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Chemistry ; 23(42): 10034-10037, 2017 Jul 26.
Article in English | MEDLINE | ID: mdl-28594451

ABSTRACT

An unprecedented two-step spin-crossover behavior with the sequence of γHS =1↔γHS =3/4↔γHS =1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)2 {Ag(CN)2 }2 ] (isoq=isoquinoline), which resulted from three crystallographically inequivalent FeII sites with distinct transition temperatures.

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