Small molecular donor materials based on ß-ß-bridged BODIPY dimers with a triphenylamine or carbazole unit for efficient organic solar cells.

Herein, we have designed and synthesized two novel BODIPY dimer-based small molecules, denoted as ZMH-1 and ZMH-2, covalently linked and functionalized with triphenylamine (TPA) (ZMH-1) and carbazole (CZ) (ZMH-2) units as the electron donor at the 3- and 5-positions of the BODIPY core, respectively. Their optical and electrochemical properties were investigated. We have fabricated all small molecule bulk heterojunction organic solar cells using these BODIPY-based small molecules as electron donors along with fullerene derivative (PC71BM) and medium bandgap non-fullerene acceptor IDT-TC as electron acceptors. The optimized OSCs based on ZMH-1:PC71BM, ZMH-2:PC71BM, ZMH-1:IDT-IC, and ZMH-2:IDT-IC attain overall PCEs of 8.91%, 6.61%, 11.28%, and 5.48%, respectively. Moreover, when a small amount of PC71BM as guest acceptor is added to the binary host ZMH-1:IDT-TC and ZMH-2:IDT-TC, the ternary OSCs based on ZMH-1 and ZMH-2 reach PCEs of 13.70% and 12.71%, respectively.

An Asymmetric Coumarin-Anthracene Conjugate as Efficient Fullerene-Free Acceptor for Organic Solar Cells.

Asymmetric wide-band gap fullerene-free acceptors (FFAs) play a crucial role in organic solar cells (OSCs). Here, we designed and synthesized a simple asymmetric coumarin-anthracene conjugate named CA-CN with optical band gap of 2.1 eV in a single-step condensation reaction. Single crystal X-ray structure analysis confirms various multiple intermolecular non-covalent interactions. The molecular orbital energy levels of CA-CN estimated from cyclic voltammetry were found to be suitable for its use as an acceptor for OSCs. Binary OSCs fabricated using CA-CN as acceptor and PTB7-Th as the donor achieve a power conversion efficiency (PCE) of 11.13 %. We further demonstrate that the insertion of 20 wt % of CA-CN as a third component in ternary OSCs with PTB7-Th : DICTF as the host material achieved an impressive PCE of 14.91 %, an improvement of ~43 % compared to the PTB7-Th : DICTF binary device (10.38 %). Importantly, the ternary blend enhances the absorption coverage from 400 to 800 nm and improves the morphology of the active layer. The findings highlight the efficacy of an asymmetric design approach for FFAs, which paves the way for developing high-efficiency OSCs at low cost.

Hybrid manifold smoothing and label propagation technique for Kannada handwritten character recognition.

Handwritten character recognition is one of the classical problems in the field of image classification. Supervised learning techniques using deep learning models are highly effective in their application to handwritten character recognition. However, they require a large dataset of labeled samples to achieve good accuracies. Recent supervised learning techniques for Kannada handwritten character recognition have state of the art accuracy and perform well over a large range of input variations. In this work, a framework is proposed for the Kannada language that incorporates techniques from semi-supervised learning. The framework uses features extracted from a convolutional neural network backbone and uses regularization to improve the trained features and label propagation to classify previously unseen characters. The episodic learning framework is used to validate the framework. Twenty-four classes are used for pre-training, 12 classes are used for testing and 11 classes are used for validation. Fine-tuning is tested using one example per unseen class and five examples per unseen class. Through experimentation the components of the network are implemented in Python using the Pytorch library. It is shown that the accuracy obtained 99.13% make this framework competitive with the currently available supervised learning counterparts, despite the large reduction in the number of labeled samples available for the novel classes.

In silico guided screening of active components of C. lanceolata as 3-chymotrypsin-like protease inhibitors of novel coronavirus.

