Hydrodynamic behavior of bubbles at gas-evolving electrode in ultrasonic field during water electrolysis.

In electrochemical processes, gas bubbles on the electrode can cause an increase in both overpotential and ohmic voltage drop which leads to higher energy consumption. Applying power ultrasound during water electrolysis can help to reduce the overpotential, enhance mass transfer, and save energy. In this study, we investigated the effect of ultrasound (20 kHz) on the hydrogen evolution reaction (HER) on a stainless steel plate with varying concentrations of NaOH solutions at 298 K, using linear sweep voltammetry (LSV). We especially focused on understanding the bubble behavior on the stainless steel plate during HER using high-speed imaging in ultrasonic field. When ultrasound was applied to solutions with NaOH concentrations of 0.1, 0.5, 1 M, the current density increased by about 9.0, 5.9, 2.8 %, respectively. As the ultrasound irradiation began, the bubbles tended to hover around on the electrode surface, coalescing with other bubbles, rather than rising. When the size of the coalesced bubbles became too large to stay on the surface of the electrode, they were expelled from the ultrasonic field. The repeated collapse and coalescence of these bubbles was observed while they were rising. The velocity increased about 2 times when ultrasound irradiation began, and increased by more than 6 times in the ultrasonic field. More nucleation of bubbles was observed on the electrode in the ultrasonic field. Using ultrasound reduced the critical diameter of bubbles which detached from the electrode, from 58.0 to 15.9 µm, and the residence time of the bubbles, from 533 to 118 ms. Further, when the ultrasound was applied, the mean diameter of bubbles decreased from 71.8 to 17 µm. Hence, bubble coverage on the electrode surface decreased from 8.3 to 1 % despite an increase in the total number of bubbles. As a result, ultrasound was found to be effective for hydrogen production during water electrolysis, increasing current by the faster removal of gas from the stainless steel plate.

Non-uniform filtration velocity of process gas passing through a long bag filter.

Filtration velocity is one of the dominant parameters that determine the pressure drop through a bag filter. Experimental investigation of the air flow pattern around a bag filter inside a bag house is very difficult because of the complexity of the 3-D air flow. For this reason, we numerically investigated flow characteristics along a bag filter in detail. We newly found that the filtration velocity is non-uniform along the axial direction of a long bag filter when the height of the filter is greater than 10 m. The filtration velocity is very small at the bottom of the bag filter but very large at the top. For bag filter lengths of over 10 m, 70% of total inlet flow is filtered in just the top 30% of the long bag filter. This indicates that the top section of the long bag filter could deteriorate faster than the bottom section, making it necessary to develop a new method to avoid the problem. We developed an equation that can help predict the initial pressure drop across long bag filters with different heights, but identical filtration characteristics.

Preparation of TiO2-Decorated Boron Particles by Wet Ball Milling and their Photoelectrochemical Hydrogen and Oxygen Evolution Reactions.

TiO2-coated boron particles were prepared by a wet ball milling method, with the particle size distribution and average particle size being easily controlled by varying the milling operation time. Based on the results from X-ray photoelectron spectroscopy, transmission electron microscopy, energy dispersive X-ray analysis, and Fourier transform infrared spectroscopy, it was confirmed that the initial oxide layer on the boron particles surface was removed by the wet milling process, and that a new B-O-Ti bond was formed on the boron surface. The uniform TiO2 layer on the 150 nm boron particles was estimated to be 10 nm thick. Based on linear sweep voltammetry, cyclic voltammetry, current-time amperometry, and electrochemical impedance analyses, the potential for the application of TiO2-coated boron particles as a photoelectrochemical catalyst was demonstrated. A current of 250 µA was obtained at a potential of 0.5 V for hydrogen evolution, with an onset potential near to 0.0 V. Finally, a current of 220 µA was obtained at a potential of 1.0 V for oxygen evolution.

Application of Ni-Oxide@TiO2 Core-Shell Structures to Photocatalytic Mixed Dye Degradation, CO Oxidation, and Supercapacitors.

Performing diverse application tests on synthesized metal oxides is critical for identifying suitable application areas based on the material performances. In the present study, Ni-oxide@TiO2 core-shell materials were synthesized and applied to photocatalytic mixed dye (methyl orange + rhodamine + methylene blue) degradation under ultraviolet (UV) and visible lights, CO oxidation, and supercapacitors. Their physicochemical properties were examined by field-emission scanning electron microscopy, X-ray diffraction analysis, Fourier-transform infrared spectroscopy, and UV-visible absorption spectroscopy. It was shown that their performances were highly dependent on the morphology, thermal treatment procedure, and TiO2 overlayer coating.

Ultrasonication assisted production of silver nanowires with low aspect ratio and their optical properties.

We investigated a facial method to produce silver nanowires with low aspect ratio by fragmentizing as produced long silver nanowires. The length of silver nanowires can be shortened in a controllable manner by increasing ultrasonication time or ultrasonication power. However, excessively large ultrasonication power caused a problem of agglomeration of nanowires. From UV absorption spectra, it was found that the UV absorption characteristic of silver nanowires is not affected by ultrasonication assisted fragmentation indicating that one dimensional structure of silver nanowires is maintained during the fragmentation process.