Bistatic, above-critical angle scattering measurements of fully buried unexploded ordnance (UXO) and clutter.

Laboratory grade bistatic scattering measurements are conducted in order to examine the acoustic response of realistic fully buried unexploded ordnance (UXO) from above-critical angle insonification, between 2 and 40 kHz. A 127 mm diameter rocket UXO, a 155 mm diameter artillery shell, a natural rock of approximately the same size, and a cinder block are fully buried in water-saturated medium grained sand (mean grain diameter, 240 µm) at depths of 10 cm below the water-sediment interface. A two-dimensional array of bistatic scattering measurements is generated synthetically by scanning a single hydrophone in steps of 3 cm over a 1 m × 1 m patch directly above the targets at a height of 20 cm above the water-sediment interface. Three-dimensional volumetric acoustic images generated from the return waveforms reveal scattering components attributed to geometric and elastic scattering, as well as multiple-scattering interactions of returns between the sediment-water interface and the buried objects. The far-field target strength of the objects is estimated through extrapolation of the angular spectrum. Agreement is found between experimental data and simulated data generated from a finite-element-based, three-dimensional time-harmonic model (2-25 kHz). Separation of the measured UXO from the clutter objects is demonstrated through exploitation of structural-acoustics-based features.

Left ventricular hypertrophy: reduction of blood pressure already in the normal range further regresses left ventricular mass.

OBJECTIVE: Left ventricular hypertrophy (LVH) confers high cardiovascular risk. Regression of LVH reduces risk. Patients with blood pressure in the normal range and LVH are common. We investigated whether further reduction in blood pressure would further regress LVH. METHODS: 51 subjects with blood pressure in the normal range and echocardiographic left ventricular hypertrophy were randomly assigned to active treatment (antihypertensive medication) or placebo in a ratio of 2:1. The aim was to maintain office systolic blood pressure at 10 mm Hg less than baseline in the active arm and at baseline level in the placebo arm. Cardiac magnetic resonance imaging was used to measure change in left ventricular mass index over 12 months. RESULTS: 35 subjects completed the study (active 23: placebo 12). Average mean baseline office systolic blood pressure was 122 (SD 9) mm Hg in the active group and 124 (9) mm Hg in the placebo group (p = 0.646). The mean baseline left ventricular mass index was 65.88 (11.87) g/m(2) in the active group and 59.16 (11.13) g/m(2) in the placebo group (p = 0.114). The mean difference between baseline and end of study office systolic blood pressure was -9.33 (8.56) mm Hg in the active group and -0.08 (9.27) mm Hg in the placebo group (p = 0.007). The mean change in left ventricular mass index was -4.68 (7.31) g/m(2) in the active group and +1.97 (6.68) g/m(2) in the placebo group (p = 0.014). CONCLUSIONS: Reduction in office systolic blood pressure, already in the normal range, of approximately 9 mm Hg, leads to a reduction in left ventricular mass. Further work is required to see if this also leads to a reduction in cardiovascular events. TRIAL REGISTRATION NUMBER: ISRCTN48331653.

Laboratory investigations of enhanced sulfate reduction as a groundwater arsenic remediation strategy.

Landfills have the potential to mobilize arsenic via induction of reducing conditions in groundwater and subsequent desorption from or dissolution of arsenic-bearing iron phases. Laboratory incubation experiments were conducted with materials from a landfill where such processes are occurring. These experiments explored the potential for induced sulfate reduction to immobilize dissolved arsenic in situ. The native microbial community at this site reduced sulfate in the presence of added acetate. Acetate respiration and sulfate reduction were observed concurrent with dissolved iron concentrations initially increasing from 0.6 microM (0.03 mg L(-1)) to a maximum of 111 microM (6.1 mg L(-1)) and subsequently decreasing to 0.74 microM (0.04 mg L(-1)). Dissolved arsenic concentrations initially covaried with iron but subsequently increased again as sulfide accumulated, consistent with the formation of soluble thioarsenite complexes. Dissolved arsenic concentrations subsequently decreased again from a maximum of 2 microM (148 microg L(-1)) to 0.3 microM (22 microg L(-1)), consistent with formation of sulfide mineral phases or increased arsenic sorption at higher pH values. Disequilibrium processes may also explain this second arsenic peak. The maximum iron and arsenic concentrations observed in the lab represent conditions most equivalent to the in situ conditions. These findings indicate that enhanced sulfate reduction merits further study as a potential in situ groundwater arsenic remediation strategy at landfills and other sites with elevated arsenic in reducing groundwater.

Refuse incinerator particulate emissions and combustion residues for New York City during the 20th century.

Refuse incineration data for New York City (NYC) have been compiled as a function of time during the 20th century to assess the historical significance of this pollutant source in a densely populated area. Thirty-two municipal and 17,000 apartment house refuse incinerators were identified. Approximately 1.1 x 10(8) t of refuse (wet weight) were combusted in NYC incinerators between 1908 and 1993, producing 3.4 x 10(7) t(dryweight) of combustion residue disposed in local landfills. Refuse incinerators were operated for most of this period without air pollution control and emitted 1.0 x 10(6) t of particles (a total of 120 mg for each cm2 of land in NYC). Incinerator particle emission (PE) rates per unit area of land were highest in Manhattan (equivalent total deposition of 530 mg cm(-2)). Incinerator PE exceeded 1.2 x 10(4) t yr(-1) between 1930 and 1975, with maximum emission rates (>2.2 x 10(4) t yr(-1)) in the late 1930s and 1960s. These and other factors support the conclusion that refuse incineration without air pollution control was an important source of airborne, respirable pollutants in NYC for many decades during the 20th century. Rates of particle emissions from Manhattan incinerators estimated here correlate stronglywith Pb accumulation rates as a function of depth (time) in Central Park Lake sediments, consistent with refuse incineration emitting large amounts of atmospheric lead in NYC for many decades afterthe 1920s.