Despite the intense worldwide efforts towards the identification of potential anti-CoV therapeutics, no antiviral drugs have yet been discovered. Numerous vaccines are now approved for use, but they all serve as preventative measures. To effectively treat viral infections, it is crucial to find new antiviral drugs that are derived from natural sources. Various compounds with potential activity against 3 chymotrypsin-like protease (3CLpro) were reported and some are validated by bioassay studies. Therefore, we performed the computational screening of phytoconstituents of Codonopsis lanceolata to search for potential antiviral hit candidates. The curated compounds of the plant C. lanceolata were collected and downloaded from the literature. The binding affinity of the curated datasets was predicted for the target 3CLpro. Stigmasterol exhibits the highest docking score for the 3CLpro target. In addition, molecular dynamics (MD) simulations were conducted for the validation of docking results using root mean square deviation and root mean square fluctuation plots. The MD results indicated that the docked complex was stable and retained hydrogen bonding and non-bonding interactions. Furthermore, the calculation of pharmacokinetic parameters and Lipinski's rule of five suggest that C. lanceolata has the potential for drug-likeness. In order to develop new medicines for this debilitating disease, we will focus on the primary virus-based and host-based targets that can direct medicinal chemists to identify novel treatments to produce new drugs for it. Supplementary Information: The online version contains supplementary material available at 10.1007/s13205-023-03745-2.

Directed Message Passing Neural Network for Predicting Power Conversion Efficiency in Organic Solar Cells.

Organic solar cells (OSCs) have emerged as a promising technology for renewable energy generation, and researchers are constantly exploring ways to improve their efficiency. For prediction of photovoltaic properties in OSCs, many machine learning models have been used in the past. All the models are used with fixed molecular descriptors and molecular fingerprints as input for power conversion efficiency (PCE) prediction. Recently, the graph neural network (GNN), which can model graph structures of the molecule, has received increasing attention as a method that could potentially overcome the limitations of fixed descriptors by learning the task-specific representations using graph convolutions. In this study, we have used the directed message passing neural network (D-MPNN), an emerging type of GNN for predicting PCE of organic solar cells, and the results are compared for the same train and test set with fixed descriptors and fingerprints. The excellent performance demonstrated by the D-MPNN model in this investigation highlights its potential for predicting PCE, surpassing the limitations of conventional fixed descriptors.

Effects of Halogenation on Cyclopentadithiophenevinylene-Based Acceptors with Excellent Responses in Binary Organic Solar Cells.

In recent years, non-fused non-fullerene acceptors (NFAs) have attracted increasing consideration due to several advantages, which include simple preparation, superior yield, and low cost. In the work reported here, we designed and synthesized three new NFAs with the same cyclopentadithiophenevinylene (CPDTV) trimer as the electron-donating unit and different terminal units (IC for FG10, IC-4F for FG8, and IC-4Cl for FG6). Both halogenated NFAs, i.e., FG6 and FG8, show red-shifted absorption spectra and higher electron mobilities (more pronounced for FG6) in comparison with FG10. Moreover, the dielectric constants of these materials also increased upon halogenation of the IC terminal units, thus leading to a reduction in the exciton binding energy, which is favorable for dissociation of excitons and subsequent charge transfer despite the driving force (highest occupied molecular orbital and lowest unoccupied molecular orbital offsets) being very small. The organic solar cells (OSCs) constructed using these acceptors and PBDB-T, as the donor, showed PCE values of 15.08, 12.56, and 9.04% for FG6, FG8, and FG10, respectively. The energy loss for the FG6-based device was the lowest (0.45 eV) of all the devices, and this may be attributed to it having the highest dielectric constant, which leads to a reduction in the binding energy of exciton and a small driving force for hole transfer from FG6 to PBDB-T. The results indicate that the NFA containing the CPDTV oligomer core and halogenated terminal units can efficiently spread the absorption spectrum to the NIR zone. Non-fused NFAs have a bright future in the quest to obtain efficient OSCs with low cost for marketable purposes.

Simple and Efficient Acceptor-Donor-Acceptor-Type Non-fullerene Acceptors for a BODIPY-Thiophene-Backboned Polymer Donor for High-Performance Indoor Photovoltaics.

