Highly effective and reusable Ni-Al oxide/Zn0.4Co0.6Fe2O4 superparamagnetic aerogel for oil-water separation.

Oily wastewater from the oil industry and oil spill accidents has become a serious environmental problem and has attracted worldwide attention. The present study reports on the successful preparation of a novel magnetic Ni-Al oxide/Zn0.4Co0.6F2O4 mesoporous aerogel (MNA) as a highly selective adsorbent for oil removal from water. Oleic acid (OA) and Triton X-100 (TX) were used as hydrophobic agents for MNA surface modification. It was found that the attached amount of OA on the mesoporous MNA aerogel is 3.5 times larger than that of TX, giving an advantage to MNA-OA in oil separation. The MNA-OA displayed superhydrophobicity (contact angle ∼150°) and superparamagnetism properties that allowed the adsorbent to be used selectively for oil removal. The MNA-OA was found to have a high oil removal efficiency of ∼97% with an adsorption capacity of ∼2 g/g. Furthermore, the produced magnetic adsorbent has high stability due to the strong chemical binding of OA, which is demonstrated by its good reusability performance. Throughout five separate runs, the MNA-OA was shown to be a very efficient and reusable adsorbent for oily wastewater.

SiO2/Zn0.4Co0.6Fe2O4 aerogel: an efficient and reusable superparamagnetic adsorbent for oily water remediation.

Magnetic SiO2/Zn0.4Co0.6Fe2O4 aerogels were successfully prepared by sol-gel method with two different drying steps: ambient pressure drying (APD) and freeze-drying (FD). The surface chemistry of silica was modified to be hydrophobic by oleic acid. The prepared materials were fully characterized, displaying superparamagnetic behavior with saturation magnetizations of 10.2 and 15.1 emu g-1, and contact angles of ∼130° and ∼140° for the materials prepared by the APD and FD methods, respectively, indicating the hydrophobic surfaces of the prepared materials. This hydrophobicity allows the efficient separation of oil. Specifically, as high as 1.7 and 2 g g-1 adsorption capacities were obtained when using APD-dried and FD-dried silica aerogels, respectively, suggesting the preference for the FD method. Additionally, magnetic recovery and reuse of the adsorbents were successfully implemented in an attempt to reduce the overall practical application costs. To sum up, the prepared materials are good candidates for oil removal from wastewater and the protection of the environment.