Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 2 de 2
Filter
Add more filters










Database
Language
Publication year range
1.
Chem Commun (Camb) ; 59(100): 14795-14798, 2023 Dec 14.
Article in English | MEDLINE | ID: mdl-38018815

ABSTRACT

We present an Ir complex that extracts electrons from H2 at room temperature and stores them as a H2-derived energy carrier (H2EC) at room temperature. Furthermore, we demonstrate that this complex reduces CO2 to a metal-CO22- species at room temperature, and present the first electrospray ionisation mass spectrum for this compound.

2.
RSC Adv ; 11(62): 39450-39454, 2021 Dec 06.
Article in English | MEDLINE | ID: mdl-35492457

ABSTRACT

This paper reports the first example of a reductive C(sp3)-C(sp3) homo-coupling of benzyl/allyl halides in aqueous solution by using H2 as an electron source {turnover numbers (TONs) = 0.5-2.3 for 12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble electron storage catalyst (ESC). The reaction mechanism, and four requirements to make it possible, are also described.

SELECTION OF CITATIONS
SEARCH DETAIL
...