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1.
Nanoscale Adv ; 5(20): 5627-5640, 2023 Oct 10.
Article in English | MEDLINE | ID: mdl-37822899

ABSTRACT

Objective: hybrid nanofluids have superior thermal efficiency and physical durability in contrast to regular nanofluids. The stagnation point flow of MHD micropolar hybrid nanofluids over a deformable sheet with viscous dissipation is investigated. Methodology: the controlling partial differential equations are converted to nonlinear ordinary differential equations using the transmuted similarity, and are subsequently solved using the bvp4c solver in MATLAB. The hybrid nanofluids consist of aluminum and copper nanoparticles, dispersed in a base fluid of water. Results: multiple solutions are obtained in the given problem for the case of shrinking as well as for the stretching sheet due to the variation in several influential parameters. Non-unique solutions, generally, exist for the case of shrinking sheets. In addition, the first branch solution is physically stable and acceptable according to the stability analysis. The friction factor is higher for the branch of the first solution and lower in the second branch due to the higher magnetic parameters, while the opposite behavior is seen in the case of the local heat transfer rate. Originality: the novelty of this model is that it finds multiple solutions in the presence of Cu and Al2O3 nanoparticles and also performs the stability analysis. In general, non-unique solutions exist for the phenomenon of shrinking sheets.

2.
Nanotechnology ; 34(48)2023 Sep 14.
Article in English | MEDLINE | ID: mdl-37625394

ABSTRACT

The customization of hybrid nanofluids to achieve a particular and controlled growth rate of thermal transport is done to meet the needs of applications in heating and cooling systems, aerospace and automotive industries, etc. Due to the extensive applications, the aim of the current paper is to derive a numerical solution to a wall jet flow problem through a stretching surface. To study the flow problem, authors have considered a non-Newtonian Eyring-Powell hybrid nanofluid with water and CoFe2O4and TiO2nanoparticles. Furthermore, the impact of a magnetic field and irregular heat sink/source are studied. To comply with the applications of the wall jet flow, the authors have presented the numerical solution for two cases; with and without a magnetic field. The numerical solution is derived with a similarity transformation and MATLAB-based bvp4c solver. The value of skin friction for wall jet flow at the surface decreases by more than 50% when the magnetic fieldMA=0.2is present. The stream function value is higher for the wall jet flow without the magnetic field. The temperature of the flow rises with the dominant strength of the heat source parameters. The results of this investigation will be beneficial to various applications that utilize the applications of a wall jet, such as in car defrosters, spray paint drying for vehicles or houses, cooling structures for the CPU of high-processor laptops, sluice gate flows, and cooling jets over turbo-machinery components, etc.

3.
Materials (Basel) ; 16(13)2023 Jun 26.
Article in English | MEDLINE | ID: mdl-37444917

ABSTRACT

The powder metallurgy method was used to manufacture three Ti-based alloys: Ti-15%Zr-2%Ta-4%Sn (Ti-Zr-Ta-4Sn), Ti-15%Zr-2%Ta-6%Sn (Ti-Zr-Ta-6Sn), and Ti-15%Zr-2%Ta-8%Sn (Ti-Zr-Ta-8Sn). Electrochemical measurements and surface analyses were used to determine the effect of Sn concentration on the corrosion of these alloys after exposure to a simulated body fluid (SBF) solution for 1 h and 72 h. It was found that the passivation of the alloy surface significantly increased when the Sn content increased from 4% to 6% and then to 8%, which led to a significant reduction in corrosion. The impedance spectra derived from the Nyquist graphs also explained how the addition of Sn significantly improved the alloys' polarization resistances. According to the change in the chronoamperometric current at an applied anodic potential over time, the increase in Sn content within the alloy significantly reduced the currents over time, indicating that the uniform and pitting corrosion were greatly decreased. The formation of an oxide layer (TiO2), which was demonstrated by the surface morphology of the alloys after exposure to SBF solution for 72 h and corrosion at 400 mV (Ag/AgCl) for 60 min, was supported by the profile analysis obtained by an X-ray spectroscopy analyzer. It was clear from all of the findings that the tested alloys have a remarkable improvement in resistance to corrosivity when the Sn content was increased to 8%.