Herein, simple acceptor-donor-acceptor (A-D-A)-type small molecules denoted as DICTF and DRCTF with modification in terminal units were synthesized and used as electron acceptors. With the tuning of the electron-withdrawing units in electron acceptors, their photovoltaic properties were investigated when combined with low-band-gap BODIPY-thiophene-backboned donor material, named P(BdP-HT). The P(BdP-HT):DICTF-based organic solar cells (OSCs) displayed excellent efficiency of around 11.94%, which is superior to the P(BdP-HT):DRCTF counterpart (8.78%). Although the open-circuit voltage (VOC) of the P(BdP-HT):DRCTF-based OSC is greater than that for the P(BdP-HT):DICTF counterpart, the rise in the short-circuit current density (JSC) may be attributed to the fact that the P(BdP-HT):DICTF blend displayed impressive panchromatic absorption compared to P(BdP-HT):DRCTF. The improved fill factor (FF) is responsible for the balanced transport of charges in the P(BdP-HT):DICTF-based device. Moreover, the P(BdP-HT):DRCTF- and P(BdP-HT):DICTF-based OSCs showed 17.68 and 21.84%, respectively, under indoor illumination (1000 lx). To the best of our observation, this might be the first report on BODIPY-based donors with power conversion efficiency (PCE) of 21.84% under indoor illumination conditions.

Harnessing the Structure-Performance Relationships in Designing Non-Fused Ring Acceptors for Organic Solar Cells.

The prerequisite for commercially viable organic solar cells (OSC) is to reduce the efficiency-stability-cost gap. Therefore, the cost of organic materials should be reduced by minimizing the synthetic steps, yet maintaining the molecular planarity and efficiencies achieved by the fused ring acceptors (FRA). In this respect, developing non-fused ring acceptors (NFRA) with suitable functionalization to favor conformational planarity and effective molecular packing is beneficial and cost-effective. Presently, the power conversion efficiency (PCE) for NFRAs is around 16 %, yet lower than the 19 % achieved for FRAs. Despite their potential, a thorough understanding of the effective structural design of NFRAs is necessary for developing efficient OSCs. This article pays special attention to the molecular design concept for NFRAs developed in the last years and analyzed the approach toward materials design and efficiency improvement, an important step toward technological application.

Medium Bandgap Nonfullerene Acceptor for Efficient Ternary Polymer Solar Cells with High Open-Circuit Voltage.

We have designed a new medium bandgap non-fullerene small-molecule acceptor consisting of an IDT donor core flanked with 2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]-thiophene-4-ylidene) malononitrile (TC) acceptor terminal groups (IDT-TC) and compared its optical and electrochemical properties with the IDT-IC acceptor. IDT-TC showed an absorption profile from 300 to 760 nm, and it has an optical bandgap of 1.65 eV and HOMO and LUMO energy levels of -5.55 and -3.83 eV, respectively. In contrast to IDT-IC, IDT-TC has an upshifted LUMO energy level, which is advantageous for achieving high open-circuit voltage. Moreover, IDT-TC showed higher crystallinity and high electron mobility than IDT-IC. Using a wide bandgap D-A copolymer P as the donor, we compared the photovoltaic performance of IDT-TC, IDT-IC, and IDT-IC-Cl nonfullerene acceptors (NFAs). Polymer solar cells (PSCs) using P: IDT-TC, P: IDT-IC, and P:IDT-IC-Cl active layers achieved a power conversion efficiency (PCE) of 14.26, 11.56, and 13.34%, respectively. As the absorption profiles of IDT-IC-Cl and IDT-TC are complementary to each other, we have incorporated IDT-TC as the guest acceptor in the P: IDT-IC-Cl active layer to fabricate the ternary (P:IDT-TC: IDT-IC-Cl) PSC, demonstrating a PCE of 16.44%, which is significantly higher than that of the binary BHJ devices. The improvement in PCE for ternary PSCs is attributed to the efficient exploitation of excitons via energy transfer from IDT-TC to IDT-IC-Cl, suitable nanoscale phase separation, compact stacking distance, and more evenly distributed charge transport.

Role of Exciton Lifetime, Energetic Offsets, and Disorder in Voltage Loss of Bulk Heterojunction Organic Solar Cells.

