Numerical Simulation and Comparison of the Mechanical Behavior of Toughened Epoxy Resin by Different Nanoparticles.

Adding nanoparticles as the second phase to epoxy can achieve a good toughening effect. The aim of this paper is to simulate the toughening behavior of epoxy resin by different nanoparticles using a convenient and effective finite element method. The mechanical behaviors of epoxy resins toughened by nano core-shell polymers, liquid rubber, and nanosilica were compared by numerical simulations using the representative volume element (RVE). It is indicated that the addition of a nano core-shell polymer and liquid rubber can reduce the tensile properties of epoxy resin, while nanosilica is on the contrary. With the increase of nanoparticle content, the length of crack propagation decreases, and the toughening effect of the nano core-shell polymer is the best. The failure mode is determined by the particle/matrix interface when the modulus of the nanoparticle is much larger than that of epoxy resin. However, it is determined by the interface properties of the particle/matrix and the modulus of nanoparticles in other cases. The results provide a theoretical basis for toughening nanoparticle selection of nanoparticle-toughened epoxy resin and other similar simulations in the future.

Evaluation of Nano-Mechanical Behavior on Flax Fiber Metal Laminates Using an Atomic Force Microscope.

The application of plant fiber-reinforced composite (PFRC) is limited due to its relatively low mechanical properties. The hybridization of a thin metal layer with plant fiber into a fiber metal laminate can largely improve the mechanical performance and the brittle fracture behavior of PFRC. However, both plant fiber and metal have difficulty bonding with the polymer matrix. In this paper, several different surface treatment methods were applied on Al alloy sheets, and the influence of surface treatments on the surface morphology and nano-mechanical properties of Al alloy were studied using an atomic force microscope (AFM). After the preparation of flax fiber-metal laminates (FFMLs) with a vacuum-assisted resin transfer molding (VARTM) technique, the nanomechanical properties of different modified FFMLs were also evaluated with an AFM. It was found that the surface treatment combination of the sulfuric acid-ferric sulfate-based treatment (P2 etching) and the silane coupling agent provided the best adhesion force and modulus for Al alloy sheets at nanoscale resolution, which contributed to the surface energy increasing and strong covalent bonds between metal and polymer matrix. The resulting manufactured FFMLs also exhibited the highest nano-mechanical properties due to the great improvement of interfacial properties between metal and matrix, which was caused by mechanical interlocking mechanism and covalent bonds between metal/fiber and resin. Macromechanical performance, including tensile and flexural properties of these modified FFMLs, was also investigated. Comparison of the modulus at the nanoscale and macroscale showed reasonable agreement, and it revealed the tough interlaminar mechanisms of these types of FFMLs.

Dynamic Mechanical Analysis on Delaminated Flax Fiber Reinforced Composites.

It is well-known that the presence of the delamination in a plant fiber-reinforced composite is difficult to detect. However, the delamination introduces a local flexibility, which changes the dynamic characteristics of the composite structure. This paper presents a new methodology for composite laminate delamination detection, which is based on dynamic mechanical analysis. A noticeable delamination-induced storage modulus reduction and loss factor enhancement have been observed when the delaminated laminate was subjected to a forced oscillation compared to the intact composite laminate. For delamination area of 12.8% of the whole area of the composite laminate, loss factor of approximately 12% increase was observed. For near-to-surface delamination position, loss factor of approximately an 18% increment was observed. The results indicate that the delamination can be reliably detected with this method, and delamination position shows greater influence on the loss factor than that of the delamination size. Further investigations on different frequencies and amplitudes configurations show that the variation of loss factor is more apparently with low frequency as well as the low amplitude.

Scale Effect on Impact Performance of Unidirectional Glass Fiber Reinforced Epoxy Composite Laminates.

As a result of the increasing use of glass fiber reinforced plastic (GFRP) composites in engineering fields, the investigation of scale effect on impact performance for this kind of composite is essential for large scale structure design. The effects of scaling on the impact response of simply supported unidirectional GFRP were investigated through drop weight impact (DWI) tests in this study. Impact tests were undertaken over a wide range of energies to generate damages between barely visible and initiated penetration on four scale size GFRP laminates. The main impact responses including impact force, contact duration, displacement, energy absorption and damage area of scaled specimens were normalized to compare with the full-size specimen. It was found that the impact response of large sample with elastic deformation and small area of delamination can be predicted accurately according to a geometrical similar scaling law. Scale effect was found in the damage threshold force and absorbed energy of the laminates when significant internal damage occurs due to the microstructural effect becoming important in resisting impact force and absorbing impact energy. Moreover, the energy partition and effective stiffness were calculated according to the energy balance model to reveal the contribution of different modes of deformations on energy absorption for the GFRP laminates.

Effect of Temperature and Water Absorption on Low-Velocity Impact Damage of Composites with Multi-Layer Structured Flax Fiber.

Temperature and moisture can cause degradation to the impact properties of plant fiber-based composites owing to their complex chemical composition and multi-layer microstructure. This study focused on experimental characterization of the effect of important influencing factors, including manufacturing process temperature, exposure temperature, and water absorption, on the impact damage threshold and damage mechanisms of flax fiber reinforced composites. Firstly, serious reduction on the impact damage threshold and damage resistance was observed, this indicated excessive temperature can cause chemical decomposition and structural damage to flax fiber. It was also shown that a moderate high temperature resulted in lower impact damage threshold. Moreover, a small amount of water absorption could slightly improve the damage threshold load and the damage resistance. However, more water uptake caused severe degradation on the composite interface and structural damage of flax fiber, which reduced the impact performance of flax fiber reinforced composites.