Efficiency of Fabricated Adsorptive Polysulfone Mixed Matrix Membrane for Acetic Acid Separation.

The ultrafiltration mixed matrix membrane (UF MMMs) process represents an applicable approach for the removal of diluted acetic acid at low concentrations, owing to the low pressures applied. The addition of efficient additives represents an approach to further improve membrane porosity and, subsequently, enhance acetic acid removal. This work demonstrates the incorporation of titanium dioxide (TiO2) and polyethylene glycol (PEG) as additives into polysulfone (PSf) polymer via the non-solvent-induced phase-inversion (NIPS) method to improve the performance of PSf MMMs performance. Eight PSf MMMs samples designated as M0 to M7, each with independent formulations, were prepared and investigated for their respective density, porosity, and degree of AA retention. Morphology analysis through scanning electron microscopy elucidated sample M7 (PSf/TiO2/PEG 6000) to have the highest density and porosity among all samples with concomitant highest AA retention at approximately 92.2%. The application of the concentration polarization method further supported this finding by the higher concentration of AA solute present on the surface of the membrane compared to that of AA feed for sample M7. Overall, this study successfully demonstrates the significance of TiO2 and PEG as high MW additives in improving PSf MMM performance.

Effect of Graphene Oxide on the Properties of Polymer Inclusion Membranes for Gold Extraction from Acidic Solution.

The cyanidation leaching method is hazardous to the environment, but it is widely applied in the gold mining process because it is effective for gold extraction. This study fabricates polymer inclusion membranes (PIMs), which have environment-friendly properties, with graphene oxide (GO) as an alternative to the cyanidation leaching method for gold extraction. Poly(vinylidenefluoride-co-hexa-fluoropropylene)-based PIMs with different GO concentrations in five membranes (i.e., M1 (0 wt.%), M2 (0.5 wt.%), M3 (1.0 wt.%), M4 (1.5 wt.%), and M5 (2.0 wt.%)) are studied for their potential to extract gold from a hydrochloric acid solution. The membranes are prepared using di-(2-ethylhexyl) phosphoric acid as the extractant and dioctyl phthalate as the plasticizer. Scanning electron microscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis, ion exchange capacity, and water uptake are used to characterize the physical and chemical properties of the fabricated PIMs. The results show that the optimized membrane for gold extraction is M4 (1.5 wt.% GO), which yields a better performance on thermal stability, ion exchange capacity (IEC), and water uptake. M4 (1.5 wt.% GO) also exhibits a smooth and dense structure, with the maximum extraction efficiency obtained at 84.71% of extracted gold. In conclusion, PIMs can be used as an alternative for extracting gold with a better performance by the presence of 1.5 wt.% GO in membrane composition.

Fabrication and Characterisation of MWCNT/Polyvinyl (PVC) Polymer Inclusion Membrane for Zinc (II) Ion Removal from Aqueous Solution.

Heavy metal pollution has prompted researchers to establish the most effective method to tackle the impacts of heavy metals on living things and the environment, which include by applying nanoparticles. An example is the employment of multi-walled carbon nanotubes (MWCNTs) as an additive in an intermediate membrane or polymer inclusion membrane (PIM). The MWCNTs were added to enhance the properties and reinforce the transport performance of zinc (II) ion (Zn2+) removal from the source phase to the receiver phase by the PIMs. The present study constructed a membrane with a poly(vinyl chloride) (PVC)-based polymer, dioctyl phthalate (DOP) plasticiser, and bis-(2-ethylhexyl) phosphate (B2EHP) carrier incorporated with different concentrations of MWCNTs. The contact angle (CA), water uptake, ion exchange capacity (IEC), and porosity of the fabricated membranes were evaluated. The membrane was also characterised by employing scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and electrochemical impedance spectroscopy (EIS). Subsequently, the fabricated PIM (W1) and mixed matrix (MM)-PIM (W2−W5) samples were assessed under different parameters to acquire the ideal membrane composition and effectiveness. Kinetic modelling of Zn2+ removal by the fabricated PIMs under similar conditions was performed to reveal the mechanisms involved. The average removal efficiency of the membranes was >99% at different parameter conditions. Nevertheless, the W3 membrane with 1.0 wt% MWCNT immersed in a 5 mg/L initial Zn2+ concentration and 1.0 M receiver solution for seven hours at pH 2 demonstrated the highest percentage of Zn2+ removal. The experimental data were best fitted to the pseudo-first-order kinetic model (PFO) in kinetic modelling, and the permeability and flux of the W3 at optimum conditions were 0.053 m s−1 and 0.0532 mol m−2 s−1, respectively. In conclusion, the transport mechanism of Zn2+ was enhanced with the addition of the MWCNTs.