Recently, the power conversion efficiency (PCE) of organic solar cells (OSCs) has significantly progressed with a rapid increase from 10 to 19% due to state-of-the-art research on nonfullerene acceptor molecules and various device processing strategies. However, OSCs still exhibit significant open circuit voltage loss (ΔVOC ∼ 0.6 V) due to high energetic offsets and molecular disorder. In this work, we present a systematic investigation to determine the effects of energetic offset and disorder on different recombination losses in open circuit voltage (VOC) using 13 different photoactive layers, wherein the PCE and ΔVOC vary in the ranges of 2.21-14.74% and 0.561-1.443 V, respectively. The detailed voltage loss analysis of all these devices was carried out, and voltage losses were correlated with energetic offset and disorder. This has enabled us to identify the key features for minimizing the voltage loss like: (1) a low energy offset between the donor and acceptor molecular states is essential to attain a nonradiative voltage loss (ΔVOC, nrad) as low as ∼200 meV and (2) Urbach energy, which is a measure of the materials' disorder and packing, should be low for the minimization of the radiative voltage loss (ΔVOC, rad). In addition, time-resolved photoluminescence spectroscopy was employed to further understand the exciton dynamics of pristine materials and donor-acceptor blends. It was observed that the absorbers with ultralong exciton lifetime (∼1000 ps) produce higher efficiencies. The current study emphasizes the importance of simultaneously testing photovoltaic performance and active layer exciton dynamics for rational device optimization and opens new prospects for designing novel molecules with fine-tuning of energetic offset and disorder with longer exciton lifetime which is the effective strategy to boost the efficiency of OSCs to their modified Shockley-Queisser (SQ) limit by minimizing radiative and nonradiative voltage losses.

Active Discovery of Donor:Acceptor Combinations For Efficient Organic Solar Cells.

The structural flexibility of organic semiconductors offers vast a search space, and many potential candidates (donor and acceptor) for organic solar cells (OSCs) are yet to be discovered. Machine learning is extensively used for material discovery but performs poorly on extrapolation tasks with small training data sets. Active learning techniques can guide experimentalists to extrapolate and find the most promising D:A combination in a significantly small number of experiments. This study uses an active learning technique with a predictive random forest model to iteratively find the most optimal D:A combinations in the search space using various acquisition functions. Active learning results with five different acquisition functions (MM, MEI, MLI, MU, and UCB) are compared. Results reveal that acquisition functions that combine exploitation and exploration (MEI, MLI, and UCB) perform far better than purely exploiting (MM) and purely exploring (MU) acquisition functions. Interestingly, the proposed model can overcome the bottleneck of extrapolating small training data sets and find most promising D:A combinations in relatively fewer experiments.

The Burden of Cardiovascular Diseases Due to COVID-19 Pandemic.

The coronavirus disease 2019 (COVID-19) is an infection caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) that produces respiratory symptoms and has serious consequences for people's cardiovascular systems (CVS). It is a severe issue and a major task not only for health care experts but also for governments to contain this pandemic. SARS-CoV-2 is the seventh member of the human coronavirus family to be implicated in this zoonotic outbreak. COVID-19's CV interactions are comparable to those of SARS-CoV, Middle East respiratory syndrome (MERS-CoV), and influenza. Those who have COVID-19 and underlying cardiovascular diseases (CVDs) are at a higher risk of serious illness and mortality, and disease has been linked to several direct and indirect CV consequences. COVID-19 causes CVDs such as arrhythmias, cardiac arrest, cardiogenic shock, myocarditis, stress-cardiomyopathy, and acute myocardial damage (AMD) as a consequence of acute coronary syndrome. The provision of CV care may expose health care professionals to risk as they become hosts or vectors of viral transmission. It binds to the angiotensin-converting enzyme receptor, causing constitutional and pulmonary signs in the beginning, and then as the infection advances, it affects other organs such as the gastrointestinal tract, CVS, neurological system, and so on. COVID-19 mortality is increased by underlying CVDs comorbidities.

Efficient Medium Bandgap Electron Acceptor Based on Diketopyrrolopyrrole and Furan for Efficient Ternary Organic Solar Cells.

