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Phys Chem Chem Phys
; 17(47): 31613-7, 2015 Dec 21.
Article
in English
| MEDLINE
| ID: mdl-26563566
ABSTRACT
The physico-chemical properties of liquid mixtures, in general, exhibit deviations from linear behaviour with respect to their composition, arising out of different types of cross-intermolecular interactions (both specific and non-specific). These specific and non-specific interactions can however be monitored to obtain the linear mixing in liquid mixtures using the pseudo-solvent methodology in such a manner that the interactions causing deviations from linearity are cancelled out and mixtures display linear behaviour.