4.
Materials (Basel) ; 16(13)2023 Jul 04.
Article in English | MEDLINE | ID: mdl-37445127

ABSTRACT

Zirconia (ZrO2) nanoparticles (1-3 wt.%) were incorporated into the epoxy matrix using the ultra-sonication mixing method of dispersion to manufacture nanocomposite coatings. An automatic applicator was used to prepare the coating samples on a stainless steel substrate. The influence of ZrO2 nanoparticles on the physicochemical characteristics of epoxy coatings was evaluated using energy dispersive X-ray spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FTIR), thermos-gravimetric analysis (TGA), elastic modulus, and micro-hardness measurement with the nano-indentation technique. The corrosion stability during immersion in 3.5% NaCl solution was monitored using electrochemical impedance spectroscopy (EIS). All ZrO2-containing coatings showed better corrosion stability and adhesion than pure epoxy coating. Epoxy coating incorporated with 2% ZrO2 exhibited the greatest values of corrosion resistance and adhesion due to the effect of nanoparticle properties and their better de-agglomeration in the epoxy matrix than pure epoxy coating.

5.
Materials (Basel) ; 16(10)2023 May 11.
Article in English | MEDLINE | ID: mdl-37241302

ABSTRACT

This work aims to study the influence of Al2O3 in CrFeCuMnNi high-entropy alloy matrix composites (HEMCs) on their microstructure, phase changes, and mechanical and wear performances. CrFeCuMnNi-Al2O3 HEMCs were synthesized via mechanical alloying (MA) followed by hot compaction (550 °C at 550 MPa), medium frequency sintering (1200 °C), and hot forging (1000 °C at 50 MPa). The XRD results demonstrate the formation of both FCC and BCC phases in the synthesized powders, which were transformed into major stable FCC and minor ordered B2-BCC phases, as confirmed by HRSEM. The microstructural variation of HRSEM-EBSD, in terms of the coloured grain map (inverse pole figures), grain size distribution, and misorientation angle, was analysed and reported. The grain size of the matrix decreased with the increase in Al2O3 particles owing to the higher structural refinement by MA and zener pinning of the incorporated Al2O3 particles. The hot-forged CrFeCuMnNi-3 vol.% Al2O3 sample exhibited an ultimate compressive strength of 1.058 GPa, which was 21% higher than that of the unreinforced HEA matrix. Both the mechanical and wear performance of the bulk samples increased with an increase in Al2O3 content due to solid solution formation, high configurational mixing entropy, structural refinement, and the effective dispersion of the incorporated Al2O3 particles. The wear rate and coefficient of friction values decreased with the increase in Al2O3 content, indicating an improvement in wear resistance owing to the lower domination of abrasive and adhesive mechanisms, as evidenced by the SEM worn surface morphology.

6.
Materials (Basel) ; 16(7)2023 Apr 05.
Article in English | MEDLINE | ID: mdl-37049185

ABSTRACT

In this study, AA5083-WC composites were developed by ball milling followed by hot consolidation. The microstructures of the developed composites were investigated using XRD, SEM, EDX, and EBSD. The developed composites exhibited a homogeneous dispersion of WC particulates in the AA5083 matrix without any interactions at the matrix/reinforcement interface. The results confirmed the development of a refined equiaxed grain structure of AA5083-WC composites where the EBSD results revealed an average grain size of 4.38 µm and 3.32 µm for AA5083-6%WC (AW-6) and AA5083-12%WC (AW-12) composites, respectively. The results showed that incorporating WC particulates in the AA5083 alloy matrix significantly improved the compressive stress-strain behaviour and considerably enhanced the resistance to wear and friction. The AA5083-12%WC (AW-12) composite displayed the maximum strength and the highest resistance to wear and friction, whereas the as-milled AA5083 alloy (AW-0) exhibited the lowest strength and the least resistance to wear and friction. The AA5083-12%WC (AW-12) composite exhibited the optimum mechanical and tribological behaviour of the developed composites, making it a promising candidate for tribological applications.

