Extracellular biosynthesis of CuO-TiO2 nanocomposites using Alcaligenes aquatilis for the photodegradation of reactive and azo dyes under visible light irradiation.

In this study, CuO/TiO2 nanocomposites were biologically synthesized using cell-free supernatant (CFS) of Alcaligenes aquatilis growth culture by two-step synthesis method, one-pot method with sequential addition of precursors, and one-pot method with simultaneous addition of precursors. The one-pot method with simultaneous addition of precursors was found to be the best method for the synthesis in terms of degradation of reactive blue-220 (RB-220) and acid yellow-17 (AY-17) dyes under visible light irradiation. CuO/TiO2 nanocomposite was found to have the crystallite size of 14.7nm and the bandgap energy of 2.5 eV. The effect of synthesis parameters such as synthesis time, pH of CFS, and the ratio of Cu to Ti in the synthesis mixture on the photocatalytic degradation efficacy of these nanocomposite structures under visible light irradiation was studied. The optimum conditions for the synthesis of CuO/TiO2 nanocomposite particles by one-pot method with simultaneous addition of precursors were found to be pH 12 of CFS, synthesis duration of 24 h, and molar ratio of Cu to Ti in the synthesis mixture as 1:22 for RB-220 dye and 1:25 for AY-17 degradation. CuO/TiO2 nanocomposite particles synthesized under the optimum conditions and without any calcination could degrade RB-220 and AY-17 dyes completely in 120 min and 150 min, respectively. The kinetics of degradation of RB-220 and AY-17 by CuO@TiO2 nanocomposite particles followed first-order kinetic model with rate constant of 0.028 min-1 and 0.018 min-1, respectively.

Continuous fixed-bed adsorption of reactive azo dye on activated red mud for wastewater treatment-Evaluation of column dynamics and design parameters.

Continuous adsorption of Remazol Brilliant Blue (RBB) dye in water onto sulfuric acid activated red mud (CATRM) in a fixed bed column was investigated. Breakthrough curves were obtained experimentally by varying the bed height (Z), influent flow rate (Q), and dye concentration(C0). The adsorption efficiency in the removal of RBB was favored at lower C0, higher Z, and lower Q. The maximum adsorption capacity of the activated red mud bed in the column was obtained at C0 = 70 mg/L, Z = 8 cm, and Q = 5 mL/min and found to be 106 mg/g. Important parameters of column dynamics and design such as mass transfer zone (MTZ) and length of unused bed (LUB) were evaluated from the breakthrough curves. The MTZ and LUB have varied with varying Z, which indicated the existence of nonideal conditions. Thomas model was found to be valid to predict the column dynamics and the model parameters were evaluated. Bed depth service time (BDST) model parameters were evaluated to facilitate the determination of packed bed height for the design of packed bed adsorption column. The bed could be regenerated with NaOH solution with desorption efficiency decreasing from 83.8 to 55.72% from the first to third cycle. A fixed bed of CATRM can be effectively used for continuous dye removal from industrial wastewater.

Suspended and polycaprolactone immobilized Ag @TiO2/polyaniline nanocomposites for water disinfection and endotoxin degradation by visible and solar light-mediated photocatalysis.

In the present study, water contaminated with Escherichia coli (E. coli) cells was photocataytically disinfected using Ag core-TiO2 shell/Polyaniline nanocomposite (Ag@TiO2/PANI) under visible light irradiation. Ag@TiO2/PANI containing 13 weight % of Ag@TiO2 was found to offer maximum disinfection activity. Band gap energy of Ag@TiO2/PANI was found to be 2.58 eV. Ag@TiO2/PANI nanocomposites were efficient in water disinfection in their suspended and immobilized form. Rate of disinfection with Ag@TiO2/PANI was faster than that with Ag@TiO2 nanoparticles. Water containing 50 × 108 CFU/mL cells was completely disinfected within 120 min with 1 g/L Ag@TiO2/PANI nanocomposite. Simultaneous disinfection and endotoxins degradation were achieved. The photocatalytic disinfection of water and endotoxin degradation using Ag@TiO2/PANI nanocomposite under visible light irradiation followed second order kinetics. The nanocomposite also exhibited a good solar photocatalytic activity.

Auto-combustion synthesis of narrow band-gap bismuth ferrite nanoparticles for solar photocatalysis to remediate azo dye containing water.

Narrow band gap of ferrites makes it a good photocatalyst, and it plays very prominent role in the level of degradation of organic dyes by photocatalysis. In the current study, bismuth ferrite (BFO) nanoparticles were synthesized by auto-combustion technique. The synthesized BFO particles have the average crystallite size of 33 nm and band gap energy of 1.9 eV. As revealed by microscopic images, uniform, distinct, and hexahedral shaped BFO nanoparticles of 42.7 nm are formed. The BFO nanoparticles exhibited visible and solar light-mediated photocatalytic activity in degrading Acid Yellow-17. The optimum pH and catalyst loading were found to be pH 5 and 0.2 g/L respectively. Around complete degradation under solar and 95% degradation under visible light could be achieved within 135 min of irradiation. Around 85% and 83% chemical oxygen demand (COD) removal could also be achieved under solar and visible light respectively. The degradation followed first-order kinetics in terms of COD removal. The BFO nanoparticles are promising as solar light active catalysts for wastewater treatment.

Floating bed reactor for visible light induced photocatalytic degradation of Acid Yellow 17 using polyaniline-TiO2 nanocomposites immobilized on polystyrene cubes.

