1.
Angew Chem Int Ed Engl
; 37(3): 333-337, 1998 Feb 16.
Article
in English
| MEDLINE
| ID: mdl-29711270
ABSTRACT
A mechanical switch in a [2]catenane, made up of a cyclobis(paraquat-p-phenylene) tetracation interlocked with a macrocyclic polyether containing a redox-active tetrathiafulvalene (TTF) unit and a 1,5-dioxynaphthalene ring system, can be thrown either chemically or electrochemically. The neutral TTF unit resides "inside" the tetracationic cyclophane in the reduced state and "alongside" it in the oxidized species (TTF+ / TTF2+ ). Switching between the reduced (I4+ ) and oxidized state (I5+ (I6+ )) is accompanied by a dramatic color change.