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1.
ACS Nano ; 11(8): 8395-8400, 2017 08 22.
Article in English | MEDLINE | ID: mdl-28753312

ABSTRACT

Ionic liquid gating has a number of advantages over solid-state gating, especially for flexible or transparent devices and for applications requiring high carrier densities. However, the large number of charged ions near the channel inevitably results in Coulomb scattering, which limits the carrier mobility in otherwise clean systems. We develop a model for this Coulomb scattering. We validate our model experimentally using ionic liquid gating of graphene across varying thicknesses of hexagonal boron nitride, demonstrating that disorder in the bulk ionic liquid often dominates the scattering.

2.
ACS Nano ; 10(11): 10267-10274, 2016 11 22.
Article in English | MEDLINE | ID: mdl-27805356

ABSTRACT

Recently, epitaxially connected at facets semiconductor nanocrystals (NCs) have been introduced to fascilitate the electron transport between nanocrystals. To fully deploy their potential, a better understanding of the exciton transfer between connected NCs is needed. We go beyond the two well-known transfer mechanisms suggested by Förster and Dexter and propose a third mechanism of exciton tandem tunneling. The tandem tunneling occurs through the intermediate state in which the electron and hole are in different NCs. The corresponding rate for exciton hops is larger than the Dexter rate and for Si is even much larger that the Förster one.

3.
Phys Rev Lett ; 97(12): 128104, 2006 Sep 22.
Article in English | MEDLINE | ID: mdl-17026003

ABSTRACT

The current-voltage characteristics of the alpha-Hemolysin protein pore during the passage of single-stranded DNA under varying ionic strength C are studied experimentally. We observe strong blockage of the current, weak superlinear growth of the current as a function of voltage, and a minimum of the current as a function of C. These observations are interpreted as the result of the ion electrostatic self-energy barrier originating from the large difference in the dielectric constants of water and the lipid bilayer. The dependence of DNA capture rate on C also agrees with our model.


Subject(s)
Biophysics/methods , DNA/chemistry , Escherichia coli Proteins/chemistry , Hemolysin Proteins/chemistry , Ions , Anions , Cell Membrane Permeability , Electric Conductivity , Ion Channels/chemistry , Ions/chemistry , Lipid Bilayers/chemistry , Membrane Potentials , Nucleic Acid Conformation , Polymers/chemistry , Potassium/chemistry , Static Electricity , Temperature
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