7.
Materials (Basel) ; 15(23)2022 Dec 01.
Article in English | MEDLINE | ID: mdl-36500058

ABSTRACT

Very often, pure Ti and (α + ß) Ti-6Al-4V alloys have been used commercially for implant applications, but ensuring their chemical, mechanical, and biological biocompatibility is always a serious concern for sustaining the long-term efficacy of implants. Therefore, there has always been a great quest to explore new biomedical alloying systems that can offer substantial beneficial effects in tailoring a balance between the mechanical properties and biocompatibility of implantable medical devices. With a view to the mechanical performance, this study focused on designing a Ti-15Zr-2Ta-xSn (where x = 4, 6, 8) alloying system with high strength and low Young's modulus prepared by a powder metallurgy method. The experimental results showed that mechanical alloying, followed by spark plasma sintering, produced a fully consolidated (α + ß) Ti-Zr-Ta-Sn-based alloy with a fine grain size and a relative density greater than 99%. Nevertheless, the shape, size, and distribution of α-phase precipitations were found to be sensitive to Sn contents. The addition of Sn also increased the α/ß transus temperature of the alloy. For example, as the Sn content was increased from 4 wt.% to 8 wt.%, the ß grains transformed into diverse morphological characteristics, namely, a thin-grain-boundary α phase (αGB), lamellar α colonies, and acicular αs precipitates and very low residual porosity during subsequent cooling after the spark plasma sintering procedure, which is consistent with the relative density results. Among the prepared alloys, Ti-15Zr-2Ta-8Sn exhibited the highest hardness (s340 HV), compressive yield strength (~1056 MPa), and maximum compressive strength (~1470). The formation of intriguing precipitate-matrix interfaces (α/ß) acting as dislocation barriers is proposed to be the main reason for the high strength of the Ti-15Zr-2Ta-8Sn alloy. Finally, based on mechanical and structural properties, it is envisaged that our developed alloys will be promising for indwelling implant applications.

8.
Materials (Basel) ; 15(24)2022 Dec 09.
Article in English | MEDLINE | ID: mdl-36556616

ABSTRACT

Ti-15%Zr alloy and Ti-15%Zr-2%Ta alloy were fabricated to be used in biomedical applications. The corrosion of these two alloys after being immersed in simulated body fluid for 1 h and 72 h was investigated. Different electrochemical methods, including polarization, impedance, and chronoamperometric current with time at 400 mV were employed. Also, the surface morphology and the compositions of its formed film were reported by the use of scanning electron microscope and energy dispersive X-ray. Based on the collected results, the presence of 2%Ta in the Ti-Zr alloy passivated its corrosion by minimizing its corrosion rate. The polarization curves revealed that adding Ta within the alloy increases the corrosion resistance as was confirmed by the impedance spectroscopy and current time data. The change of current versus time proved that the addition of Ta reduces the absolute current even at high anodic potential, 400 mV. The results of both electrochemical and spectroscopic methods indicated that pitting corrosion does not occur for both Ti-Zr and Ti-Zr-Ta alloys, even after their immersion in SBF solutions for 72 h.

9.
Sci Rep ; 12(1): 17419, 2022 10 19.
Article in English | MEDLINE | ID: mdl-36261589

ABSTRACT

The blood flow through stenotic artery is one of the important research area in computational fluid mechanics due to its application in biomedicine. Aim of this research work is to investigate the impact of nanoparticles on the characteristics of human blood flow in a stenosed blood artery. In under consideration problem Newtonian fluid is assumed as human blood. Newtonian fluid flows through large blood vessels (more than 300 µm). The constitutive equations together with the boundary conditions are diminished to non-dimensional form by using boundary layer approximation and similarity transfiguration to attain the solution of velocity and temperature distribution of blood flow through arterial stenosis numerically with the help of Matlab bvp4c. The results for physical quantities at cylindrical surface are calculated and their effects are also presented through tables. The heat transfer rate increases throughout the stenosed artery with the concentration of copper nanoparticle. Velocity curve decreases by increasing the values of flow parameter and nanoparticle volume fraction. Temperature curve increases due to increase in the values of nanoparticle volume fraction and decrease in Prandtl number.


Subject(s)
Copper , Nanoparticles , Humans , Hemodynamics , Arteries , Temperature
10.
Heliyon ; 8(10): e10835, 2022 Oct.
Article in English | MEDLINE | ID: mdl-36262296

ABSTRACT

Herein, we report the electropolymerization of crystal violet (CRV) on a bare glassy carbon electrode (GCE) for the detection of adrenaline (AD). Electropolymerization parameters such as electrolyte pH, scan rate and monomer concentrations were optimized using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The characterization of CRV and poly(crystal violet) (PCV) was done using FT-IR, UV-visible spectroscopy and EIS. More importantly, the charge transfer resistance (Rct) and other EIS data recorded from the EIS of various forms of the poly(crystal violet) (PCV) modified glassy carbon electrode (GCE) in AD were used for identifying the best PCV modified electrode. Subsequent application of the electrode prepared at optimum conditions (PGCE) for AD detection using the square wave voltammetry (SWV) gave a limit of detection (LOD) of 2.86 µM over a linear range of 10.3-102.7 µM. This sensor also showed considerable stability, good AD recovery from the real sample (98.9%), and excellent reproducibility, making it a suitable analytical tool for AD detection at the micromolar level.

