ABSTRACT
The Surface-enhanced Raman spectroscopy is the essential tool for various levels of the molecular studies. In order to become widely used as a fast analytical tool, the enhancing structures such as the nanoparticles have to be simple, inexpensive, and offer good flexibility in enhancing properties and the spectral range. In this paper, we investigated the plasmonic properties of the metal nanoparticles, to which the molecules of interest can be adsorbed, forming the bionanocomplexes. Here, for the first time, we provided the collection of the results gathered in one article, which can serve as the basis or guidance for designing the SERS studies on different bionanocomplexes, various nanoparticle structures, sizes, and excitation wavelengths. The presented plasmonic properties describe the spectral position of the plasmonic resonances as results of their size and structure. The electric field enhancement as a key contributor to the SERS effect is given as well. We considered silver and gold nanoparticles and their variations. Gold is one of the best choice, due to its relevant surface properties, however, suffers from the plasmonic activity and rather static spectral position of the plasmonic resonances. Therefore, one of the main purposes was to show the effective resonance tuning using simple and less expensive geometries. We showed the possibility to adjust the plasmonic resonances with the excitation wavelengths from the blue region to the near infrared region of lasers most commonly used for Raman spectroscopy. The presented studies indicated the high potential of the core-shell structures for this kind of applications.
ABSTRACT
The Double Quantum Well structure (DQWs) of special engineering providing a rectangular shape of QW's, is investigated. The Scanning Transmission Electron Microscopy (STEM) observations confirmed a high quality of interfaces and smooth change of the In-content in a rectangular shape QW. Micro-Raman experiment enabled to detect interface phonons in DQWs which are manifested in Magnetophonon Resonance. This contribution of interface phonons in the electron magneto-transport is important because as could be expected, the role of these phonons will increase in case of electron transport in the Double Quantum Wires fabricated from DQWs investigated.
ABSTRACT
In the HgCdTe (MCT) alloys, a zero-gap state E(g)=Gamma(6)-Gamma(8)=0 may occur as the composition varies from HgTe to CdTe. This singular mechanism of the E(g) variation may be triggered by an external pressure or by a temperature. In this Letter, we present experimental data of the optical reflectivity in the far-infrared (FIR) domain in a wide interval of temperature (from 10 to 290 K) of the Hg1-xCdxTe (x=0.115) samples. Since the intensity of classical IR sources drops abruptly in this spectral region, a brilliant synchrotron radiation FIR source has been used. The results clearly show that frequencies of the optical phonon modes exhibit discontinuity in their temperature dependence when a zero-gap state occurs.
