Unifying fast computer-generated hologram calculation and prepress for new and existing production techniques.

Directed by successfully manufacturing the computer-generated hologram (CGH) using the computer-to-film (CtF) process, we present, to the best of our knowledge, a new method for low-cost and fast hologram manufacturing. This new method allows for advances in the CtF process and manufacturing using new techniques in hologram production. These techniques include computer-to-plate, offset printing, and surface engraving utilizing the same CGH calculations and prepress. With an advantage in cost and the possibility to be mass manufactured, the aforementioned techniques combined with the presented method have a solid foundation to be implemented as security elements.

Polymerization kinetics of experimental resin composites functionalized with conventional (45S5) and a customized low-sodium fluoride-containing bioactive glass.

This study aimed to investigate polymerization kinetics and curing light transmittance of two series of experimental dental resin composites filled with 0-40 wt% of either 45S5 bioactive glass (BG) or a customized low-Na F-containing BG. Polymerization kinetics in 0.1-mm and 2-mm thick layers were investigated through real-time degree of conversion measurements using a Fourier transform infrared (FTIR) spectrometer. FTIR spectra were continuously collected at a rate of 2 s-1 during light-curing (1340 mW/cm2). Light transmittance through 2-mm thick composite specimens was measured using a UV-Vis spectrometer at a rate of 20 s-1. Unlike BG 45S5, which led to a dose-dependent reduction in the rate and extent of polymerization, the customized low-Na F-containing BG showed a negligible influence on polymerization. The reduction in light transmittance of experimental composites due to the addition of the low-Na F-containing BG did not translate into impaired polymerization kinetics. Additionally, the comparison of polymerization kinetics between 0.1-mm and 2-mm thick layers revealed that polymerization inhibition identified for BG 45S5 was not mediated by an impaired light transmittance, indicating a direct effect of BG 45S5 on polymerization reaction. A customized low-Na F-containing BG showed favourable behaviour for being used as a functional filler in light-curing dental resin composites.

Wavelength-dependent light transmittance in resin composites: practical implications for curing units with different emission spectra.

OBJECTIVES: To evaluate light transmittance as a function of wavelength for eight composite materials and compare the transmittance for blue light produced from two curing units with different emission spectra. MATERIALS AND METHODS: Light transmittance through 2- and 4-mm-thick composite specimens was recorded in real time during 30 s of curing using a broad-spectrum (peaks at 405 and 450 nm) and a narrow-spectrum (peak at 441 nm) LED-curing unit. The spectral resolution of 0.25 nm and temporal resolution of 0.05 s resulted in a large amount of light transmittance data, which was averaged over particular spectral ranges, for the whole measurement period. Statistical analysis was performed using Welch ANOVA with Games-Howell post hoc test, t test, and Pearson correlation analysis. The level of significance was 0.05 and n = 5 specimens per experimental group were prepared. RESULTS: Light transmittance varied as a function of wavelength and time, revealing significantly different patterns among the tested materials. Light transmittance for different parts of curing unit spectra increased in the following order of emission peaks (nm): 405 < 441 < 450. Of particular interest was the difference in transmittance between 441 and 450 nm, as these peaks are relevant for the photoactivation of camphorquinone-containing composites. A high variability in light transmittance among materials was identified, ranging from statistically similar values for both peaks up to a fourfold higher transmittance for the peak at 450 nm. CONCLUSION: Each material showed a unique pattern of wavelength-dependent light transmittance, leading to highly material-dependent differences in blue light transmittance between two curing units. CLINICAL RELEVANCE: Minor differences in blue light emission of contemporary narrow-peak curing units may have a significant effect on the amount of light which reaches the composite layer bottom.

The effects of extended curing time and radiant energy on microhardness and temperature rise of conventional and bulk-fill resin composites.

OBJECTIVES: To investigate radiant energy, microhardness, and temperature rise in eight resin composites cured with a blue or violet-blue curing unit, using a curing protocol which exceeded manufacturer recommendations. MATERIALS AND METHODS: Cylindrical composite specimens (d = 8 mm, h = 2 or 4 mm, n = 5 per experimental group) were light-cured for 30 s. Light transmittance through specimens was recorded in real time to calculate radiant energy delivered to the specimen bottom. Vickers microhardness was used to evaluate the polymerization effectiveness at depth. Temperature rise at the bottom of the specimens was measured in real time using a T-type thermocouple. RESULTS: Radiant energy delivered from the blue and violet-blue curing unit amounted to 19.4 and 28.6 J/cm2, which was 19 and 13% lower than specified by the manufacturer. Radiant energies at bottom surfaces (0.2-7.5 J/cm2) were significantly affected by material, thickness, and curing unit. All of the composites reached 80% of maximum microhardness at clinically relevant layer thicknesses. The benefit of using the higher-irradiance violet-blue curing unit was identified only in composites containing alternative photoinitiators. Temperature rise during curing ranged from 4.4 to 9.3 °C and was significantly reduced by curing with the lower-intensity blue curing unit and by increasing layer thickness. CONCLUSION: Curing for 30 s, which can be regarded as extended considering manufacturer specifications, produced radiant energies which are in line with the recommendations from the current scientific literature, leading to adequate curing efficiency and acceptable temperature rise. CLINICAL RELEVANCE: Extended curing time should be used to minimize concerns regarding undercuring of composite restorations.

