ABSTRACT
In the present age of industrialization, oil contamination in the waste water has become a huge global concern due to its several negative impacts on human health and aquatic ecosystem. In order to address this problem, a novel oleophobic and super-hydrophilic graphene-based membrane has been developed using simple and cost-effective vacuum filtration methodology. Prior developing the membranes, the graphene oxide (GO) sheets were crosslinked with tannic acid (TA) molecules in order to improve their mechanical and surface properties. To obtain the structural and morphological information of the membranes and their constituents, Field Emission Scanning Electron (FE-SEM) microscopy, X-Ray Diffraction (XRD), FTIR spectroscopy and Raman spectroscopy was used. When tested with simulated oilfield effluent samples, these membranes exhibited significant reduction in the values of chemical oxygen demand (COD), total dissolved solids (TDS), total suspended solids (TSS) and turbidity demonstrating low-oil adhesion and preferable oil rejection rates. Moreover, such crosslinked membranes are highly stable which can withstand the pressure of water filtration. In such a way, TA crosslinked GO membranes present a robust and efficient way to treat oil contaminated water released from various industries which can be reused for numerous further applications.