We report the design of novel medium bandgap nonfullerene small molecule acceptor NFSMA SPS-TDPP-2CNRh with A2-π-A1-π-A2 architecture, with the molecular engineering of this material comprising a strong electron-accepting backbone unit DPP (A1) as the acceptor, which is attached to the dicyanomethylene-3-hexylrhodanine (A2) acceptor via a furan (π-spacer) linker. We systematically studied its structural and optoelectronic properties. The incorporation of dicyanomethylene-3-hexylrhodanine and furan enhance the light absorption and electrochemical properties by extending π-conjugation and is anticipated to improve VOC by decreasing the LUMO level. The long alkyl chain units were responsible for the better solubility and aggregation of the resultant molecule. Binary BHJ-OSCs constructed with polymer P as the donor and SPS-TDPP-2CNRh as the acceptor resulted in a PCE of 11.49% with improved VOC = 0.98 V, JSC = 18.32 mA/cm2, and FF = 0.64 for P:SPS-TDPP-2CNRh organic solar cells. A ternary solar cell device was also made using Y18-DMO and SPS-TDPP-2CNRh as acceptors having complementary absorption profiles and polymer P as the donor, resulting in a PCE of 15.50% with improved JSC = 23.08 mA/cm2, FF = 0.73, and VOC = 0.92 V for the P:SPS-TDPP-2CNRh:Y18-DMO solar cell. The ternary OSCs with SPS-TDPP-2CNRh as the host acceptor in the P:Y18-DMO binary film were shown to have improved PCE values, which is mainly attributed to the effective photoinduced charge transfer through multiple networks and the use of excitons from SPS-TDPP-2CNRh and Y18-DMO. Moreover, in the ternary BHJ active layers, the superior stable charge transport that was observed compared to the binary counterparts may also lead to an increase in the fill factor. These results demonstrate that combining medium bandgap and narrow bandgap NFSMAs with a wide bandgap polymer donor is a successful route to increasing the overall PCE of the OSCs via the ternary BHJ concept.

Gold(III) Porphyrin Was Used as an Electron Acceptor for Efficient Organic Solar Cells.

The widespread use of nonfullerene-based electron-accepting materials has triggered a rapid increase in the performance of organic photovoltaic devices. However, the number of efficient acceptor compounds available is rather limited, which hinders the discovery of new, high-performing donor:acceptor combinations. Here, we present a new, efficient electron-accepting compound based on a hitherto unexplored family of well-known molecules: gold porphyrins. The electronic properties of our electron-accepting gold porphyrin, named VC10, were studied by UV-Vis spectroscopy and by cyclic voltammetry (CV) , revealing two intense optical absorption bands at 500-600 and 700-920 nm and an optical bandgap of 1.39 eV. Blending VC10 with PTB7-Th, a donor polymer, which gives rise to an absorption band at 550-780 nm complementary to that of VC10, enables the fabrication of organic solar cells (OSCs) featuring a power conversion efficiency of 9.24% and an energy loss of 0.52 eV. Hence, this work establishes a new approach in the search for efficient acceptor molecules for solar cells and new guidelines for future photovoltaic material design.

Novel Pyrrolo [3,4-b] Dithieno [3, 2-f:2″,3″-h] Quinoxaline-8,10 (9H)-Dione Based Wide Bandgap Conjugated Copolymers for Bulk Heterojunction Polymer Solar Cells.

Two D-A copolymers consisting of fused ring pyrrolo-dithieno-quinoxaline acceptors are synthesized with different donor units, i.e., benzodithiophene (BDT) with alkylthienyl (P134) and 2-ethylhexyloxy (P117) side chains. These copolymers are used as donors and a narrow bandgap acceptor Y6 to fabricate bulk heterojunction polymer solar cell devices. Owing to the strong electron-deficient fused ring pyrrolo-bithieno-quinoxaline and weak alkyl thienyl side chains in BDT, the polymer solar cells (PSCs) based on P134:Y6 attain the power conversion efficiency (PCE) of 15.42%, which is higher than the P117:Y6 counterpart (12.14%). The superior value of PCE for P134:Y6 can be associated with more well-adjusted charge transport, weak charge recombination, proficient exciton generation, and dissociation into free charge carriers and their subsequent charge collection owing to the dense π-π stacking distance and more considerable crystal coherence length for the P134:Y6 thin films. This investigation confirms the great potential of a strong acceptor-weak donor tactic for developing efficient D-A copolymers consists of quinoxaline acceptor for PSCs.

