ABSTRACT
In this research, the dimensional catalysts of pure g-C3N4 photocatalysts (1D, 2D, and 3D) were investigated for the reduction of the highly toxic/carcinogenic Cr(VI) under visible light irradiation. The catalysts underwent explanation through various surface analysis techniques. According to the BET data, the specific surface area of the 3D catalyst was 1.3 and 7 times higher than those of the 2D and 1D CN catalysts, respectively. The 3D catalyst demonstrated superior performance, achieving an efficiency greater than 99% within 60 min under visible light irradiation in the presence of EDTA due to the abundance of active sites. The study also delved into the influence of factors such as the amount of EDTA-hole scavenger, pH, catalyst dosage, and temperature on the photocatalytic reduction of Cr(VI). Moreover, the 3D catalyst showed excellent reusability, maintaining an efficiency of more than 80% even after 10 cycles, and performed effectively in real water samples. The 3D CN catalyst, with its facile synthesis process, excellent visible light harvesting properties, high reduction efficiency that sustains over multiple cycles, and outstanding performance in real water samples, presents a significant advancement for practical applications in environmental remediation. This research contributes to a new understanding of developing efficient degradation methods for heavy metals in polluted water, highlighting the potential of 3D g-C3N4 catalysts in environmental cleanup efforts.
ABSTRACT
Biochar usage in soil remediation has turned out to be an enticing topic recently. Biochar, a product formed by pyrolysis of organic waste, which is rich in carbon, has the aptitude to ameliorate climate change by sequestering carbon while also enhancing soil quality and crop yields. Two-edged implications of biochar on soil amendment are still being discussed yet, clarity on the long-term implications of biochar on soil health and the environment is not yet achieved. As a result, it is crucial to systematically uncover the pertinent information regarding biochar remediation, as this can serve as a roadmap for future research on using biochar to remediate contaminated soils in mining regions. This review endeavors to bring forth run thoroughly the latest state of research on the use of biochar in soil remediation, along with its potential benefits, limitations, challenges, and future scope. By synthesizing existing literature on biochar soil remediation, this review aims to provide insights into the potential of biochar as a sustainable solution for soil remediation. Specifically, this review will highlight the key factors that influence the effectiveness of biochar for soil remediation and the potential risks associated with its use, as well as the current gaps in knowledge and future research directions.