Curing potential of experimental resin composites with systematically varying amount of bioactive glass: Degree of conversion, light transmittance and depth of cure.

OBJECTIVES: The aim of this work was to investigate the curing potential of an experimental resin composite series with the systematically varying amount of bioactive glass 45S5 by evaluating the degree of conversion, light transmittance and depth of cure. METHODS: Resin composites based on a Bis-GMA/TEGDMA resin with a total filler load of 70 wt% and a variable amount of bioactive glass (0-40 wt%) were prepared. The photoinitiator system was camphorquinone and ethyl-4-(dimethylamino) benzoate. The degree of conversion and light transmittance were measured by Raman spectroscopy and UV-vis spectroscopy, respectively. The depth of cure was evaluated according to the classical ISO 4049 test. RESULTS: The initial introduction of bioactive glass into the experimental series diminished the light transmittance while the further increase in the bioactive glass amount up to 40 wt% caused minor variations with no clear trend. The curing potential of the experimental composites was similar to or better than that of commercial resin composites. However, unsilanized bioactive glass fillers demonstrated the tendency to diminish both the maximum attainable conversion and the curing efficiency at depth. CONCLUSIONS: Experimental composite materials containing bioactive glass showed a clinically acceptable degree of conversion and depth of cure. The degree of conversion and depth of cure were diminished by bioactive glass fillers in a dose-dependent manner, although light transmittance was similar among all of the experimental composites containing 5-40 wt% of bioactive glass. CLINICAL SIGNIFICANCE: Reduced curing potential caused by the bioactive glass has possible consequences on mechanical properties and biocompatibility.

Light transmittance and polymerization kinetics of amorphous calcium phosphate composites.

OBJECTIVES: This study investigated light transmittance and polymerization kinetics of experimental remineralizing composite materials based on amorphous calcium phosphate (ACP), reinforced with inert fillers. MATERIALS AND METHODS: Light-curable composites were composed of Bis-EMA-TEGDMA-HEMA resin and ACP, barium glass, and silica fillers. Additionally, a commercial composite Tetric EvoCeram was used as a reference. Light transmittance was recorded in real-time during curing, and transmittance curves were used to assess polymerization kinetics. To obtain additional information on polymerization kinetics, temperature rise was monitored in real-time during curing and degree of conversion was measured immediately and 24 h post-cure. RESULTS: Light transmittance values of 2-mm thick samples of uncured ACP composites (2.3-2.9 %) were significantly lower than those of the commercial composite (3.8 %). The ACP composites presented a considerable transmittance rise during curing, resulting in post-cure transmittance values similar to or higher than those of the commercial composite (5.5-7.9 vs. 5.4 %). The initial part of light transmittance curves of experimental composites showed a linear rise that lasted for 7-20 s. Linear fitting was performed to obtain a function whose slope was assessed as a measure of polymerization rate. Comparison of transmittance and temperature curves showed that the linear transmittance rise lasted throughout the most part of the pre-vitrification period. CONCLUSIONS: The linear rise of light transmittance during curing has not been reported in previous studies and may indicate a unique kinetic behavior, characterized by a long period of nearly constant polymerization rate. CLINICAL RELEVANCE: The observed kinetic behavior may result in slower development of polymerization shrinkage stress but also inferior mechanical properties.

Effects of bleaching agent on physical and aesthetic properties of restorative materials.

To investigate the effects of bleaching agent on microhardness, color and light transmission of different restorative materials. Specimens (n=20) of Tetric EvoCeram (TEC), Tetric EvoCeram Bulk Fill (TECBF) and Equia Fill (EQUIA) were treated with either 40% hydrogen peroxide Opalesence Boost or destilled water for 45 min. Specimens were stained in tea solution or stored in deionized water for one and two weeks. Color, microhardness and light transmission were monitored at the baseline, after the bleaching and after the tea immersion or storage in deionized water. After the bleaching a significant reduction in surface microhardness (p<0.001) was recorded for all materials. Clinically visible color change (ΔE>3) was observed after the bleaching and after treatment in tea solution, but only in EQUIA samples. The absorption coefficient was the largest for the samples stained in tea solution. Bleaching can affect the microhardness and color of fillings; therefore, they should be sometimes replaced.

