1.
Org Biomol Chem
; 16(14): 2406-2410, 2018 04 04.
Article
in English
| MEDLINE
| ID: mdl-29565432
ABSTRACT
A visible-light-induced cascade Meerwein addition/cyclization of alkenes involving C-F bond cleavage was developed. This method offers a rapid access to azaspirocyclic cyclohexadienones from N-benzylacrylamides via C-F bond cleavage applying H2O as an external oxygen source, allowing for the incorporation of various aromatic moieties originating from aryldiazonium salts.