ABSTRACT
In this report, the strong-dependence of low-frequency (terahertz) vibrational dynamics on weak and long-range forces in crystals is leveraged to determine the bulk magnetic configuration of iron phosphate - a promising material for cathodes in lithium ion batteries. We demonstrate that terahertz time-domain spectroscopy - coupled with quantum mechanical simulations - can discern between various spin configurations in FePO4. Furthermore, the results of this work unambiguously show that the well-accepted space group symmetry for FePO4 is incorrect, and the low-frequency spectroscopic measurements provide a clearer picture of the correct structure over the gold-standard of X-ray diffraction. This work opens the door for characterizing, predicting, and interpreting crystalline magnetic ordering using low-frequency vibrational spectroscopy.
ABSTRACT
THz waves have interesting applications in refractive index sensing. A THz gas sensor based on the guided Bloch surface wave resonance (GBSWR) in a one-dimensional photonic crystal (1DPhC), which consists of periodic polycarbonate (PC) layers and polyvinylidene fluoride (PVDF) layers, has been proposed. Numerical results based on finite element method (FEM) show that the photonic band gap that confines Bloch surface waves (BSWs) lies in the regime of 11.54 to 21.43 THz, in which THz wave can transmit in both PC and PVDF with the ignored absorption. The calculated sensitivity of hazardous gas HCN in angle is found to be 118.6°/RIU (and the corresponding figure of merit (FOM) is 227) and the sensitivity in frequency is 4.7 THz/RIU (the corresponding FOM is 301.3). The proposed structure may also be used for monitoring hazardous gases which show absorption to the incident THz wave. Further results show that for N2O gas, the maximum sensitivity goes up to 644 (transmittance unit/ one unit of the imaginary part of the refractive index). The proposed design may find applications in the detection of dangerous gases.
