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1.
RSC Adv ; 9(7): 3856, 2019 Jan 25.
Article in English | MEDLINE | ID: mdl-35532468

ABSTRACT

[This corrects the article DOI: 10.1039/C5RA23848J.].

2.
ACS Appl Mater Interfaces ; 5(18): 9186-93, 2013 Sep 25.
Article in English | MEDLINE | ID: mdl-24032539

ABSTRACT

Enhancement to the electrochemical performance of supercapacitor electrodes were realized by incorporating highly porous conductive polymer films prepared with solution-processed polyaniline. The resultant nanostructures contained characteristic pores measuring 30-150 nm. Such electrodes generated from a solution of polyaniline-camphorsulfonic acid (PANI/CSA) exhibited higher porosity and electro-catalytic activity than those generated from conventional PANI nanomaterials. These improvements were attributed to faster ion diffusion at the PANI electrode/electrolyte interface. The highest specific capacitance observed for a supercapacitor fabricated with a porous PANI electrode obtained was 361 F g(-1) at 0.25 A g(-1), which is more than twice that of an equivalent electrode made with pristine PANI. Furthermore, supercapacitors made with highly porous PANI electrodes exhibited high electrochemical stability and rate performances.

3.
Talanta ; 105: 333-9, 2013 Feb 15.
Article in English | MEDLINE | ID: mdl-23598027

ABSTRACT

Polyaniline (PANi) patterns on flexible substrate are fabricated for biomolecule detection from live cells. PANi patterns are prepared by inkjet printing on polyethylene terephthalate film. Subsequently, arginine-glycine-aspartate (RGD) peptide is immobilized on the PANi pattern to selectively adhere cells. Rat pheochromocytoma PC12 cells are cultured on the RGD-immobilized PANi pattern, and patterned with high selectivity and growth. Additionally, the cells show focal adhesion on the RGD-immobilized PANi pattern, which are confirmed with vinculin staining and scanning electron microscopic images. To monitor dynamic biomolecular release from PC12 cells, RGD-immobilized PANi pattern is used for a real-time electrical signal detector. RGD-immobilized PANi patterning and sensing system represents outstanding ability to translate and amplify exocytosis molecules into a detectable signal as a transducer.


Subject(s)
Aniline Compounds/chemistry , Exocytosis , Animals , Focal Adhesions , PC12 Cells , Rats
4.
Chem Commun (Camb) ; 49(43): 4887-9, 2013 May 28.
Article in English | MEDLINE | ID: mdl-23575448

ABSTRACT

An effective approach to fabricate graphene-based conductive films is explored on the basis of the pressure-assisted reduction technique.

5.
ChemSusChem ; 4(3): 363-8, 2011 Mar 21.
Article in English | MEDLINE | ID: mdl-21265026

ABSTRACT

It is a great challenge to develop solution-processed, polymeric hole-injection layers (HILs) that perform better than small molecular layers for realizing high-performance small-molecule organic light-emitting diodes (SM-OLEDs). We have greatly improved the injection efficiency and the current efficiency of SM-OLEDs by introducing conducting polymer compositions composed of polyaniline doped with polystyrene sulfonate and perfluorinated ionomer (PFI) as the HIL. During single spin-coating of conducting polymer compositions, the PFI layer was self-organized at the surface and greatly increased the film work function. It enhanced hole-injection efficiency and current efficiency by introducing a nearly ohmic contact and improving electron blocking. Our results demonstrate that solution-processed polyaniline HILs with tunable work functions are good candidates for reducing process costs and improving OLED performance.


Subject(s)
Aniline Compounds , Electric Conductivity , Electrochemical Techniques , Light , Electrons , Polymers , Polystyrenes , Solutions
6.
J Colloid Interface Sci ; 341(1): 83-7, 2010 Jan 01.
Article in English | MEDLINE | ID: mdl-19846105

ABSTRACT

Plasmonic photocatalytic nanostructured system was investigated on silver chloride/silver nanoparticles under visible light. Silver chloride/silver nanoparticles were readily prepared using dispersing agent and light irradiation. The d-spacing analysis, high resolution-transmission electron microscopy, X-ray diffraction analysis and diffuse-reflectance spectroscopy demonstrated that silver nanoparticles were introduced on the surface of silver chloride nanoparticles and then silver chloride/silver nanostructured photocatalytic materials were successfully synthesized. The as-synthesized plasmonic photocatalysts exhibited the enhanced photocatalytic performance over nitrogen-doped titania nanomaterials. The improved catalytic activity was originated from the enhanced adsorption for visible light, electron-hole separation, and the formation of chloride atoms in silver chloride/silver nanostructured materials.

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