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1.
Sci Rep ; 14(1): 16484, 2024 Jul 17.
Article in English | MEDLINE | ID: mdl-39019925

ABSTRACT

Tremendous research efforts have been directed toward developing polymer-based piezoelectric nanogenerators (PENG) in a promising step to investigate self-charging powered systems (SCPSs) and consequently, support the need for flexible, intelligent, and ultra-compact wearable electronic devices. In our work, electrospun polyvinylidene fluoride (PVDF) nanofiber mats were investigated while graphene oxide (GO) was added with different concentrations (from 0 to 3 wt.%). Sonication treatment was introduced for 5 min to GO nanosheets before combined PVDF solution. A comprehensive study was conducted to examine the GO incremental effect. Microstructural and mechanical properties were examined using a scanning electron microscope (SEM) and a texture analyzer. Moreover, piezoelectric properties were assessed via various tests including impulse response, frequency effect, d33 coefficient, charging and discharging analysis, and sawyer tower circuit. Experimental results indicate that incorporation of GO nanosheets enhances piezoelectric properties for all concentrations, which was linked to the increase in ß phase inside the nanofibers, which has a significant potential of enhancing nanogenerator performance. PVDF-GO 1.5 wt.% shows a notably higher enhancing effect where the electroactive ß-phase and γ-phase are recorded to be boosted to ~ 68.13%, as well as piezoelectric coefficient (d33 ~ 55.57 pC/N). Furthermore, increasing impact force encouraged the output voltage. Also noted that the delivered open circuit voltage is ~ 3671 V/g and the power density is ~ 150 µw/cm2. It was observed that GO of concentration 1.5 wt.% recorded a conversion efficiency of ~ 74.73%. All results are in line, showing better performance for PVDF-GO 1.5 wt.% for almost all concentrations.

2.
Sensors (Basel) ; 23(12)2023 Jun 20.
Article in English | MEDLINE | ID: mdl-37420898

ABSTRACT

Wireless Sensor Networks (WSNs) have been adopted in various environmental pollution monitoring applications. As an important environmental field, water quality monitoring is a vital process to ensure the sustainable, important feeding of and as a life-maintaining source for many living creatures. To conduct this process efficiently, the integration of lightweight machine learning technologies can extend its efficacy and accuracy. WSNs often suffer from energy-limited devices and resource-affected operations, thus constraining WSNs' lifetime and capability. Energy-efficient clustering protocols have been introduced to tackle this challenge. The low-energy adaptive clustering hierarchy (LEACH) protocol is widely used due to its simplicity and ability to manage large datasets and prolong network lifetime. In this paper, we investigate and present a modified LEACH-based clustering algorithm in conjunction with a K-means data clustering approach to enable efficient decision making based on water-quality-monitoring-related operations. This study is operated based on the experimental measurements of lanthanide oxide nanoparticles, selected as cerium oxide nanoparticles (ceria NPs), as an active sensing host for the optical detection of hydrogen peroxide pollutants via a fluorescence quenching mechanism. A mathematical model is proposed for the K-means LEACH-based clustering algorithm for WSNs to analyze the quality monitoring process in water, where various levels of pollutants exist. The simulation results show the efficacy of our modified K-means-based hierarchical data clustering and routing in prolonging network lifetime when operated in static and dynamic contexts.


Subject(s)
Environmental Monitoring , Unsupervised Machine Learning , Cluster Analysis , Environmental Monitoring/instrumentation , Environmental Monitoring/methods , Nanoparticles , Computer Simulation , Environmental Pollutants/analysis
3.
Membranes (Basel) ; 13(6)2023 Jun 15.
Article in English | MEDLINE | ID: mdl-37367808

