and road-wear particles on Yujing Expressway in the restoration area of Mu Us Sandy Land: Occurrence characteristics and ecological risk screening.

Tire plastic and road-wear particles (TPR-WP) are a current research priority as one of the main environmental sources of microplastics. We selected a unique land use type - desert restoration area, collected soil and dust samples from the Yujing Expressway and its service areas, and analyzed TPR-WP abundance, type, size and morphology by laser direct infrared (LDIR). The abundance of TPR-WP in expressway dust (14,446.87 ± 10,234.24 n/kg) was higher than that in soil (7500 ± 3253.64 n/kg). Random forest model showed that the source of TPR-WP was highly correlated with economic factors and natural climate. Overall, the proportion of small and medium-sized TPR-WP in dust was higher than soil, more than half of the TPR-WP in dust were in 20 - 50 µm range. The proportion of small particle size TPR-WP increased with the rise of elevation. The pollution load index suggested that the survey region was generally at level I risk zone, while the ecological risk index indicated that the pollution level of expressway was III and IV, and the service area was IV. In general, the study was of great significance for clarifying the distribution and risk of TPR-WP in soil and dust of expressways and service areas.

Antibiotics and microplastics in manure and surrounding soil of farms in the Loess Plateau: Occurrence and correlation.

The wide use of animal manure in farmland operations is a source of soil nutrients. However, the return of manure affected antibiotics and microplastics in the soil, thus the potential ecological risks cannot be overlooked. This study investigated the distribution of different antibiotics and microplastics and their correlation. It was found that multiple classes of veterinary antibiotics and microplastics could be detected simultaneously in most manure and soil. In manure, the average concentration of tetracycline antibiotics was higher than fluoroquinolones and sulfonamides. A much lower concentration of antibiotics was found in the soil samples relative to manure. The abundance of microplastics ranged from 21,333 to 88,333 n/kg in manure, and the average abundance was 50,583 ± 24,318 n/kg. The average abundance was 3056 ± 1746 n/kg in the soil. It confirmed that applying organic fertilizer to agricultural soil and the application of plastic mulch in farmlands introduced microplastics. Moreover, microplastics were found to be significantly correlated with antibiotics (r = 0.698, p < 0.001). The correlation between microplastics and antibiotics in soil was significantly weaker than that in manure. Farms could be the hotspot for the co-spread of microplastics and antibiotics. These findings highlighted the co-occurrence of antibiotics and microplastics in agricultural environments.

Research progress of heavy metals in desert-visual analysis based on CiteSpace.

In this paper, Web of Science (a database) is used to retrieve related literature in the field of heavy metal pollution in desert. CiteSpace is used to make a quantitative and qualitative evaluation on the literature in the field on the basis of a brief analysis on the research status, research focus, and evolution process in the field. Through CiteSpace visual analysis, a comparative analysis is given on related literature in terms of annual number of published papers, author groups, and their countries and regions, journals, publishing institutions, highly cited papers, research focuses, and burst terms, so as to explore the research status and future development trend of the field on a global scale. The results are shown as follows: (1) The literature in the field was originally published in 2000; the number of published papers increased steadily. The literature was mostly published on high-quality journals, the USA topped in terms of the number of published papers, and the research results achieved by developed countries had a greater influence. Chinese Acad Sci topped with the highest centrality and most published papers, which have made outstanding contributions to the field and occupy a leading position in the field. However, the fact is that there lacks communication and cooperation among research institutions. The most influential journal is Science of the Total Environment. (2) The hot research words in the field are as follows: heavy metal, soil, pollution, lead, desert, cadmium, and microelement. (3) In the field, burst terms have transformed from atmospheric deposition, biomonitoring, and phytoremediation to trace element, stream sediment, street dust, and water quality, and finally transformed to river and sediment. New words keep emerging in the research, and more and more attention is paid to the issue of heavy metal pollution in river sediment, which will be a future research hotspot in the field.

[Influencing Factors of Ozone Concentration in Xi'an Based on Generalized Additive Models].