New Medium Bandgap Donor D-A1 -D-A2 Type Copolymers Based on Anthra[1,2-b: 4,3-b":6,7-c"'] Trithiophene-8,12-dione Groups for High-Efficient Non-Fullerene Polymer Solar Cells.

A new acceptor unit anthra[1,2-b: 4,3-b': 6,7-c'']trithiophene-8,12-dione (А3Т) (A2) is synthesized and used to design D-A1 -D-A2 medium bandgap donor copolymers with same thiophene (D) and A2 units but different A1, i.e., fluorinated benzothiadiazole (F-BTz) and benzothiadiazole (BTz) denoted as P130 and P131, respectively. Their detailed optical and electrochemical properties are examined. The copolymers show good solubility in common organic solvents, broad absorption in the visible spectral region from 300 to 700 nm, and deeper HOMO levels of -5.45 and -5.34 eV for P130 and P131, respectively. Finally, an optimized polymer solar cell (PSC) based on P131 as the donor and narrow bandgap non-fullerene small molecule acceptor Y6 demonstrated a power conversion efficiency (PCE) of >11.13%. To further improve the efficiency of the non-fullerene PSC, the P130 is optimized by introducing a fluorine atom into the BTz unit, F-BTz acceptor unit, and PCE PSC based on P130: Y6 active layer increased to >15.28%, which is higher than that for the non-fluorinated analog P131:Y6. The increase in the PCE for former PSC is attributed to the more crystalline nature and compact π-π stacking distance, leading to more balanced charge transport and reduced charge recombination. These remarkable results demonstrate that A3T-based copolymer P130 with F-BTz as the second acceptor is a promising donor material for high-performance PSCs.

Binary and Ternary Polymer Solar Cells Based on a Wide Bandgap D-A Copolymer Donor and Two Nonfullerene Acceptors with Complementary Absorption Spectral.

A new wide-bandgap conjugated D-A polymer denoted as P106 with a medium acceptor dithieno [2,3-e;3'2'-g]isoindole-7,9 (8H) (DTID) unit and strong 2-dodecylbenzo[1,2-b:3,4-b':6,5-b"]trithiophene (3TB) donor units shows an optical bandgap of 2.04 and highest occupied molecular orbital energy level of -5.56 eV. P106 is used as the donor and two nonfullerene acceptors-medium bandgap DBTBT-IC and narrow band Y18-DMO-are used as acceptors for the construction of binary and ternary bulk heterojunction polymer solar cells. The optimized polymer solar cells based on P106 : DBTBT-IC and P106 : Y18-DMO exhibit power conversion efficiencies of 11.76 % and 14.07 %, respectively. The short-circuit current density (22.78 mA cm-2 ) for the P106 : Y18-DMO device is higher than that for P106 : DBTBT-IC (18.56 mA cm-2 ) one, which could be attributed to the more photon harvesting efficiency of the P106 : Y18-DMO active layer. In light of the high short-circuit current densities and fill factors for the Y18-DMO based device and the high value of open circuit voltage of the DBTBT-IC based device, ternary polymer solar cells are fabricated by using ternary active layer (P106 : DBTBT-IC : Y18-DMO) and achieve a power conversion efficiency of 16.49 % with low energy loss of 0.47 eV.

Fullerene/Non-fullerene Alloy for High-Performance All-Small-Molecule Organic Solar Cells.

