The First Discovery of Spherical Carborane Molecular Ferroelectric Crystals.

Carborane compounds, known for their exceptional thermal stability and non-toxic attributes, have garnered widespread utility in medicine, supramolecular design, coordination/organometallic chemistry, and others. Although there is considerable interest among chemists, the integration of suitable carborane molecules into ferroelectric materials remains a formidable challenge. In this study, we employ the quasi-spherical design strategy to introduce functional groups at the boron vertices of the o-carborane cage, aiming to reduce molecular symmetry. This approach led to the successful synthesis of the pioneering ferroelectric crystals composed of cage-like carboranes: 9-OH-o-carborane (1) and 9-SH-o-carborane (2), which undergo above-room ferroelectric phase transitions (Tc) at approximately 367 K and 347 K. Interestingly, 1 and 2 represent uniaxial and multiaxial ferroelectrics respectively, with 2 exhibiting six polar axes and as many as twelve equivalent polarization directions. As the pioneering instance of carborane ferroelectric crystals, this study introduces a novel structural archetype for molecular ferroelectrics, thereby providing fresh insights into the exploration of molecular ferroelectric crystals with promising applications.

Boosting tetracycline degradation of BaTiO3-based piezo-catalysts via modulating phase boundary and band structure.

Piezoelectric catalysis, which converts mechanical energy into chemical activity, has important applications in environmental remediation. However, the piezo-catalytic activity of various piezoelectric materials is limited by the weak piezoelectricity as well as the mismatched band-gap, leading to inefficient electron-hole pair generation and difficult carrier migration. Here, a simple strategy combining phase boundary and energy band structure modulation was innovatively proposed to enhance the piezo-catalytic activity of BaTiO3 ferroelectric by Ce ions selecting different doping sites. Thanks to the coexistence of tetragonal (P4mm) and orthorhombic (Amm2) phases effectively flattened the Gibbs free-energy and thus enhanced the piezoelectric activity, as well as suitable energy bandwidth facilitating the carrier migration were realized in the B-sites doped Ba(Ti0.95Ce0.05)O3. The degradation rate constant k of tetracycline (TC) was high to 30.56 × 10-3 min-1, which was 2.03 times higher than that of pure BaTiO3 and superior to most representative lead-free perovskite piezoelectric materials. Theoretical calculations validated that the charge density and high O2 and OH- adsorption energy on the Ba(Ti0.95Ce0.05)O3 surface promoted more efficient •O2- and •OH radicals conversion and bettered response to piezo-catalytic reaction. This work is important to design high-performance piezo-catalysts by synergistic regulation of phase boundary and energy band structure in perovskite materials for long-term antibiotic tetracycline removal.

Flexophotovoltaic Effect and Above-Band-Gap Photovoltage Induced by Strain Gradients in Halide Perovskites.

We have measured the flexophotovoltaic effect of single crystals of halide perovskites MAPbBr_{3} and MAPbI_{3}, as well as the benchmark oxide perovskite SrTiO_{3}. For halide perovskites, the flexophotovoltaic effect is found to be orders of magnitude larger than for SrTiO_{3}, and indeed large enough to induce photovoltages bigger than the band gap. Moreover, we find that in MAPbI_{3} the flexophotovoltaic effect is additional to a native bulk photovoltaic response that is switchable and ferroelectric-like. The results suggest that strain gradient engineering can be a powerful tool to modify the photovoltaic output even in already well-established photovoltaic materials.

Significant hydrogen generation via photo-mechanical coupling in flexible methylammonium lead iodide nanowires.

The flexoelectric effect, which refers to the mechanical-electric coupling between strain gradient and charge polarization, should be considered for use in charge production for catalytically driving chemical reactions. We have previously revealed that halide perovskites can generate orders of higher magnitude flexoelectricity under the illumination of light than in the dark. In this study, we report the catalytic hydrogen production by photo-mechanical coupling involving the photoflexoelectric effect of flexible methylammonium lead iodide (MAPbI3) nanowires (NWs) in hydrogen iodide solution. Upon concurrent light illumination and mechanical vibration, large strain gradients were introduced in flexible MAPbI3 NWs, which subsequently induced significant hydrogen generation (at a rate of 756.5 µmol g-1 h-1, surpassing those values from either photo- or piezocatalysis of MAPbI3 nanoparticles). This photo-mechanical coupling strategy of mechanocatalysis, which enables the simultaneous utilization of multiple energy sources, provides a potentially new mechanism in mechanochemistry for highly efficient hydrogen production.

