ABSTRACT
Carbon capture utilization and storage (CCUS), the technology for decarbonizing carbon dioxide (CO2) from greenhouse gas emitters such as steel, cement, oil, gas, petrochemicals, chemicals, and fertilizers, has a critical role to play in the world to achieve industrial net zero targets by 2050. CO2 can be separated from industrial exhaust gases/flue gases using amine-based solvents utilizing the post-combustion CO2 Capture process. One most crucial solvent characterization for this application is the kinetics of CO2 absorption. This work identifies aqueous 1-(2-aminoethyl) piperazine (AEPZ) as a potential candidate for CO2 capture solvent. The kinetics of absorption of CO2 in aqueous AEPZ is studied using stirred cell reactor. The experiments are performed at temperatures ranging from 303 to 333 K with weight fractions of AEPZ in an aqueous solution ranging from 0.1 to 0.4. One of the critical parameters of the kinetic study is Henry's constant which is determined experimentally using another stirred cell reactor at a similar temperature and pressure range. The experimental data shows that the overall rate constant is Kov = 2.52987 × 10-4 mol/m2s-kPa for 0.1 wt fr. of AEPZ at 313 K with an initial CO2 partial pressure of 10 kPa. The temperature dependency relation of the second-order reaction rate constant, [Formula: see text] is found to be [Formula: see text] using the Arrhenius equation. The activation energy of 0.3 wt fr. AEPZ is found to be 42.42 kJ/mol. In addition, the density and viscosity of the aqueous solvent are determined at a wide range of temperatures. The diffusivity of CO2 and physical solubility used in the model development has also been determined. The kinetic parameters obtained from this study are helpful in the process design of CO2 capture in a regenerative process with a blended solvent with AEPZ.
ABSTRACT
The effluents released from textile industries mainly consist of dyes, metals and other pollutants. Dyes often are discharged in wastewater streams causing adverse effect on the environment. To eliminate these harmful dyes, various techniques are emerging out of which nanotechnology is the most reliable and safer. Nanotechnology offers convincing applications in case of environmental and economic concerns. The bio-synthesis of nanoparticles has several advantages over conventional methods and approach towards environment concern as well. Biological method of nanoparticles synthesis is concluded to be the most promising and efficient in action. Bio-synthesised nanoparticles could be used for treatment and decolourisation of dyes in an efficient manner. This review comprises the study of number of bio-synthesised nanoparticles utilised for degradation of various dyes present as pollutants in wastewater. Bio-synthesised nanoparticles such as gold, silver, iron, cobalt, zinc, titanium and molybdenum used for degradation of various dyes have been discussed in this review.