Organic solar cells (OSCs) that contain small molecules only were prepared with FG1 as the donor, a narrow band gap non-fullerene acceptor MPU4, and a wide band gap PC71BM. The OSCs based on optimized FG1:MPU4 (1:1.2) and FG1:PC71BM (1:1.5) active layers, respectively, gave power conversion efficiencies (PCEs) of 11.18% with a short circuit current (JSC) of 19.54 mA/cm2, open circuit voltage (VOC) of 0.97 V, and fill factor (FF) of 0.59, and 6.62% with a JSC of 12.50 mA/cm2, VOC of 0.84 V, and FF of 0.63%, respectively. A PCE of 13.26% was obtained from the optimized ternary FG1:PC71BM:MPU4 (1:0.3:0.9) OSCs and this arises because of the boost in a JSC of 21.91 mA/cm2 and FF of 0.68. The VOC of the ternary OSCs (0.89 V) lies between those for the OSCs based on FG1:MPU4 and FG1:PC71BM, which indicates the formation of an alloy of the two acceptors. The increase in JSC and FF in the ternary OSCs may result from the efficient energy transfer from PC71BM to MPU4 as well as more charge-transfer donor/acceptor interfaces, enhanced charge carrier mobilities resulting in better adjusted charge transport, and lower bimolecular and trap-assisted recombination. The appropriate phase separation, increased crystallinity, and reduced π-π stacking distance in the ternary active layer are consistent with the enhancement in the FF for OSCs based on a ternary active layer. The results of this work suggest the merging of the fullerene acceptor into the non-fullerene acceptor to form a fullerene/non-fullerene acceptor alloy, and this may be a viable approach to obtain high-performance OSCs.

Reducing Energy Loss in Organic Solar Cells by Changing the Central Metal in Metalloporphyrins.

The effect of central donor core on the properties of A-π-D-π-A donors, where D is a porphyrin macrocycle, cyclopenta[2,1-b:3,4-b']dithiophene is the π bridge, and A is a dicyanorhodanine terminal unit, was investigated for the fabrication of the organic solar cells (OSCs), along [6,6]-phenyl-C71-butyric acid methyl ester (PC71 BM) as electron acceptor. A new molecule consisting of Ni-porphyrin central donor core (VC9) showed deep HOMO energy level and OSCs based on optimized VC9:PC71 BM realized overall power conversion efficiency (PCE) of 10.66 % [short-circuit current density (JSC )=15.48 mA/cm2 , fill factor (FF)=0.65] with high open circuit voltage (VOC ) of 1.06 V and very low energy loss of 0.49 eV, whereas the Zn-porphyrin analogue VC8:PC71 BM showed PCE of 9.69 % with VOC of 0.89 V, JSC of 16.25 mA/cm2 and FF of 0.67. Although the OSCs based on VC8 showed higher JSC in comparison to VC9, originating from the broader absorption profile of VC8 that led to more exciton generation, the higher value of PCE of VC9 is owing to the higher VOC and reduced energy loss.

Efficient Fullerene-Free Organic Solar Cells Using a Coumarin-Based Wide-Band-Gap Donor Material.

In recent years, tremendous growth has been seen for solution-processed bulk heterojunction solar cells (BHJSCs) using fullerene-free molecular acceptors. Herein, we report the synthesis, characterization of a coumarin-based organic semiconducting molecule C1, and its use in BHJSCs as an electron donor. The compound exhibited an absorption band at 472 nm in chloroform solution with an optical energy gap of 2.33 eV. The HOMO/LUMO energy levels of C1 were found to be ideal for use in BHJSCs. Using PC71BM and a fullerene-free acceptor IT-4F, the device generated power conversion efficiencies (PCEs) of 6.17 and 8.31%, respectively. The success of the device based on a fullerene-free acceptor is a result of complementary absorption and well-matched energy levels, resulting in an improved photocurrent and photovoltage in the device. Moreover, ternary solar cells fabricated by employing C1 (20 wt%) as a secondary donor, i.e., an active layer of C1:PM6:IT-4F (0.2:0.8:1.5), generated an enhanced PCE of 11.56% with a high short-circuit current density (JSC) of 16.42 mA cm-2, an open-circuit voltage (VOC) of 1.02 V, and a fill factor of 0.69 under 1 sun spectral illumination, which is ∼8% higher than that for the PM6:IT-4F-based binary device (PCE = 10.70%). The increased PCE for the ternary organic solar cell may be related to the efficient exciton generation and its dissociation via Forster resonance energy transfer, which guarantees enough time for an exciton to diffuse toward the D/A interfaces.