11.
J Mol Model ; 28(9): 254, 2022 Aug 11.
Article in English | MEDLINE | ID: mdl-35951104

ABSTRACT

Pyrimidine compounds have proven to be effective and efficient additives capable of protecting mild steel in acidic media. This class of organic compounds often functions as adsorption-type inhibitors of corrosion by forming a protective layer on the metallic substrate. The present study reports a computational study of forty pyrimidine compounds that have been investigated as sustainable inhibitors of mild steel corrosion in molar HCl solution. Quantitative structure property relationship was conducted using linear (multiple linear regression) and nonlinear (artificial neural network) models. Standardization method was employed in variable selection yielding five top chemical descriptors utilized for model development along with the inhibitor concentration. Multiple linear regression model yielded a fair predictive model. Artificial neural network model developed using k-fold cross-validation method provided a comprehensive insight into the corrosion protection mechanism of studied pyrimidine-based corrosion inhibitors. Using a multilayer perceptron with Levenberg-Marquardt algorithm, the study obtained the optimal model having a MSE of 8.479, RMSE of 2.912, MAD of 1.791, and MAPE of 2.648. The optimal neural network model was further utilized to forecast the protection capacities of nine non-synthesized pyrimidine derivatives. The predicted inhibition efficiencies ranged from 89 to 98%, revealing the significance of the considered chemical descriptors, the predictive capacity of the developed model, and the potency of the theoretical inhibitors.


Subject(s)
Quantitative Structure-Activity Relationship , Steel , Corrosion , Neural Networks, Computer , Pyrimidines , Steel/chemistry
12.
ACS Omega ; 7(23): 19193-19203, 2022 Jun 14.
Article in English | MEDLINE | ID: mdl-35721908

ABSTRACT

3,3'-Methylenedisalicylic acid (MDS) was synthesized and ascertained on the basis of elemental analyses (C, H) and spectral measurements (IR, mass, 1H NMR, and UV-vis). Moreover, the prepared MDS compound has been assayed for its antimicrobial action against the growth of fungi as well as Gram-positive and Gram-negative bacteria. The results demonstrated the possibility of its usefulness to restrain the growth of both fungi and bacteria, whereas MDS showed its best impact against Candida albicans. The inhibitive impact of MDS on the corrosion of aluminum (Al) in concentrated sodium chloride solution (3.5 wt % NaCl) has been investigated. The corrosion work was done by potentiodynamic cyclic polarization, electrochemical impedance spectroscopy, and chronoamperometric current-time measurements and complemented by scanning electron microscopy and energy-dispersive X-ray investigations. It was found that MDS molecules protect the aluminum against corrosion, and its ability increases with the increase of concentration from 5 × 10-5 to 1 × 10-4 M and further to 5 × 10-4 M. The electrochemical results were supported by the morphological analysis and proved that the presence of MDS inhibits the uniform and pitting corrosion of Al in the chloride solutions.

13.
Materials (Basel) ; 15(7)2022 Mar 31.
Article in English | MEDLINE | ID: mdl-35407894

ABSTRACT

The optimization of two different types of hardeners, namely polyaminoamine adduct (Aradur 450 BD) and polyamidoamine adduct (Aradur 3282 BD), with diglycidyle ether of bisphenol-A (DGEBA) epoxy resin was carried out. Three different stoichiometries of PA 450 to the epoxy resin to fabricate E-0, E-1, and E-2 coating samples and the other three of PA 3282 to the epoxy resin to fabricate F-0, F-1, and F-2 coating samples were coated on mild steel panels. All coated samples were characterized by scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and nanoindentation techniques. The electrochemical corrosion behavior of the fabricated coatings was investigated using electrochemical impedance spectroscopy (EIS) after various exposures in the climatic conditions in 3.5% NaCl solutions. It was found that the coatings possess almost identical thermal and mechanical properties. Moreover, the E-1 coating shows better corrosion resistance compared to E-0 and E-2 coatings. On the other hand, the F-1 coating was the most effective in significantly improving corrosion resistance. Overall, the addition of PA 450 and PA 3282 to some stoichiometries improves the corrosion resistance of the fabricated coatings.