Based on the ozone monitoring data from 2014 to 2018, we presented the variation of ozone concentration in Xi'an and revealed the effects of ozone concentration by meteorological factors based on the generalized additive model (GAM). The results showed that ① with increasing ozone concentration year by year, the assessment standard of ozone pollution was overtaken by three consecutive years since 2016. However, the rising trend was slowed down since 2017 as a result of the strengthened pollution control during summer. ② The monthly curve of ozone concentration was presented as a reversed "V" model with a rising trend accompanying the rising temperature from January to July and a decreasing one during the rest of the year, peaking in July in terms of average monthly ozone concentration. However, this model would turn into an "M" in years with high precipitation when the valley witnessed the highest precipitation in a month. ③ The ozone pollution increased from the year 2014 to 2018 with a stretch-forward ozone polluted time. Furthermore, the rates of ozone non-attainment increased from 1.9% in 2014 to 14% in 2018. In addition, the time ozone pollution emerged advanced from July to May. ④ Based on the GAM model, ozone concentration was non-colinearly related to temperature, air pressure, sunshine duration, and relative humidity. However, the curves of these factors varied considerably, with a positive influence of temperature and sunshine duration and a negative influence of air pressure and relative humidity. The influence of precipitation was mainly witnessed in summers, while no influence of wind was observed. Furthermore, ozone pollution can be easily triggered under the following conditions:temperature>24℃, air pressure <962 hPa, sunshine duration>9 h, and a relative humidity 36%-65% with no rain.

Content of Heavy Metal in the Dust of Leisure Squares and Its Health Risk Assessment-A Case Study of Yanta District in Xi'an.

Taking Yanta District in Xi'an as the research object, the present study measures the contents of Cadmium (Cd), Lead (Pb), Copper (Cu), Nickel (Ni), and Chromium (Cr) in dust samples and further assesses the health risk of heavy metals intake through dust based on the assessment method of human exposure risk proposed by U.S. EPA, with an aim to investigate the content of heavy metal in the dust of leisure squares and its exposure risk. As the results indicate, the average contents of five heavy metals are obviously higher than the soil background value in Shaanxi Province. Therefore, Cd, Ni, Cu, Pb, and Cr are obviously enriched in urban surface dust in Shaanxi Province, due to the influence of human activities. In addition, it can also be found that the non-carcinogen exposure risk in children is significantly higher than that in adults with the risk values of these five heavy metals all one order of magnitude higher than those of adults. Irrespective of whether addressing the results for children or adults, the non-carcinogen exposure doses of five heavy metals are sorted as Cr > Pb > Cu > Ni > Cd. According to the present situation, for a child, the total non-carcinogenic risk values of five heavy metals have exceeded the safety limit in 11 of the 20 leisure squares in Yanta District of Xi'an. That means the leisure squares are no longer suitable for physical and recreational activities. For the five heavy metals, the average non-carcinogenic risk value of Cr is largest, and causes the largest threat to health in Yanta District, Xi'an. The carcinogenic exposure doses of the heavy metals Cr, Cd, and Ni are very low in respiratory pathways and there is no carcinogenic health risk. In general, the Cr content in dust in domestic cities is higher than that of foreign cities; however, the Pb content is much lower.

[Study on the change of dune CO2 concentration in the autumn at Minqin in Tengger desert].

In order to find out the CO2 concentration of the desert area, the influence of it on the CO2 in the atmosphere and the role that it played on the global carbon cycle, the research team utilized in September 2009 infrared CO2 monitor to observe the CO2 concentration of the 12 drill holes day and night in Minqin desert area in the Tengger desert. The difference of various observation spots' CO2 concentration of the desert area in the Tengger desert area is relatively big. The CO2 concentration at night is low but high in the daytime and the CO2 concentration at each observation spot changes from 310 x 10(-6) to 2 630 x 10(-6). The CO2 concentration is also obviously different in depth and the CO2 concentration at different depths in order of size is as follows: 4 m(3m) > 2 m > 1m. Compared with Xi' an area where is in the temperate and semi-humid region, the CO2 concentration of the desert area in Tengger desert is very low. The diurnal variation of CO2 concentration of the desert area in Tengger desert is obvious, and from the day 09:00 am to 09:00 am the next day, the CO2 concentrations at different depths which rang from 1 m to 4 m present the regularity that it changes from low to high, and then from high to low. The diurnal variation in temperature is the main reason that causes the change of the CO2 concentration in the sand layer, both of which have the positive correlation. The sand layer's CO2 concentration with higher water content is obviously higher than that with lower water content. The moisture content of sand layer is the main factor of the CO2 concentration. The CO2 concentration above 4m in the desert area is higher than that above the surface, which maybe indicates that the CO2 from the highest desert area is also the resource of CO2 in the atmosphere.