Domain Matching Strategy for Orientation Control of van der Waals Epitaxial Perovskite Thin Films.

The advantages of van der Waals epitaxy have attracted great interest because they can meet the requirements that conventional epitaxy struggles to satisfy. The weak adatom-substrate interaction without directional covalent bonding drastically relaxes the lattice matching limitation. However, the weak adatom-substrate interaction also leads to ineffectiveness in directing the crystal growth structure, limiting it to one orientation in epitaxial growth. In this work, we propose a domain matching strategy to guide the perovskite-type crystal epitaxial growth on 2D substrates, and we have demonstrated selective deposition of highly (001)-, (110)-, and (111)-oriented epitaxial Fe4N thin films on mica substrates using applicable transition structure design. Our work makes it possible to achieve and control different orientations of van der Waals epitaxy on the same substrate.

Photoflexoelectric effect in halide perovskites.

Harvesting environmental energy to generate electricity is a key scientific and technological endeavour of our time. Photovoltaic conversion and electromechanical transduction are two common energy-harvesting mechanisms based on, respectively, semiconducting junctions and piezoelectric insulators. However, the different material families on which these transduction phenomena are based complicate their integration into single devices. Here we demonstrate that halide perovskites, a family of highly efficient photovoltaic materials1-3, display a photoflexoelectric effect whereby, under a combination of illumination and oscillation driven by a piezoelectric actuator, they generate orders of magnitude higher flexoelectricity than in the dark. We also show that photoflexoelectricity is not exclusive to halides but a general property of semiconductors that potentially enables simultaneous electromechanical and photovoltaic transduction and harvesting in unison from multiple energy inputs.

Three-dimensional macroporous graphene monoliths with entrapped MoS2 nanoflakes from single-step synthesis for high-performance sodium-ion batteries.

Layered metal sulfides (MoS2, WS2, SnS2, and SnS) offer high potential as advanced anode materials in sodium ion batteries upon integration with highly-conductive graphene materials. However, in addition to being costly and time-consuming, existing strategies for synthesizing sulfides/graphene composites often involve complicated procedures. It is therefore essential to develop a simple yet scalable pathway to construct sulfide/graphene composites for practical applications. Here, we highlight a one-step, template-free, high-throughput "self-bubbling" method for producing MoS2/graphene composites, which is suitable for large-scale production of sulfide/graphene composites. The final product featured MoS2 nanoflakes distributed in three-dimensional macroporous monolithic graphene. Moreover, this unique MoS2/graphene composite achieved remarkable electrochemical performance when being applied to Na-ion battery anodes; namely, excellent cycling stability (474 mA h g-1 at 0.1 A g-1 after 100 cycles) and high rate capability (406 mA h g-1 at 0.25 A g-1 and 359 mA h g-1 at 0.5 A g-1). This self-bubbling approach should be applicable to delivering other graphene-based composites for emerging applications such as energy storage, catalysis, and sensing.

Atomic-Scale Mechanism on Nucleation and Growth of Mo2C Nanoparticles Revealed by in Situ Transmission Electron Microscopy.

With a similar electronic structure as that of platinum, molybdenum carbide (Mo2C) holds significant potential as a high performance catalyst across many chemical reactions. Empirically, the precise control of particle size, shape, and surface nature during synthesis largely determines the catalytic performance of nanoparticles, giving rise to the need of clarifying the underlying growth characteristics in the nucleation and growth of Mo2C. However, the high-temperature annealing involved during the growth of carbides makes it difficult to directly observe and understand the nucleation and growth processes. Here, we report on the use of advanced in situ transmission electron microscopy with atomic resolution to reveal a three-stage mechanism during the growth of Mo2C nanoparticles over a wide temperature range: initial nucleation via a mechanism consistent with spinodal decomposition, subsequent particle coalescence and monomer attachment, and final surface faceting to well-defined particles with minimum surface energy. These microscopic observations made under a heating atmosphere offer new perspectives toward the design of carbide-based catalysts, as well as the tuning of their catalytic performances.