14.
Nanomaterials (Basel) ; 12(2)2022 Jan 15.
Article in English | MEDLINE | ID: mdl-35055293

ABSTRACT

Colloidal suspensions of regular fluids and nanoparticles are known as nanofluids. They have a variety of applications in the medical field, including cell separation, drug targeting, destruction of tumor tissue, and so on. On the other hand, the dispersion of multiple nanoparticles into a regular fluid is referred to as a hybrid nanofluid. It has a variety of innovative applications such as microfluidics, heat dissipation, dynamic sealing, damping, and so on. Because of these numerous applications of nanofluids in minds, therefore, the objective of the current exploration divulged the axisymmetric radiative flow and heat transfer induced by hybrid nanofluid impinging on a porous stretchable/shrinkable rotating disc. In addition, the impact of Smoluchowski temperature and Maxwell velocity slip boundary conditions are also invoked. The hybrid nanofluid was formed by mixing the copper (Cu) and alumina (Al2O3) nanoparticles scattered in the regular (viscous) base fluid (H2O). Similarity variables are used to procure the similarity equations, and the numerical outcomes are achieved using bvp4c in MATLAB software. According to the findings, double solutions are feasible for stretching (λ>0) and shrinking cases (λ<0). The heat transfer rate is accelerated as the hybrid nanoparticles increases. The suction parameter enhances the friction factors as well as heat transfer rate. Moreover, the friction factor in the radial direction and heat transfer enrich for the first solution and moderate for the second outcome due to the augmentation δ1, while the trend of the friction factor in the radial direction is changed only in the case of stretching for both branches.

15.
Sci Rep ; 11(1): 23736, 2021 Dec 09.
Article in English | MEDLINE | ID: mdl-34887469

ABSTRACT

In this present article the entropy generation, induced magnetic field, and mixed convection stagnant point flow of pseudoplastic nano liquid over an elastic surface is investigated. The Buongiorno model is employed in modeling. Through the use of the boundary layer idea, flow equations are transformed from compact to component form. The system of equations is solved numerically. The Induced magnetic spectrum falls near the boundary and grows further away as the reciprocal of the magnetic Prandtl number improves. The fluctuation of induced magnetic rises while expanding the values of mixed convection, thermophoresis, and magnetic parameters, whereas it declines for increment in the Brownian and stretching parameters. The velocity amplitude ascends and temperature descends for the rise in magnetic parameter. The mass transfer patterns degrade for the higher amount of buoyancy ratio while it boosts by the magnification of mixed convection and stretching parameters. Streamlines behavior is also taken into account against the different amounts of mixed convection and magnetic parameters. The pseudoplastic nanofluids are applicable in all electronic devices for increasing the heating or cooling rate in them. Further, pseudoplastic nanofluids are also applicable in reducing skin friction coefficient.

16.
Sci Rep ; 11(1): 20030, 2021 Oct 08.
Article in English | MEDLINE | ID: mdl-34625588

ABSTRACT

In this article, the primary focus is to investigate the heat transfer effects with viscous compressible laminar flow in the permeable elliptic cylinder. The Reynolds number is kept 100 for flow to be laminar. The physics of heat transfer is selected to be coupled with the laminar flow. The results for particular step-size time for Velocity distribution, pressure profile, temperature profile, isothermal temperature contours, and drag coefficient have been analyzed. Mesh has been generated through COMSOL, mesh entities have been elaborated statistically. The maximum and minimum velocity profile is observed at the elliptical cylinder's walls and upper, lower boundary respectively. The maximum velocity observed is 2.22 m/s. Pressure profile around elliptic corners is found maximum, distinct patterns are observed even under the influence of applied heat. Temperature is observed maximum at walls but it gradually increases as moving from the upper boundary towards the lower boundary. The isothermal contour patterns are observed maximum near the walls, drag coefficient of gradual decrease is observed. COMSOL multi-physics is utilized for mathematical modeling of problems and the Backward-Differentiation-Formula has been exploited to handle problems numerically. The results will help greatly to understand the characterizations of viscous fluids and in industries like air furnaces and automobile cooling systems.

17.
Sci Rep ; 11(1): 17837, 2021 Sep 08.
Article in English | MEDLINE | ID: mdl-34497311

ABSTRACT

Stretched flows have numerous applications in different industrial, biomedical and engineering processes. Current research is conducted to examine the flow phenomenon of Prandtl fluid model over a moveable surface. The phenomenon of mass and thermal transportation is based on generalized theory of Cattaneo-Christov which considers the involvement of relaxation times. In addition to these, variable characteristics of thermal conductivity and diffusion coefficient are considered as a function of temperature. The physical problem in Cartesian coordinate system is modeled via boundary layer theory which yields a coupled system of partial differential equations. Group scaling transportation is applied to model these PDEs system. The converted equations have been approximated via optimal homotopic scheme. The efficiency and validity of used approach has been shown by computing the error analysis and establishing a comparative study. It is noted that the enhancement in magnetic parameter plays a controlling role for velocity field and it augment the concentration and temperature fields. Furthermore, increase in thermal relaxation parameter and Prandtl number maintains the fluid temperature.