ABSTRACT

Accelerated wound healing in infected skin is still one of the areas where current therapeutic tactics fall short, which highlights the critical necessity for the exploration of new therapeutic approaches. The present study aimed to encapsulate Eucalyptus oil in a nano-drug carrier to enhance its antimicrobial activity. Furthermore, in vitro, and in vivo wound healing studies of the novel nano-chitosan/Eucalyptus oil/cellulose acetate electrospun nanofibers were investigated. Eucalyptus oil showed a potent antimicrobial activity against the tested pathogens and the highest inhibition zone diameter, MIC, and MBC (15.3 mm, 16.0 µg/mL, and 256 µg/mL, respectively) were recorded against Staphylococcus aureus. Data indicated a three-fold increase in the antimicrobial activity of Eucalyptus oil encapsulated chitosan nanoparticle (43 mm inhibition zone diameter against S. aureus). The biosynthesized nanoparticles had a 48.26 nm particle size, 19.0 mV zeta potential, and 0.45 PDI. Electrospinning of nano-chitosan/Eucalyptus oil/cellulose acetate nanofibers was conducted, and the physico-chemical and biological properties revealed that the synthesized nanofibers were homogenous, with a thin diameter (98.0 nm) and a significantly high antimicrobial activity. The in vitro cytotoxic effect in a human normal melanocyte cell line (HFB4) proved an 80% cell viability using 1.5 mg/mL of nano-chitosan/Eucalyptus oil/cellulose acetate nanofibers. In vitro and in vivo wound healing studies revealed that nano-chitosan/Eucalyptus oil/cellulose acetate nanofibers were safe and efficiently enhanced the wound-healing process through enhancing TGF-ß, type I and type III collagen production. As a conclusion, the manufactured nano-chitosan/Eucalyptus oil/cellulose acetate nanofiber showed effective potentiality for its use as a wound healing dressing.

4.
Sensors (Basel) ; 23(5)2023 Feb 27.
Article in English | MEDLINE | ID: mdl-36904836

ABSTRACT

Advances in nanotechnology have enabled the creation of novel materials with specific electrical and physical characteristics. This leads to a significant development in the industry of electronics that can be applied in various fields. In this paper, we propose a fabrication of nanotechnology-based materials that can be used to design stretchy piezoelectric nanofibers for energy harvesting to power connected bio-nanosensors in a Wireless Body Area Network (WBAN). The bio-nanosensors are powered based on harvested energy from mechanical movements of the body, specifically the arms, joints, and heartbeats. A suite of these nano-enriched bio-nanosensors can be used to form microgrids for a self-powered wireless body area network (SpWBAN), which can be used in various sustainable health monitoring services. A system model for an SpWBAN with an energy harvesting-based medium access control protocol is presented and analyzed based on fabricated nanofibers with specific characteristics. The simulation results show that the SpWBAN outperforms and has a longer lifetime than contemporary WBAN system designs without self-powering capability.


Subject(s)
Electronics , Nanotechnology , Electricity
5.
Sci Rep ; 12(1): 21788, 2022 12 16.
Article in English | MEDLINE | ID: mdl-36526645

ABSTRACT

This paper introduces a new approach of testing piezoelectric nanofibers as antibacterial mat. In this work, both Polyvinylidene fluoride (PVDF) and PVDF embedded with thermoplastic polyurethane nanofibers are synthesized as nanofibers mat via electrospinning technique. Then, such mat is analyzed as piezoelectric material to generate electric voltage under different mechanical excitations. Furthermore, morphological and chemical characteristics have been operated to prove the existence of beta sheets piezoelectricity of the synthesized nanofibers mats. Then, the synthesized nanofibers surfaces have been cyclically stretched and exposed to bacteria specimen. It has been noticed that the generated voltage and the corresponding localized electric field positively affect the growth of bacteria and reduces the formation of K. penomenue samples bacteria colonies. In addition, the effect of both stretching frequency and pulses numbers have been studied on the bacteria count, growth kinetics, and protein leakage. Our contribution here is to introduce an innovative way of the direct impact of the generated electric field from piezoelectric nanofibers on the reduction of bacteria growth, without depending on traditional anti-bacterial nanoparticles. This work can open a new trend of the usability of piezoelectric nanofibers through masks, filters, and wound curing mats within anti-bacterial biological applications.


Subject(s)
Nanofibers , Polyvinyls , Anti-Bacterial Agents/pharmacology , Polyurethanes/pharmacology , Bacteria
6.
Molecules ; 27(17)2022 Aug 24.
Article in English | MEDLINE | ID: mdl-36080176

ABSTRACT

A series of novolac phenolic polymeric networks (NPPN) were prepared via an acid-catalyzed polycondensation reaction of formaldehyde with chalcones possessing a p-phenolic OH group. When p-hydroxybenzaldehyde was treated with formaldehyde under the same conditions, a phenolic polymer (PP) was obtained. The resulting polymers were isolated in excellent yields (83-98%). Isolated polymers (NPPN, PP) were characterized using FTIR, TGA, and XRD. The results obtained from the TGA revealed that all prepared phenolic polymers have high thermal stability at high temperatures and can act as thermosetting materials. XRD data analysis showed a high degree of amorphousness for all polymers (78.8-89.2%). The electrical conductivities and resistivities of all chalcone-based phenolic networks (NPPN) and p-hydroxybenzaldehyde polymer (PP) were also determined. The physical characteristics obtained from the I-V curve showed that the conductivity of phenolic polymers has a wide range from ultimately negligible values of 0.09 µS/cm up to 2.97 µS/cm. The degree of polarization of the conjugated system's carbonyl group was attributed to high, low, or even no conductivity for all phenolic polymers since the electronic effects (inductive and mesomeric) could impact the polarization of the carbonyl group and, consequently, change the degree of the charge separation to show varied conductivity values.