Gadolinium based contrast agents (GBCAs): Uniqueness, aquatic toxicity concerns, and prospective remediation.

The current toxicity concerns of gadolinium-based contrast agents (GBCAs) have birthed the need to regulate and, sometimes restrict its clinical administration. However, tolerable concentration levels of Gd in the water sector have not been set. Therefore, the detection and speedy increase of the anthropogenic Gd-GBCAs in the various water bodies, including those serving as the primary source of drinking water for adults and children, is perturbing. Nevertheless, the strongly canvassed risk-benefit considerations and superior uniqueness of GBCAs compared to the other ferromagnetic metals guarantees its continuous administration for Magnetic resonance imaging (MRI) investigations regardless of the toxicity concerns. Unfortunately, findings have shown that both the advanced and conventional wastewater treatment processes do not satisfactorily remove GBCAs but rather risk transforming the chelated GBCAs to their free ionic metal (Gd 3+) through inadvertent degradation processes. This unintentional water processing-induced GBCA dechelation leads to the intricate  pathway for unintentional human intake of Gd ion. Hence exposure to its probable ecotoxicity and several reported inimical effects on human health such as; digestive symptoms, twitching or weakness, cognitive flu, persistent skin diseases, body pains, acute renal and non-renal adverse reactions, chronic skin, and eyes changes. This work proposed an economical and manageable remediation technique for the potential remediation of Gd-GBCAs in wastewater, while a precautionary limit for Gd in public water and commercial drinks is advocated.

Characterization and Kinetic Studies of Poly(vinylidene fluoride-co-hexafluoropropylene) Polymer Inclusion Membrane for the Malachite Green Extraction.

Textile industry effluent contains a high amount of toxic colorants. These dyes are carcinogenic and threats to the environment and living beings. In this study, poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP) was used as the based polymer for PIMs with bis-(2-ethylhexyl) phosphate (B2EHP) and dioctyl phthalate (DOP) as the carrier and plasticizer. The fabricated PIMs were employed to extract the cation dye (Malachite Green; MG) from the feeding phase. PIMs were also characterized by scanning electron microscopy (SEM), atomic force microscope (AFM), contact angle, water uptake, Fourier-transform infrared spectroscopy (FTIR) and ions exchange capacity. The performance of the PIMs was investigated under various conditions such as percentage of carrier and initial dye concentration. With permeability and flux values of 0.1188 cm/min and 1.1913 mg cm/min, PIM produced with 18% w/w PVDF-co-HFP, 21% w/w B2EHP, 1% w/w DOP and 40% w/w THF and was able to achieve more than 97% of MG extraction. The experimental data were then fitted with a pseudo-second-order (PSO) model, and the calculated R2 value was ~0.99. This shows that the data has a good fit with the PSO model. PIM is a potential alternative technology in textile industry effluent treatment; however, the right formulation is crucial for developing a highly efficient membrane.

Removal of Humic Acid Using 3-Methacryloxypropyl Trimethoxysilane Functionalized MWCNT Loaded TiO2/PES Hybrid Membrane.

In the present work, a highly efficient mixed matrix membrane (MMM) for humic acid (HA) removal was developed. Multiwalled carbon nanotubes (MWCNTs) were functionalized in the presence of 3-methacryloxypropyl trimethoxysilane using the co-condensation method and were subsequently loaded with TiO2 (prepared via the sol-gel route). The as-prepared material was then incorporated into a PES polymer solution to prepare a fMWCNT-TiO2/PES hybrid membrane via non-solvent induced phase inversion. The microstructure of the membrane was characterized using Fourier transform infrared spectroscopy, atomic force microscopy, scanning electron microscopy, water contact angle, thickness, porosity, and pore size. The fMWCNT-TiO2/PES hybrid membrane was tested for the removal of HA and antifouling performance. The results show that the surface hydrophilicity of the membranes was greatly improved upon the addition of the fMWCNT-TiO2 particles. The results show that 92% of HA was effectively removed after 1 h of filtration. In comparison with pristine membrane, the incorporation of fMWCNT-TiO2 nanoparticles led to enhanced pure water flux (99.05 L/m2 h), permeate flux (62.01 L/m2 h), higher HA rejection (92%), and antifouling improvement (RFR: 37.40%, FRR: 86.02%). Thus, the fMWCNT-TiO2/PES hybrid membrane is considered to be a great potential membrane for the improvement of ultrafiltration membranes.