18.
ACS Omega ; 6(22): 14525-14532, 2021 Jun 08.
Article in English | MEDLINE | ID: mdl-34124475

ABSTRACT

Corrosion of iron in sodium chloride (3.5% wt) solutions and its inhibition by ethanedihydrazide (EH) have been reported. Electrochemical impedance spectroscopy (EIS), cyclic potentiodynamic polarization (CPP), and change of current with time at -475 mV (Ag/AgCl) measurements were employed in this study. Scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) techniques were utilized to report surface morphology and elemental analysis, respectively. The presence of 5 × 10-5 M EH was found to inhibit the corrosion of iron, and the effect of inhibition profoundly increased with an increase in EH concentration up to 1 × 10-4 M and further to 5 × 10-4 M. The low values of corrosion current and high corrosion resistance, which were obtained from the EIS, CPP, and change of current with time experiments, affirmed the adequacy of EH as a corrosion inhibitor for iron. Surface investigations demonstrated that the chloride solution without EH molecules causes severe corrosion, while the coexistence of EH within the chloride solution greatly minimizes the acuteness of chloride, particularly pitting corrosion.

19.
Sci Rep ; 11(1): 12271, 2021 Jun 10.
Article in English | MEDLINE | ID: mdl-34112851

ABSTRACT

Matrix nanocomposites are high performance materials possessing unusual features along with unique design possibilities. Due to extraordinary thermophysical characteristic contained by these matrix nanocomposites materials they are useful in several areas ranging from packaging to biomedical applications. Being an environment friendly, utilization of nanocomposites offer new technological opportunities for several sectors of aerospace, automotive, electronics and biotechnology. In this regards, current pagination is devoted to analyze thermal features of viscous fluid flow between orthogonally rotating disks with inclusion of metallic matrix nanocomposite (MMNC) and ceramic matrix nanocomposites (CMNC) materials. Morphological aspects of these nanomaterials on flow and heat transfer characteristics has been investigated on hybrid viscous fluid flow. Mathematical structuring of problem along with empirical relations for nanocomposites materials are formulated in the form of partial differential equations and later on converted into ordinary differential expressions by using suitable variables. Solution of constructed coupled differential system is found by collaboration of Runge-Kutta and shooting methods. Variation in skin friction coefficient at lower and upper walls of disks along with measurement about heat transfer rate are calculated against governing physical parameters. Impact of flow concerning variables on axial, radial components of velocity and temperature distribution are also evaluated. Contour plots are also drawn to explore heat and thermal profiles. Comparison and critical analysis of MMNc and CMNc have been presented at lower and upper porous disks. Our computed analysis indicates that hybrid nanofluids show significant influence as compared to simple nanofluids with the permutation of the different shape factors.

20.
Polymers (Basel) ; 13(6)2021 Mar 11.
Article in English | MEDLINE | ID: mdl-33799586

ABSTRACT

Denture base materials need appropriate mechanical and tribological characteristics to endure different stresses inside the mouth. This study investigates the properties of poly(methyl methacrylate) (PMMA) reinforced with different low loading fractions (0, 0.2, 0.4, 0.6, and 0.8 wt.%) of hydroxyapatite (HA) nanoparticles. HA nanoparticles with different loading fractions are homogenously dispersed in the PMMA matrix through mechanical mixing. The resulting density, Compressive Young's modulus, compressive yield strength, ductility, fracture toughness, and hardness were evaluated experimentally; the friction coefficient and wear were estimated by rubbing the PMMA/HA nanocomposites against stainless steel and PMMA counterparts. A finite element model was built to determine the wear layer thickness and the stress distribution along the nanocomposite surfaces during the friction process. In addition, the wear mechanisms were elucidated via scanning electron microscopy. The results indicate that increasing the concentration of HA nanoparticles increases the stiffness, compressive yield strength, toughness, ductility, and hardness of the PMMA nanocomposite. Moreover, tribological tests show that increasing the nanoparticle weight fraction considerably decreases the friction coefficient and wear loss.

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