Subject(s)
Chalcone , Chalcones , Electric Conductivity , Formaldehyde , Phenols , Polymers
8.
Sci Rep ; 12(1): 8335, 2022 05 18.
Article in English | MEDLINE | ID: mdl-35585095

ABSTRACT

Interest in piezoelectric nanocomposites has been vastly growing in the energy harvesting field. They are applied in wearable electronics, mechanical actuators, and electromechanical membranes. In this research work, nanocomposite membranes of different blend ratios from PVDF and TPU have been synthesized. The PVDF is responsible for piezoelectric performance where it is one of the promising polymeric organic materials containing ß-sheets, to convert applied mechanical stress into electric voltage. In addition, the TPU is widely used in the plastic industry due to its superior elasticity. Our work investigates the piezoresponse analysis for different blending ratios of PVDF/TPU. It has been found that TPU blending ratios of 15-17.5% give higher output voltage at different stresses conditions along with higher piezosensitivity. Then, TPU addition with its superior mechanical elasticity can partially compensate PVDF to enhance the piezoelectric response of the PVDF/TPU nanocomposite mats. This work can help reducing the amount of added PVDF in piezoelectric membranes with enhanced piezo sensitivity and mechanical elasticity.


Subject(s)
Nanocomposites , Nanofibers , Elasticity , Fluorocarbon Polymers , Polyurethanes , Polyvinyls
9.
Polymers (Basel) ; 13(22)2021 Nov 18.
Article in English | MEDLINE | ID: mdl-34833289

ABSTRACT

Herein, in the present work two series of thermoplastic polyurethane (TPU) nanofibers were manufactured using the electrospinning techniques with ZnO and CuO nanoparticles for a potential use as an elastic functional layer in antimicrobial applications. Percentages of 0%, 2 wt%, and 4 wt% of the nanoparticles were used. The morphological characterization of the electrospun TPU and TPU/NPs composites nanofibers were observed by using scanning electron microscopy to show the average fiber diameter and it was in the range of 90-150 nm with a significant impact of the nanoparticle type. Mechanical characterization showed that TPU nanofiber membranes exhibit excellent mechanical properties with ultra-high elastic properties. Elongation at break reached up to 92.5%. The assessment of the developed nanofiber membranes for medical and personal protection applications was done against various colistin resistant bacterial strains and the results showed an increment activity by increasing the metal oxide concentration up to 83% reduction rate by using TPU/ZnO 4% nanofibers against K. pneumoniae strain 10. The bacterial growth was completely eradicated after 8 and 16 h incubation with TPU/ZnO and TPU/CuO nanofibers, respectively. The nanofibers SEM study reveals the adsorption of the bacterial cells on the metal oxides nanofibers surface which led to cell lysis and releasing of their content. Finally, in vitro study against Spike S-protein from SARS-CoV-2 was also evaluated to investigate the potent effectiveness of the proposed nanofibers in the virus deactivation. The results showed that the metal oxide concentration is an effective factor in the antiviral activity due to the observed pattern of increasing the antibacterial and antiviral activity by increasing the metal oxide concentration; however, TPU/ZnO nanofibers showed a potent antiviral activity in relation to TPU/CuO.

10.
Nanomaterials (Basel) ; 11(8)2021 Jul 27.
Article in English | MEDLINE | ID: mdl-34443759

ABSTRACT

This paper investigates the spontaneous decay rate of elliptical plasmonic nanostructures. The refractive index was analyzed using the effective medium theory (EMT). Then, the polarizability, spontaneous radiative, non-radiative decay rate, and electric field enhancement factor were characterized for the targeted elliptical nanostructures at different aspect ratios. All of the optical analyses were analyzed at different distances between the excited fluorescent coupled atom and the plasmonic nanostructure (down to 100 nm). This work is promising in selecting the optimum elliptical nanostructure according to the required decay rates for optical conversion efficiency control in energy harvesting for solar cells and optical sensing applications.

