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J Colloid Interface Sci ; 418: 292-9, 2014 Mar 15.
Article in English | MEDLINE | ID: mdl-24461848

ABSTRACT

Experiments were done to observe the coalescence of highly viscous liquid droplets (87 wt% glycerin-in-water solutions) deposited onto a flat, solid steel plate. Droplets were deposited sequentially in straight lines or square droplet arrays. Droplet center-to-center distance was varied and the final dimensions of lines and sheets measured from photographs. When overlapping droplets were deposited surface tension forces pulled impacting droplets towards those already on the surface, a phenomena known as drawback. A dimensionless drawback index, quantifying the extent of droplet displacement, was calculated from experimental measurements for different values of droplet overlap. At large overlaps droplets deposited in a line or square array coalesced to form a circular film. When the droplet center-to-center distance increased, leading to less interaction, long, thin lines and square sheets were formed. As overlap was further decreased lines and sheets became discontinuous. A simple model was developed to predict the conditions under which rupture occurred. The lowest droplet overlap ratio (defined as droplet overlap distance divided by droplet spread diameter) at which a continuous liquid film could be formed was λ=0.293. At large overlap ratios (λ>0.6) droplets deposited in a square array formed a circular film. The minimum thickness of a continuous film formed by coalescence of droplets was shown to vary from 5% to 70% of the initial droplet diameter while increasing impact Weber and Reynolds number reduced the film thickness.

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