Satellite bands of the RbCs molecule in the range of highly excited states.

We report on the observation of three RbCs satellite bands in the blue and green ranges of the visible spectrum. Absorption measurements are performed using all-sapphire cell filled with a mixture of Rb and Cs. We compare high resolution absorption spectrum of Rb-Cs vapor mixture with pure Rb and Cs vapor spectra from the literature. After detailed analysis, the new satellite bands of RbCs molecule at 418.3 nm, 468.3, and 527.5 nm are identified. The origin of these bands is discussed by direct comparison with difference potentials derived from quantum chemistry calculations of RbCs potential energy curves. These bands originate from the lower Rydberg states of the RbCs molecule. This study thus provides further insight into photoassociation of lower Rydberg molecular states, approximately between Cs(7s) + Rb(5s) and Cs(6s) + Rb(6p) asymptotes, in ultracold gases.

Conversion and temperature rise of remineralizing composites reinforced with inert fillers.

OBJECTIVES: Remineralizing experimental composites based on amorphous calcium phosphate (ACP) were investigated. The impact of curing time (20 and 40s), curing depth (1, 2, 3 and 4mm) and addition of inert fillers (barium glass and silica) on the conversion and temperature rise during curing were examined. METHODS: Five ACP-composites and two control composites were prepared based on the light-curable EBPADMA-TEGDMA-HEMA resin. For temperature measurements, a commercial composite was used as an additional control. Conversion was assessed using FT-Raman spectroscopy by comparing the relative change of the band at 1640 cm(-1) before and after polymerization. The temperature rise during curing was recorded in real-time using a T-type thermocouple. RESULTS: At 1mm depth, the ACP-composites attained significantly higher conversion (77.8-87.3%) than the control composites based on the same resin (60.5-66.3%). The addition of inert fillers resulted in approximately 5% lower conversion at clinically relevant depths (up to 2mm) for the curing time of 40s. Conversion decline through depths depended on the added inert fillers. Conversion values higher than 80% of the maximum conversion were observed for all of the ACP-composites at depths up to 3mm, when cured for 40s. Significantly higher total temperature rise for the ACP-composites (11.5-13.1 °C) was measured compared to the control composites (8.6-10.8 °C) and the commercial control (8.7 °C). CONCLUSIONS: The admixture of inert fillers represents a promising strategy for further development of ACP-composites, as it reduced the temperature rise while negligibly impairing the conversion. CLINICAL SIGNIFICANCE: High conversions of ACP-composites are favorable in terms of mechanical properties and biocompatibility. However, high conversions were accompanied with high temperature rise, which might present a pulpal hazard.

Time-averaged photon-counting digital holography.

Time-averaged holography has been using photo-emulsions (early stage) and digital photo-sensitive arrays (later) to record holograms. We extend the recording possibilities by utilizing a photon-counting camera, and we further investigate the possibility of obtaining accurate hologram reconstructions in rather severe experimental conditions. To achieve this, we derived an expression for fringe function comprising the main parameters affecting the hologram recording. Influence of the main parameters, namely the exposure time and the number of averaged holograms, is analyzed by simulations and experiments. It is demonstrated that taking long exposure times can be avoided by averaging over many holograms with the exposure times much shorter than the vibration cycle. Conditions in which signal-to-noise ratio in reconstructed holograms can be substantially increased are provided.

Digital holography at light levels below noise using a photon-counting approach.

Recording of digital holograms of a weak signal [0.44 counts per second (cps)] hidden below the detector's noise (21 cps) is investigated by employing the high dynamic range of a photon-counting detector. Recording conditions are discussed in terms of the most important holographic measures, namely, the fringe visibility (or contrast) and signal-to-noise ratio (SNR), and in relation to the main holographic parameters. Theoretically evaluated curves are tested by recording holograms for a wide range of the parameter values. We found that (i) the optimum set of holographic parameters can be determined for a harsh signal conditions, (ii) increasing the visibility does not necessarily improve the more important SNR, and (iii) in cases of nearly constant visibility, the SNR clearly reveals differences in the quality of holographic recordings.

Atomic wave-packet dynamics and third-harmonic generation in sodium.

In femtosecond degenerate four-wave mixing experiments in sodium vapor, quantum beats are observed at the wavelength of the third harmonic when the fundamental beams are three-photon resonant. The period of beating, which corresponds to fine structure energy-level splitting, does not change with the atomic number density, buffer gas pressure, or laser intensity. Surprisingly, the third-harmonic signal is observed only at negative time delays for the transient grating pulse sequence. We relate this to the well-known interference effect between excitation pathways involving the fundamental and the third-harmonic fields, which leaves atoms virtually unexcited and prevents formation of population grating.