11.
Materials (Basel) ; 14(14)2021 Jul 10.
Article in English | MEDLINE | ID: mdl-34300781

ABSTRACT

Biodegradable nanofibrous hybrid membranes of polyvinyl alcohol (PVA) with ZnO and CuO nanoparticles were manufactured and characterized, and their anti-COVID-19 and anti-multidrug resistant bacteria activities were also evaluated. The morphological structures of the prepared PVA composites nanofibers were observed by scanning electron microscope (SEM), which revealed a homogenous pattern of the developed nanofibers, with an average fibrous diameter of 200-250 nm. Moreover, the results of the SEM showed that the fiber size changed with the type and the concentration of the metal oxide. Moreover, the antiviral and antibacterial potential capabilities of the developed nanofibrous membranes were tested in blocking the viral fusion of SARS-COV-2, as a representative activity for COVID-19 deactivation, as well as for their activity against a variety of bacterial strains, including multi-drug resistant bacteria (MDR). The results revealed that ZnO loaded nanofibers were more potent antiviral agents than their CuO analogues. This antiviral action was attributed to the fact that inorganic metallic compounds have the ability to extract hydrogen bonds with viral proteins, causing viral rupture or morphological changes. On the other hand, the anti-multi-drug resistant activity of the prepared nanofibers was also evaluated using two techniques; the standard test method for determining the antimicrobial activity of immobilized antimicrobial agents under dynamic contact conditions and the standard test method for determining the activity of incorporated antimicrobial agents in polymeric or hydrophobic materials. Both techniques proved the superiority of the ZnO loaded nanofibers over the CuO loaded fibers. The results of the antiviral and antibacterial tests showed the effectiveness of such nanofibrous formulas, not only for medical applications, but also for the production of personal protection equipment, such as gowns and textiles.

12.
Polymers (Basel) ; 13(11)2021 Jun 04.
Article in English | MEDLINE | ID: mdl-34200040

ABSTRACT

Chronic wounds are commonly colonized with bacteria in a way that prevents full healing process and capacity for repair. Nano-chitosan, a biodegradable and nontoxic biopolymer, has shown bacteriostatic activity against a wide spectrum of bacteria. Effectively, pulsed electromagnetic fields are shown to have both wound healing enhancement and antibacterial activity. This work aimed to combine the use of nano-chitosan and exposure to a pulsed electric field to overcome two common types of infectious bacteria, namely P. aeruginosa and S. aureus. Here, bacteria growing rate, growth kinetics and cell cytotoxicity (levels of lactate dehydrogenase, protein leakage and nucleic acid leakage) were investigated. Our findings confirmed the maximum antibacterial synergistic combination of nano-chitosan and exposure against P. aeruginosa than using each one alone. It is presumed that the exposure has influenced bacteria membrane charge distribution in a manner that allowed more chitosan to anchor the surface and enter inside the cell. Significantly, cell cytotoxicity substantiates high enzymatic levels as a result of cell membrane disintegration. In conclusion, exposure to pulsed electromagnetic fields has a synergistic antibacterial effect against S. aureus and P. aeruginosa with maximum inhibitory effect for the last one. Extensive work should be done to evaluate the combination against different bacteria types to get general conclusive results. The ability of using pulsed electromagnetic fields as a wound healing accelerator and antibacterial cofactor has been proved, but in vivo experimental work in the future to verify the use of such a new combination against infectious wounds and to determine optimum treatment conditions is a must.