A Review on Haematococcus pluvialis Bioprocess Optimization of Green and Red Stage Culture Conditions for the Production of Natural Astaxanthin.

As the most recognizable natural secondary carotenoid astaxanthin producer, the green microalga Haematococcus pluvialis cultivation is performed via a two-stage process. The first is dedicated to biomass accumulation under growth-favoring conditions (green stage), and the second stage is for astaxanthin evolution under various stress conditions (red stage). This mini-review discusses the further improvement made on astaxanthin production by providing an overview of recent works on H. pluvialis, including the valuable ideas for bioprocess optimization on cell growth, and the current stress-exerting strategies for astaxanthin pigment production. The effects of nutrient constituents, especially nitrogen and carbon sources, and illumination intensity are emphasized during the green stage. On the other hand, the significance of the nitrogen depletion strategy and other exogenous factors comprising salinity, illumination, and temperature are considered for the astaxanthin inducement during the red stage. In short, any factor that interferes with the cellular processes that limit the growth or photosynthesis in the green stage could trigger the encystment process and astaxanthin formation during the red stage. This review provides an insight regarding the parameters involved in bioprocess optimization for high-value astaxanthin biosynthesis from H. pluvialis.

Graphene Oxide-Doped Polymer Inclusion Membrane for Remediation of Pharmaceutical Contaminant of Emerging Concerns: Ibuprofen.

The application of polymer inclusion membranes (PIMs) for the aquatic remediation of several heavy metals, dyes, and nutrients has been extensively studied. However, its application in treating organic compounds such as Ibuprofen, an emerging pharmaceutical contaminant that poses potential environmental problems, has not been explored satisfactorily. Therefore, graphene oxide (GO) doped PIMs were fabricated, characterized, and applied to extract aqueous Ibuprofen at varied pH conditions. The doped PIMs were synthesized using a low concentration of Aliquat 336 as carrier and 0, 0.15, 0.45, and 0.75% GO as nanoparticles in polyvinyl chloride (PVC) base polymer without adding any plasticizer. The synthesized PIM was characterized by SEM, FTIR, physical, and chemical stability. The GO doped PIM was well plasticized and had an optimal Ibuprofen extraction efficiency of about 84% at pH of 10 and 0.75% GO concentration. Furthermore, the GO doped PIM's chemical stability indicates better stability in acidic solution than in the alkaline solution. This study demonstrates that the graphene oxide-doped PIM significantly enhanced the extraction of Ibuprofen at a low concentration. However, further research is required to improve its stability and efficiency for the remediation of the ubiquitous Ibuprofen in the aquatic environment.

Antifouling Properties of PES Membranes by Blending with ZnO Nanoparticles and NMP⁻Acetone Mixture as Solvent.

In this study, the antifouling properties of polyethersulfone (PES) membranes blended with different amounts of ZnO nanoparticles and a fixed ratio of N-methyl-2-pyrrolidone (NMP)-acetone mixture as a solvent were investigated. The properties and performance of the fabricated membranes were examined in terms of hydrophilicity, porosity, pore size, surface and cross-section image using scanning electron microscopy (SEM), surface roughness using atomic force microscopy (AFM), pure water flux, and humic acid filtration. Addition of ZnO as expected was found to improve the hydrophilicity as well as to encourage pore formation. However, the agglomeration of ZnO at a higher concentration cannot be avoided even when dissolved in a mixed solvent. The presence of highly volatile acetone contributed to the tight skin layer of the membrane which shows remarkable antifouling ability with the highest flux recovery ratio and negligible irreversible fouling. ZnO NPs in acetone/NMP mixed solvent shows an improvement in flux and rejection, but, the fouling resistance was moderate compared to the pristine membrane.