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1.
J Chem Phys ; 161(4)2024 Jul 28.
Article in English | MEDLINE | ID: mdl-39051832

ABSTRACT

A novel phenomenon is described that enables the control of the flux of free electrons through a resonance tunneling diode (RTD) via coupling the RTD to a quantized electromagnetic mode in a dark cavity. As the control parameter, one uses here the distance between the two cavity mirrors (which are set to oscillate in time). The effect is illustrated by carrying out standard scattering calculations of the electron flux. However, the only efficient way to rationalize the phenomenon and to be able to select the proper distance between the two cavity mirrors is to employ non-Hermitian quantum mechanics and the language of discrete resonance poles of the scattering matrix. The demonstrated ability to control the flux of free electrons by using a dark cavity might open a new field of research and development of controllable RTD devices.

2.
Phys Rev Lett ; 131(4): 040401, 2023 Jul 28.
Article in English | MEDLINE | ID: mdl-37566852

ABSTRACT

We consider the dynamics of a quantum system immersed in a dilute gas at thermodynamic equilibrium using a quantum Markovian master equation derived by applying the low-density limit technique. It is shown that the Gibbs state at the bath temperature is always stationary while the detailed balance condition at this state can be violated beyond the Born approximation. This violation is generically related to the absence of time-reversal symmetry for the scattering T matrix, which produces a thermalization mechanism that allows the presence of persistent probability and heat currents at thermal equilibrium. This phenomenon is illustrated by a model of an electron hopping between three quantum dots in an external magnetic field.

3.
Phys Rev Lett ; 125(2): 020401, 2020 Jul 10.
Article in English | MEDLINE | ID: mdl-32701313

ABSTRACT

We introduce a complex-extended continuum level density and apply it to one-dimensional scattering problems involving tunneling through finite-range potentials. We show that the real part of the density is proportional to a real "time shift" of the transmitted particle, while the imaginary part reflects the imaginary time of an instantonlike tunneling trajectory. We confirm these assumptions for several potentials using the complex scaling method. In particular, we show that stationary points of the potentials give rise to specific singularities of both real and imaginary densities which represent close analogues of excited-state quantum phase transitions in bound systems.

4.
Phys Rev Lett ; 124(25): 253202, 2020 Jun 26.
Article in English | MEDLINE | ID: mdl-32639760

ABSTRACT

According to the familiar Breit-Wigner formula, tunneling through a potential barrier is strongly enhanced when the energy of the projectile is equal to the resonance energy. Here we show how a weak continuous wave laser can qualitatively change the character of resonance tunneling, and enforce a sudden and total suppression of the transmission by inducing an exceptional point (EP, special non-Hermitian degeneracy). Our findings are relevant not only for laser control of transmission in the resonance tunneling diodes, but also in the context of electron scattering through any type of metastable (e.g., autoionization, Auger, intermolecular Coulombic decay) atomic or molecular states, and even in the case of transmission of light or sound waves in active systems with gain and loss.

5.
J Phys Chem A ; 116(11): 2636-43, 2012 Mar 22.
Article in English | MEDLINE | ID: mdl-22043872

ABSTRACT

In previous publications (J. Phys. B: At., Mol. Opt. Phys.2008, 41, 221001; J. Phys. B: At., Mol. Opt. Phys. 2011, 44, 045603) a novel and physically interesting phenomenon was found in the field of light-matter interactions. It was shown theoretically that exposing a molecule to a laser field can give rise to the appearance of so-called light-induced conical intersections (LICIs). The existence of such LICIs may change significantly the field free physical properties of a molecular system. In this article we review the LICIs in diatomics and provide a new insight to the LICI phenomenon. The sodium dimer is chosen as an explicit sample system. We calculated the Berry phase for a contour that surrounds the point of LICI and found it to be π, which is the same value as for the case of a "natural" CI in triatomic or larger molecules. We also present results to stress the impact of LICIs on molecular wave packet dynamics and molecular alignment in different electronic states.

6.
Phys Rev Lett ; 101(16): 163002, 2008 Oct 17.
Article in English | MEDLINE | ID: mdl-18999663

ABSTRACT

The dc field Stark effect is studied theoretically for atoms in high intensity laser fields. We prove that the first-order perturbation corrections for the energy and photoionization rate vanish when the dc field strength serves as a perturbational strength parameter. Our calculations show that by applying a dc field in the same direction as the polarization direction of the ac field, the photoinduced ionization rate is almost entirely suppressed. This suppression is attributed to changes in the phase shift of the continuum atomic wave functions which can be controlled by the dc field.

7.
J Phys Chem A ; 110(16): 5561-71, 2006 Apr 27.
Article in English | MEDLINE | ID: mdl-16623490

ABSTRACT

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to a variety of specific applications, such as alignment or orientation of molecules by lasers, trapping of ultracold molecules in optical traps, molecular optics and interferometry, rovibrational spectroscopy of molecules in the presence of intense laser light, or generation of high order harmonics from molecules. Starting from the first quantum mechanical principles, we derive an appropriate molecular Hamiltonian suitable for description of the center of mass, rotational, vibrational, and electronic molecular motions driven by the field within the electric dipole approximation. Consequently, the concept of the Born-Oppenheimer separation between the electronic and the nuclear degrees of freedom in the presence of an electromagnetic field is introduced. Special cases of the dc/ac-field limits are then discussed separately. Finally, we consider a perturbative regime of a weak dc/ac field, and obtain simple analytic formulas for the associated Born-Oppenheimer translational/rotational/vibrational molecular Hamiltonian.

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