Trends in chlorinated hydrocarbon levels in Hudson River basin sediments.

Analysis of sections from dated sediment cores were used to establish geographic distributions and temporal trends of chlorinated hydrocarbon contaminant levels in sediments from natural waters of the Hudson River basin. Radiometric dating was based primarily on the depth distribution of 137(Cs) in the cores and on the occurrence of detectable levels of 7(Be) in surface sediment samples. Eighteen sampling sites included several along the main stem of the Hudson, its major tributaries, and components of the New York/New Jersey (NY/NJ) harbor complex. Drinking-water reservoirs were sampled to place upper limits on atmospheric inputs. Core sections were analyzed for polychlorinated biphenyls (PCBs), 1,1,1-trichloro-2,2-bis(p-chlorophenyl) ethane (DDT)-derived compounds, chlordane, and dioxins. Sediment concentrations of most contaminants at most sites have decreased significantly since the mid-1960s. The data provide a basinwide perspective on major point-source inputs of PCBs to the upper Hudson River and of 2,3,7,8-tetrachlorodibenzo-p-dioxin and DDT to the lower Passaic River. Evidence was found for significant but poorly characterized sources of PCBs and chlordane to the western NY/NJ harbor, and of highly chlorinated dioxins to the upstream sites on the main stem of the Hudson. The results indicate that analysis of dated sediment samples is a most effective and efficient monitoring tool for the study of large-scale geographic and temporal trends in levels of particle-associated contaminants.

E(6) diffraction catastrophe of the primary rainbow of oblate water drops: observations with white-light and laser illumination.

Oblate drops of water illuminated perpendicular to their symmetry axis exhibit catastrophe patterns near the primary-rainbow scattering angle. Previous patterns include the hyperbolic umbilic focal section and separate lips events [see, e.g., H. J. Simpson and P. L. Marston, Appl. Opt. 30, 3468 (1991)]. The present observations concern a much higher-order singularity analyzed by J. F. Nye [Proc. R. Soc. London Ser. A 438, 397 (1992)], the E(6) or symbolic umbilic, in the scattering by levitated drops with monochromatic and collimated white-light illumination. Photographs show the colors produced when the drop is illuminated by white light. The E(6) occurs when the Gaussian curvature of the scattered wave front vanishes in both principal directions, resulting in a high degree of directional focusing. This type of focusing, although only slightly explored, is applicable to the more general problem of scattering from penetrable spheroids.

Scattering of white light from levitated oblate water drops near rainbows and other diffraction catastrophes.

Oblate drops of water illuminated perpendicular to their symmetry axis generate a hyperbolic-umbilic diffraction catastrophe near the primary rainbow [P. L. Marston and E. H. Trinh, Nature London 312, 529-531 (1984)]. Observations were made of this diffraction catastrophe generated by white-light illumination of acoustically levitated drops of water in air. The observations suggest what generalized rainbows would look like if they were produced in nature when sunlight illuminates large raindrops. Unlike the usual rainbow arc, the transverse cusp of the unfolded catastrophe is not distinctly colored. The hyperbolic-umbilic focal section is distinctly colored as is another diffraction catastrophe generated in the rainbow region when the drop is highly oblate.

Radionuclides in mono lake, california.

Several radioisotopes of the naturally occurring uranium and thorium decay series, in addition to fallout plutonium, have unusually high concentrations in the water column of Mono Lake, a natural alkaline, saline lake. Complexing by carbonate ions appears to be responsible for the enhanced solubility of actinide elements with oxidation states of IV to VI. In contrast, fallout strontium-90 has been largely removed from the water, probably as a result of coprecipitation with calcium carbonate. The daughter/parent activity ratios of thorium, radium, and uranium isotopes suggest that thorium is removed from the water column to the sediments on time scales substantially longer than a month and that the desorption of thorium from the sediments to the water column requires less than a few years.

Fallout plutonium in an alkaline, saline lake.

Plutonium isotopes, derived from global fallout following atmospheric testing of nuclear weapons, have been measured in the water and sediments of a natural alkaline, saline lake. The activities of fallout plutonium in the water column are about two orders of magnitude greater than in most freshwater lakes, where these nuclides are found predominantly in the sediments.

Fate of fossil fuel carbon dioxide and the global carbon budget.

The fate of fossil fuel carbon dioxide released into the atmosphere depends on the exchange rates of carbon between the atmosphere and three major carbon reservoirs, namely, the oceans, shallow-water sediments, and the terrestrial biosphere. Various assumptions and models used to estimate the global carbon budget for the last 20 years are reviewed and evaluated. Several versions of recent atmosphere-ocean models appear to give reliable and mutually consistent estimates for carbon dioxide uptake by the oceans. On the other hand, there is no compelling evidence which establishes that the terrestrial biomass has decreased at a rate comparable to that of fossil fuel combustion over the last two decades, as has been recently claimed.

Man-made radionuclides and sedimentation in the Hudson River estuary.

Recently deposited fine-grained sediments in the Hudson River estuary contain radionuclides from global fallout produced by atmospheric bomb tests as well as from low-level releases of a local nuclear reactor. Accumulation rates of these nuclides are dependent on rates of sediment deposition and vary with location in the estuary by more than two orders of magnitude. Within the Hudson estuary, New York harbor is currently the zone of most rapid deposition of sediments containing radionuclides, some of which were released from a nuclear reactor about 60 kilometers upstream of the harbor.