ABSTRACT
In the title compound, C29H23ClN2O, the 5-chloro-phenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76â (9)° between them. The ethyl-phenyl ring and the two phenyl rings subtend angles of 71.09â (7), 43.95â (5) and 36.53â (9)°, respectively, with the imidazole plane. An intra-molecular O-Hâ¯N hydrogen bond supports the mol-ecular conformation, and an inter-molecular C-Hâ¯O inter-action, originating from an ortho-phenyl H atom, stabilizes the packing arrangement. In addition, a weak C-Hâ¯π inter-action, also involving an ortho-phenyl H atom, is observed.
ABSTRACT
In the title compound, C10H13N5, the piperidine ring adopts a chair conformation with the exocyclic N-C bond in an axial orientation, and the dihedral angle between the mean planes of piperidine and pyrimidine rings is 49.57â (11)°. A short intra-molecular C-Hâ¯N contact generates an S(7) ring. In the crystal, N-Hâ¯N hydrogen bonds link the mol-ecules into (100) sheets and a weak aromatic π-π stacking inter-action is observed [centroid-centroid separation = 3.5559â (11)â Å] between inversion-related pyrimidine rings.
ABSTRACT
In the title compound, C31H26Cl2N2O, the 4,6-di-chloro-phenol and the imidazole rings are almost coplanar, with a dihedral angle of 8.89â (6)° between them and an intra-molecular O-Hâ¯N hydrogen bond occurs between the rings. The dihedral angles subtended by the tert-butyl-phenyl ring and the two phenyl rings with the imidazole ring are 85.18â (9), 81.22â (9) and 19.00â (8)°, respectively. The methyl groups of the tert-butyl grouping are disordered over two sets of sites in 0.589â (5):0.411â (5) ratio. In the crystal, inversion dimers linked by pairs of weak C-Hâ¯Cl inter-actions generate R 2 2(24) loops.