In the present study, PANI-TiO2 nanocomposites have been used in suspended and immobilized form for photocatalytic degradation of Acid Yellow 17 (AY-17) dye under visible light. PANI-TiO2 nanocomposites were immobilized in polystyrene cubes to form PANI-TiO2 @ polystyrene cubes. The nanocomposites were found to be visible light active both in suspended and immobilized form. PANI-TiO2 nanocomposite with 13% TiO2 loading was found to be the optimum in terms of maximum degradation of AY-17. The efficiency of floating bed photoreactor (FBR) operated in liquid recycle mode using PANI-TiO2 @ polystyrene cubes was studied. In this reactor, around 89% degradation of 1 L of AY-17 with an initial concentration of 10 mg/L could be achieved with 2.83 g/L per pass of immobilized catalyst. The FBR operated with PANI-TiO2 @ polystyrene cubes has exhibited good performance as a photocatalytic reactor and may be recommended over other conventional photo reactors for treatment of wastewater contaminated with synthetic dyes. The kinetics of degradation of AY-17 by photocatalysis under visible light with suspended PANI-TiO2 and PANI-TiO2 @ polystyrene cubes followed first-order kinetics. The values of apparent kinetic parameter for degradation by immobilized photocatalysts are lower than the corresponding kinetic parameter for suspended photocatalysts. It confirms the existence of diffusional limitations in photocatalysis by PANI-TiO2 @polystyrene cubes.

Solar light-driven photocatalysis using mixed-phase bismuth ferrite (BiFeO3/Bi25FeO40) nanoparticles for remediation of dye-contaminated water: kinetics and comparison with artificial UV and visible light-mediated photocatalysis.

Mixed-phase bismuth ferrite (BFO) nanoparticles were prepared by co-precipitation method using potassium hydroxide as the precipitant. X-ray diffractogram (XRD) of the particles showed the formation of mixed-phase BFO nanoparticles containing BiFeO3/Bi25FeO40 phases with the crystallite size of 70 nm. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed the formation of quasi-spherical particles. The BFO nanoparticles were uniform sized with narrow size range and with the average hydrodynamic diameter of 76 nm. The band gap energy of 2.2 eV showed its ability to absorb light even in the visible range. Water contaminated with Acid Yellow (AY-17) and Reactive Blue (RB-19) dye was treated by photocatalysis under UV, visible, and solar light irradiation using the BFO nanoparticles. The BFO nanoparticles showed maximum photocatalytical activity under solar light as compared to UV and visible irradiations, and photocatalysis was favored under acidic pH. Complete degradation of AY-17 dyes and around 95% degradation of RB-19 could be achieved under solar light at pH 5. The kinetics of degradation followed the Langmuir-Hinshelhood kinetic model showing that the heterogeneous photocatalysis is adsorption controlled. The findings of this work prove the synthesized BFO nanoparticles as promising photocatalysts for the treatment of dye-contaminated industrial wastewater.

Visible light-induced photocatalytic degradation of Reactive Blue-19 over highly efficient polyaniline-TiO2 nanocomposite: a comparative study with solar and UV photocatalysis.

Polyaniline-TiO2 (PANI-TiO2) nanocomposite was prepared by in situ polymerisation method. X-ray diffractogram (XRD) showed the formation of PANI-TiO2 nanocomposite with the average crystallite size of 46 nm containing anatase TiO2. The PANI-TiO2 nanocomposite consisted of short-chained fibrous structure of PANI with spherical TiO2 nanoparticles dispersed at the tips and edge of the fibres. The average hydrodynamic diameter of the nanocomposite was 99.5 nm. The band gap energy was 2.1 eV which showed its ability to absorb light in the visible range. The nanocomposite exhibited better visible light-mediated photocatalytic activity than TiO2 (Degussa P25) in terms of degradation of Reactive Blue (RB-19) dye. The photocatalysis was favoured under initial acidic pH, and complete degradation of 50 mg/L dye could be achieved at optimum catalyst loading of 1 g/L. The kinetics of degradation followed the Langmuir-Hinshelhood model. PANI-TiO2 nanocomposite showed almost similar photocatalytic activity under UV and visible light as well as in the solar light which comprises of radiation in both UV and visible light range. Chemical oxygen demand removal of 86% could also be achieved under visible light, confirming that simultaneous mineralization of the dye occurred during photocatalysis. PANI-TiO2 nanocomposites are promising photocatalysts for the treatment of industrial wastewater containing RB-19 dye.

Simultaneous adsorption of Remazol brilliant blue and Disperse orange dyes on red mud and isotherms for the mixed dye system.

The paper presents the adsorption of Remazol brilliant blue (RBB) and Disperse orange 25 (DO25) dyes from aqueous solution of the mixture of dyes onto concentrated sulphuric acid-treated red mud (ATRM). First-order derivative spectrophotometric method was developed for the analysis of RBB and DO25 in mixed dye aqueous solution to overcome the limitations arising due to interference in the zero-order spectral method. The optimum conditions to maximize RBB adsorption favoured the adsorption of RBB, and those for DO25 favoured DO25 adsorption from the mixed dye aqueous solutions. Presence of a second dye always inhibited the adsorption of a target dye. The uptake and percentage adsorption of each of the dyes onto ATRM from the aqueous solution of the mixture of dyes decreased considerably with increasing concentrations of the other dye showing the antagonistic effect. Monocomponent Langmuir isotherm fitted the mixed dye adsorption equilibrium data better than the monocomponent Freundlich isotherm. However, monocomponent models are suitable for the fixed concentration of the other dye. Modified Langmuir isotherm model adequately predicted the multi-component adsorption equilibrium data for RBB-DO25-ATRM adsorption system with a good accuracy and is more generic from the application point of view.