13.
Polymers (Basel) ; 13(11)2021 May 28.
Article in English | MEDLINE | ID: mdl-34071484

ABSTRACT

In this research work, nanofibrous hybrids are manufactured, characterized, and assessed as active antiviral and antibacterial membranes. In more detail, both polyvinyl alcohol (PVA) and thermoplastic polyurethane (TPU) nanofibrous (NF) membranes and their composites with embedded silver nanoparticles (Ag NPs) are manufactured by an electrospinning process. Their morphological structures have been investigated by a scanning electron microscope (SEM) which revealed a homogenous distribution and almost beads-free fibers in all manufactured samples. Characterization with spectroscopic tools has been performed and proved the successful manufacturing of Ag-incorporated PVA and TPU hybrid nanofibers. The crystalline phase of the nanofibers has been determined using an X-ray diffractometer (XRD) whose patterns showed their crystalline nature at an angle value (2θ) of less than 20°. Subsequent screening of both antiviral and antibacterial potential activities of developed nanohybrid membranes has been explored against different viruses, including SARS-Cov-2 and some bacterial strains. As a novel approach, the current work highlights potential effects of several polymeric hybrids on antiviral and antibacterial activities particularly against SARS-Cov-2. Moreover, two types of polymers have been tested and compared; PVA of excellent biodegradable and hydrophilic properties, and TPU of excellent mechanical, super elasticity, hydrophobicity, and durability properties. Such extreme polymers can serve a wide range of applications such as PPE, filtration, wound healing, etc. Consequently, assessment of their antiviral/antibacterial activities, as host matrices for Ag NPs, is needed for different medical applications. Our results showed that TPU-Ag was more effective than PVA-Ag as HIV-1 antiviral nanohybrid as well as in deactivating spike proteins of SARS-Cov-2. Both TPU-Ag and PVA-Ag nanofibrous membranes were found to have superior antimicrobial performance by increasing Ag concentration from 2 to 4 wt.%. Additionally, the developed membranes showed acceptable physical and mechanical properties along with both antiviral and antibacterial activities, which can enable them to be used as a promising functional layer in Personal Protective Equipment (PPE) such as (surgical gowns, gloves, overshoes, hair caps, etc.). Therefore, the developed functional membranes can support the decrease of both coronavirus spread and bacterial contamination, particularly among healthcare professionals within their workplace settings.

14.
Polymers (Basel) ; 13(2)2021 Jan 15.
Article in English | MEDLINE | ID: mdl-33467752

ABSTRACT

The over-reliance on antibiotics and their enormous misuse has led to warnings of a future without effective medicines and so, the need for alternatives to antibiotics has become a must. Non-traditional antibacterial treatment was performed by using an aray of nanocomposites synergised with exposure to electromagnetic waves. In this manuscript, electrospun poly(vinyl alcohol) (PVA) nanofiber mats embedded with silver nanoparticles (Ag NPs) were synthesized. The nanocomposites were characterized by Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM), Current-Voltage (I-V) curves, and Thermogravimetric analysis (TGA) along with analysis of antibacterial impact against E. coli and S. aureus bacteria, studied by bacterial growing analysis, growth kinetics, and cellular cytotoxicity. The results indicated a spherical grain shape of silver of average size 20 nm and nanofibers' mean diameter of less than 100 nm. The nanocomposite mats showed good exposure to bacteria and the ability to sustain release of silver for a relatively long time. Moreover, the applied electromagnetic waves (EMWs) were shown to be a synergistic co-factor in killing bacteria even at low concentrations of Ag NPs. This caused pronounced alterations of the bacterial preserved packing of the cell membrane. Thereby, the treatment with nanocomposite mats under EM wave exposure elucidated maximum inhibition for both bacterial strains. It was concluded that the functioning of nanofiber with silver nanoparticles and exposure to electromagnetic waves improved the antibacterial impact compared to each one alone.

15.
Sensors (Basel) ; 20(11)2020 May 31.
Article in English | MEDLINE | ID: mdl-32486397

ABSTRACT

This paper introduces a new usage of piezoelectric poly (vinylidene fluoride) (PVDF) electrospun nanofiber (NF) membrane as a sensing unit for acoustic signals. In this work, an NF mat has been used as a transducer to convert acoustic signals into electric voltage outcomes. The detected voltage has been analyzed as a function of both frequency and amplitude of the excitation acoustic signal. Additionally, the detected AC signal can be retraced as a function of both frequency and amplitude with some wave distortion at relatively higher amplitudes and within a certain acoustic spectrum region. Meanwhile, the NFs have been characterized through piezoelectric responses, beta sheet calculations and surface morphology. This work is promising as a low-cost and innovative solution to harvest acoustic signals coming from wide resources of sound and noise.

16.
Polymers (Basel) ; 12(6)2020 Jun 07.
Article in English | MEDLINE | ID: mdl-32517387

ABSTRACT

Polyvinylidene fluoride (PVDF)-based piezoelectric materials (PEMs) have found extensive applications in energy harvesting which are being extended consistently to diverse fields requiring strenuous service conditions. Hence, there is a pressing need to mass produce PVDF-based PEMs with the highest possible energy harvesting ability under a given set of conditions. To achieve high yield and efficiency, solution blow spinning (SBS) technique is attracting a lot of interest due to its operational simplicity and high throughput. SBS is arguably still in its infancy when the objective is to mass produce high efficiency PVDF-based PEMs. Therefore, a deeper understanding of the critical parameters regarding design and processing of SBS is essential. The key objective of this review is to critically analyze the key aspects of SBS to produce high efficiency PVDF-based PEMs. As piezoelectric properties of neat PVDF are not intrinsically much significant, various additives are commonly incorporated to enhance its piezoelectricity. Therefore, PVDF-based copolymers and nanocomposites are also included in this review. We discuss both theoretical and experimental results regarding SBS process parameters such as solvents, dissolution methods, feed rate, viscosity, air pressure and velocity, and nozzle design. Morphological features and mechanical properties of PVDF-based nanofibers were also discussed and important applications have been presented. For completeness, key findings from electrospinning were also included. At the end, some insights are given to better direct the efforts in the field of PVDF-based PEMs using SBS technique.

