Intracavity absorption spectroscopy of HCl isotopes, H2O, CH4, C2H4, and C2H6 in the 3.1-3.4 µm spectral range using a Cr:CdSe laser.

We demonstrate the first application of a Cr:CdSe laser for highly-sensitive multicomponent intracavity absorption spectroscopy around λ = 3.1-3.4 µm. A detection scheme based on an integrated recording of multiple (∼70) individual Cr:CdSe laser pulses after a single pump-pulse excitation is reported. The sensitivity of our system corresponds to an effective absorption path length of Leff ≈ 850 m. Exemplary measurements of atmospheric H2O and CH4, and additionally introduced gas-phase HCl, C2H4, or C2H6 are presented. The achieved noise-equivalent detection limits are in the ppb range. Possibilities for further sensitivity enhancement by up to a factor of 104 are discussed.

Room-temperature Fe:ZnSe laser tunable in the spectral range of 3.7-5.3†µm applied for intracavity absorption spectroscopy of CO2 isotopes, CO and N2O.

We demonstrate an intracavity absorption spectroscopy system based on a broadband single-crystal pulsed Fe:ZnSe laser. The laser operates at room-temperature and is continuously tunable in the spectral range of 3.76-5.29 µm. The long-wavelength emission up to 5.29 µm is a record achievement for Fe:ZnSe lasers, to the best of our knowledge. The developed laser system is applied for measurements of gaseous absorption inside the laser resonator. We demonstrate sensitive detection of (i) CO2 isotopes in the atmosphere and in human breath, (ii) CO in breath (after cigarette smoking) and in the smoke of a smoldering paper, and (iii) N2O in a gas flow. The achieved detection limits are: 0.1 ppm for 12CO2 and 13CO2, 3 ppm for CO, and 1 ppm for N2O. The sensitivity of the current system is primarily limited by the short pump-pulse duration of 40 ns. Possibilities for sensitivity enhancement by up to a factor of 107 are discussed.

Tunable in the range of 4.5-6.8†µm room temperature single-crystal Fe:CdTe laser pumped by Fe:ZnSe laser.

We report a laser operation from a Fe:CdTe single crystal, pumped by 40-ns pulses of a 4.12-µm Fe:ZnSe laser. The maximum output energy of 5.8 mJ was produced at 5.4 µm with 30% absorbed energy slope efficiency. A record 2300-nm-wide smooth and continuous wavelength tunability over 4.5-6.8 µm range was demonstrated, being the longest wavelength tuning achieved for Fe2+-doped chalcogenide lasers. We also discuss the features of the oscillation spectra.

High-efficiency continuous-wave single-mode room-temperature operation of Cr:CdSe single-crystal laser with output power of 2.3 W.

We report on the study of quenching and thermal lensing based on simple effective lens approximation in a Cr2+:CdSe active medium, including detailed research on the medium's luminescence lifetime dependence on temperature in the 236-391 K range. This work has allowed us to partially overcome the limitations associated with thermal effects in the medium and build a laser system that allowed power scalability to be realized for the Cr2+:CdSe laser. Longitudinal pumping using a continuous-wave Tm-doped fiber laser at 1.908 µm produced an output of 2.3 W at 2.65 µm with an absorbed pump power slope efficiency of 47.6%, which, to the best of our knowledge, is the highest output power achieved in Cr:CdSe continuous-wave lasers.

High-efficiency high-repetition-rate gain-switched operation around 3 µm in Cr2+:CdSe single-crystal laser pumped by fiber-laser-pumped Ho3+:YAG laser.

We report the efficient gain-switched high-repetition-rate Cr2+:CdSe single-crystal laser operating around 3 µm and pumped at 2.09 µm by a fiber-laser-pumped Ho3+:YAG laser. Average power of up to 6 W with the optical-to-optical efficiency of 67% at 2.65-2.85 µm was achieved in the Cr2+:CdSe laser with nanosecond pulses at 8 kHz repetition rate. Wavelength tunability from 2.5 µm to 3.15 µm was demonstrated using a set of cavity mirrors and an intracavity Lyot filter.