17.
Polymers (Basel) ; 12(5)2020 May 16.
Article in English | MEDLINE | ID: mdl-32429457

ABSTRACT

Computational fluid dynamics (CFD) was used to investigate characteristics of high-speed air as it is expelled from a solution blow spinning (SBS) nozzle using a k-ε turbulence model. Air velocity, pressure, temperature, turbulent kinetic energy and density contours were generated and analysed in order to achieve an optimal attenuation force for fibre production. A bespoke convergent nozzle was used to produce polyvinylidene fluoride (PVDF) fibres at air pressures between 1 and 5 bar. The nozzle comprised of four parts: a polymer solution syringe holder, an air inlet, an air chamber, and a cap that covers the air chamber. A custom-built SBS setup was used to produce PVDF submicron fibres which were consequently analysed using scanning electron microscope (SEM) for their morphological features. Both theoretical and experimental observations showed that a higher air pressure (4 bar) is more suitable to achieve thin fibres of PVDF. However, fibre diameter increased at 5 bar and intertwined ropes of fibres were also observed.

19.
Nanomaterials (Basel) ; 10(2)2020 Feb 12.
Article in English | MEDLINE | ID: mdl-32059378

ABSTRACT

Cerium oxide (ceria) nanoparticles (NPs) have been proved to be an efficient optical fluorescent material through generating visible emission (~530 nm) under violet excitation. This feature allowed ceria NPs to be used as an optical sensor via the fluorescence quenching Technique. In this paper, the impact of in-situ embedded gold nanoparticles (Au NPs) inside ceria nanoparticles was studied. Then, gold-ceria NPs were used for sensing dissolved oxygen (DO) in aqueous media. It was observed that both fluorescence intensity and lifetime were changed due to increased concentration of DO. Added gold was found to enhance the sensitivity of ceria to DO quencher detection. This enhancement was due to optical coupling between the fluorescence emission spectrum of ceria with the surface plasmonic resonance of gold nanoparticles. In addition, gold caused the decrease of ceria nanoparticles' bandgap, which indicates the formation of more oxygen vacancies inside the non-stoichiometric crystalline structure of ceria. The Stern-Volmer constant, which indicates the sensitivity of optical sensing material, of ceria-gold NPs with added DO was found to be 893.7 M-1, compared to 184.6 M-1 to in case of ceria nanoparticles only, which indicates a superior optical sensitivity to DO compared to other optical sensing materials used in the literature to detect DO. Moreover, the fluorescence lifetime was found to be changed according to the variation of added DO concentration. The optically-sensitivity-enhanced ceria nanoparticles due to embedded gold nanoparticles can be a promising sensing host for dissolved oxygen in a wide variety of applications including biomedicine and water quality monitoring.

20.
Polymers (Basel) ; 11(10)2019 Oct 10.
Article in English | MEDLINE | ID: mdl-31658601

ABSTRACT

Poly (vinylidene fluoride) nanofibers (PVDF NFs) have been extensively used in energy harvesting applications due to their promising piezoresponse characteristics. However, the mechanical properties of the generated fibers are still lacking. Therefore, we are presenting in this work a promising improvement in the elasticity properties of PVDF nanofibrous membrane through thermoplastic polyurethane (TPU) additives. Morphological, physical, and mechanical analyses were performed for membranes developed from different blend ratios. Then, the impact of added weight ratio of TPU on the piezoelectric response of the formed nanofibrous composite membranes was studied. The piezoelectric characteristics were studied through impulse loading testing where the electric voltage had been detected under applied mass weights. Piezoelectric characteristics were investigated further through a pressure mode test the developed nanofibrous composite membranes were found to be mechanically deformed under applied electric potential. This work introduces promising high elastic piezoelectric materials that can be used in a wide variety of applications including energy harvesting, wearable electronics, self-cleaning filters, and motion/vibration sensors.

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